• Title/Summary/Keyword: Methyl green

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${\gamma}-Pyrone$ Derivatives, Kojic Acid Methyl Ethers from a Marine-Derived Fungus Altenaria sp.

  • Li, Xifeng;Jeong, Jee-Hean;Lee, Kang-Tae;Rho, Jung-Rae;Choi, Hong-Dae;Kang, Jung-Sook;Son, Byeng-Wha
    • Archives of Pharmacal Research
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    • v.26 no.7
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    • pp.532-534
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    • 2003
  • Kojic acid dimethyl ether (1), and the known kojic acid mono methyl ether (2), kojic acid (3) and phomaligol A (4) have been isolated from the organic extract of the broth of the marine-derived fungus Altenaria sp. collected from the surface of the marine green alga Ulva pertusa. The structures were assigned on the basis of comprehensive spectroscopic analyses. Each isolate was tested for its tyrosinase inhibitory activity. Kojic acid (3) was found to have significant tyrosinase inhibitory activity, but compounds 1, 2, and 4 were found to be inactive.

Studies on the Composition of Green and Roast Coffee bean (커피생두(生豆)(Green Coffee)와 볶은 커피두(豆)(Roast Coffee)의 성분(成分)에 관(關)한 연구(硏究))

  • Choi, Min-Kang;Lee, Yong-Ock;Ko, Young-Su
    • Journal of Nutrition and Health
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    • v.11 no.1
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    • pp.9-16
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    • 1978
  • A Comparison of the analysis of the green and roast coffee of Arabica and Robusta compositions and regular instant coffee has been investigated by chromatography. The coffee oil were obtained by extracting the green and roast coffee with ethyl ether by soxhlet methood. Instant coffee samples were accurately weighted into 100ml beaker (ca. 0.5g regular coffee and 1.5g decaffeinated coffee) and add ca. 50ml water, heat and boil, remove from heat, and mechanically stried ca. 15min. and filtered of one sample and another sample were without filtrated and proceed with liquid chromatographic separation. The fatty acid compositions of green and roast coffee were compared by gas liquid chromatography and general chemical compositions of sample were analysed. Some similarities between green and roast coffee fatty acids were found in the case of green and roast coffee of both kinds acid methyl esters. They contained stearic, oleic, linoleic, and unknown fatty acid, and palmitic ana linoleic acid were rich.

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Studies on the substitution pigment of Dan-Chung (양록단청 대체안료 개발 연구)

  • Kim, Sa-Dug;Kim, Soon-Kwan;Hong, Jung-Ki;Kang, Da-Il;Lee, Myong-Hee
    • 보존과학연구
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    • s.20
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    • pp.121-137
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    • 1999
  • Among pigment used at work of Dan-Chung, Emerald Green is specific illuminating fluorescent light of green. It is very difficult to change other organic or inorganic pigment. All of the internal high class pigment has rare light. But Emerald Green is superior to fresh color and stability out of industrial chemical products. It forms over 50% of quantity and importance of a pattern painting. Emerald Green prohibited to produce because of its toxicpollutants, so required to changing pigment development. It is characterized to excellent color, convenient work, economical, against-sunlight, against-air pollutant and durability. The result of a test is follows; 1. We are investigated into producing internal natural Emerald Green, import external pigment and industrial synthesis method etc. but unable to buy because of its toxic pollutant. 2. We are made six samples by yellowish and green is hpigment mixing. We tested on against sunlight and air pollutant. The best mixing ratio is follows. Titanium Dioxide R760 : 18g- Chalk, White Wash : 10g- Permanent Yellow : 7g- Cyanine Green : 8g- Chrome Yellow : 3g- Resin(Vehicle) : Acryl Emulsion(Styrene + 2-Ethyl HexylAcrylate + Methyl Meth Acrylate) 8%

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Inhibitory Effect of Green-Yellow Vegetables on the Mutagenicity in Salmonella Assay System and on the Growth of AZ-521 Human Gastric Cancer Cells (녹황색 채소류의 돌연변이유발 억제 및 AZ-521 위암세포의 성장 저해효과)

