• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.1
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• pp.92-100
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• 2000

The model gas reaction tests were carried out to investigate the purification characteristics of methane on the exclusive catalyst for NGV. The experiment was conducted with the factors which affect the conversion efficiency of methane, such as Redox ratio, coexistence components of CO, MO, $H_2$O, precious metals and additives. The catalyst loaded with larger amount of pd and with additive La showed lower light-off temperature. In the presence of CO and NO, the conversion efficiency of methane was varied according to the kind of additive loaded. The conversion efficiency of methane was dropped for the catalyst loaded with La under lean air-fuel ratio, while it increased for the one loaded with Ti+Zr for the same condition. It was shown that the water vapor inhibited methane from oxidation by its poisoning on the surface of catalyst.

• Journal of the Korean Solar Energy Society
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• v.27 no.1
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• pp.75-81
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• 2007

Steam reforming of methane using Xe-arc solar simulator was studied for the application of concentrated solar energy into chemical reaction. The reactor, a volumetric absorber, consisted of a porous ceramic foam disk coated with commercial reforming catalyst. Operating temperature was in the range of $450\;-\;550^{\circ}C$ and the excess steam ratio to methane was from 3.0 to 5.0. At the steady-state condition, the conversion of methane Increased with temperature in the range of 15 % - 30 % and the experimentally determined