  • 박건영;이경임;이숙희
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.2
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    • pp.149-153
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    • 1992
  • The antimutagenic effect of green-ye1low vegetables on the mutagenicities induced by N-methyl-N'-nitro-N-nitrosoguanidine(MNNG) and N-nitrosodimethylamine (NDMA) in Salmonella assay system and also their inhibitory effect on AZ-521 human gastric cancer cells were studied. Twenty-four items from twenty six kinds of vegetables(92%) revealed antimutagenic activity toward MNNG (p< 0.0l, 0.05). Perilla leaf, Korean cabbage, cauliflower, lettuce, mustard leaf, water dropwort, small water dropwort, carrot and burdock inhibited the mutagenicity more than 80%. The methanol extracts of the vegetables also showed the antimutagenic activity toward NDMA (p< 0.01, 0.05). Especially, perilla leaf, kale, soybean sprout and onion inhibited more than 80% of the NDMA induced mutagenicity in S. typhimurium TA100. Small water dropwort and perilla leaf exhibited the strong inhibitory effect (97~100%) on the growth of the AZ-521 human gastric cancer cells. Soybean sprout, water dropwort, broccoli, crown daisy, green red pepper, red pepper leaves, spinach, cabbage and sweet potato also inhibited growth of the cancer cells (p < 0.001~0.05).

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Herbicidal Efficacy of Bispyribac-sodium Combined with Other Herbicides for Annual Bluegrass(Poa annua L.) Suppression (새포아풀(Poa annua L.) 방제를 위한 Bispyribac-sodium과 타약제와의 혼합 상호작용)

  • Park, Nam-Il;Lee, In-Yong;Park, Jae-Eup;Kim, Ho-Jun;Chun, Jae-Chul;Ogasawara, Masaru
    • Asian Journal of Turfgrass Science
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    • v.21 no.1
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    • pp.39-49
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    • 2007
  • Bispyribac-sodium is a new-type herbicide that prevents the occurrence of annual bluegrass by the suppression of anthesis and inflorescence emergence on the bent green. The greenhouse experiment was conducted to investigate interaction effect of the bispyribac-sodium with 21 soil- and foliar-applied herbicides in regards of herbicidal activity of annual bluegrass. The remarkable synergism was not found on the combination of bispyribac-sodium with benfluralin, pendimethalin, oryzalin, siduron, chlorphtalim, isoxaben, bifenox, tenylchlor, indanofan, bentazone, imazosulfuron, imazaquin, halosulfuron-methyl and limsulfuron. However, mixture of bispyribac-sodium with mecoprop, triclopyr, metsulfuron-methyl, cyclosulfamuron, pyrazosulfuron-ethyl and pyributicarb produced greater synergism of herbicidal activity when compared with unmixed, single application. Phytotoxicity was low on bentgrass green and fast recovery was observed. In future, it would be strongly necessary to do research to Investigate the effect of bispyribac-sodium combination with other herbicides under various environment and management practices on-site bentgrass green.

Synthesis of 6-Alkyl-3-Chromonealdehyde(2,2-dialkyl)hydrazone Derivatives for Green Light Emitting Materials (녹색발광 6-알킬-3-크로몬알데히드(2,2-디알킬)하이드라존 유도체의 합성)

  • Chung, Pyung-Jin;Chang, Hong-Joon
    • Applied Chemistry for Engineering
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    • v.21 no.4
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    • pp.424-429
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    • 2010
  • 6-Alkyl-3-chromonealdehyde (2,2-dialkyl)hydrazone derivatives were synthesized by dehydration condensation. They are green-emitting materials for organic light emitting device (OLED) composed of electron acceptor of 6-alkyl-3-chromonealdehydes and electron donor of 2,2-dialkylhydrazones in a conjugated structure. The structural properties of reaction products were analyzed by FT-IR and $^1H$-NMR spectroscopy. The thermal stabilities and reactivities were measured by melting points and yields. The UV-visibles and PL properties were also determined by excitation spectra and emission spectra, respectively.

Synthesis, Characterization and Application of Poly(4-Methyl Vinylpyridinium Hydroxide)/SBA-15 Composite as a Highly Active Heterogeneous Basic Catalyst for the Knoevenagel Reaction

  • Kalbasi, Roozbeh Javad;Kolahdoozan, Majid;Massah, Ahmadreza;Shahabian, Keinaz
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2618-2626
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    • 2010
  • In this paper poly (4-methyl vinylpyridinium hydroxide)/SBA-15 composite was prepared as a highly efficient heterogeneous basic catalyst by in situ polymerization method for the first time. It was characterized by XRD, FT-IR, BET, TGA, SEM and back titration using NaOH. This catalyst exhibited the excellent catalytic activities for the Knoevenagel condensation of various aldehydes with ethyl cyanoacetate. Over this catalyst, ${\alpha},{\beta}$-unsaturated carbonyl compounds were obtained in the reasonable yield at $95^{\circ}C$ in 10 - 30 min in $H_2O$ as a solvent with a 100% selectivity to the condensation products. Catalyst could be easily recycled after the reaction and it could be reused without the significant loss of activity/selectivity performance. No by-product formation, high yields, short reaction times, mild reaction conditions and operational simplicity with reusability of the catalyst were the salient features of the present synthetic protocol. Presence of $H_2O$ as a solvent was also recognized as a "green method".

Antibaterial Activity and Skin Moisturizing Effect of Cedrela sinensis A. Juss Shoots Extracts (참죽나무 새순 추출물의 항균 활성과 피부 보습효과에 관한 연구)

  • Kim, Sun-Young;Lee, Min-Hye;Jo, Na-Rae;Park, Soo-Nam
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.36 no.4
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    • pp.315-321
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    • 2010
  • In this study, we investigated the antibacterial activity and the skin moisturizing effect of cream contaning Cedrela sinensis A. Juss shoots extracts. MIC values of ethyl acetate fraction from Cedrela sinensis A. Juss shoots extracts on P. acnes and S. aureus were 0.13 %, 0.03% respectively and P. ovale and E. coli were 0.25 % equally. The results showed that the antibacterial activity of the ethyl acetate fraction on P. acnes and S. aureus were higher than the methyl paraben. The cream containing the ethyl acetate fraction from Cedrela sinensis A. Juss shoots extracts was formulated and its skin moisturizing effect was evaluated in a clinical trial. The skin hydration and transepidermal water loss (TEWL) were investigated after topical application of the cream. The skin hydrating effect of the cream containing Cedrela sinensis A. Juss shoots extract was 10 ~ 15 % higher than the placebo cream, and transepidermal water loss was decreased to 6.7 g/$m^2h$ in the subjects applied with cream containing the ethyl acetate fraction of Cedrela sinensis A. Juss shoots extracts. These results indicate that ethyl acetate fraction from Cedrela sinensis A. Juss shoots extracts could be applicable to new functional antibacterial cosmetics.

Karyotype and Insecticide Resistance of the Green Peach Aphids (Myzus persicae Sulzer) collected from Tobacco fields (연초포장에서 발생하는 복숭아혹진딧물의 핵형과 살충제 저항성)

  • 채순용;김영호;김상석;장영덕
    • Journal of the Korean Society of Tobacco Science
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    • v.19 no.2
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    • pp.107-116
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    • 1997
  • Karyotype of apterous green peach aphid (Myzus persicae SuIBer) populations occurring in tobacco fields and their resistance to insecticides were investigated. All of the 16 clones collected from tobacco fields had same chromosome number of 2n=12. Among them, 5 clones had the normal karyotype, regardless of color morph, but chromosomal translnations between #1 and #3 autosomal chromosomes were noted in the other 11 clones. All of the aphid clones were highly resistant tolambda cyhalothrin, a pyrethroid pesticide, having over 20 times higher concentrations of LD90 than recommended concentration (10ppm) for the aphid. However, their resistance to acephate, demeton 5-methyl and pirimicarh varied depending on the clones, among which green-colored clones were generally more resistant to the pesticides than red-colored ones. No association was found between the insecticide resistance and the karyotype of the aphid in this experiment.

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A study on crystal growth and properties of high quality DAST (고품질 DAST 결정성장과 특성에 관한 연구)

  • 윤선웅;연석주;김종흠
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.1
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    • pp.12-16
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    • 2004
  • In this study, we have investigated the development of the crystal growth stability and reproducibility for large and high-quality DAST. DAST crystal were grown from a saturated methanol solution by a slow cooling method and DAST was synthesized by the condensation of 4-methyl-n-methyl pyridinum tosylate, which was prepared from 4-pocoline and methyl toluenesulponate and 4-N-dimethyl amino-bezaldehyde in the presence of piperidine. We had synthesized DAST crystals in dry Argon atmosphere in order to avoid the formation of hydride organge co-crystals, DAST$.$$H_2O$. Since DAST molecules crystallize in a humid atmosphere, crystal structure become centrosymmetric, and then second order NLO (nonlinear optical) properties would be disappeared. We fixed the growth orientation of DAST crystal (001) surface. The crystal growth was proceeded at a cooling rate of $H_2O$/day and the cooling period is for 4 days. The dimensions of seed crystal was $2.5\times 3.6\times0.4\textrm{mm}^3$ and we have obtained a DAST crystal with the dimension of $10\times 10.5\times3.0\textrm{mm}^3$. The color of grown DAST crystal is red and it's surface appears to be metallic green.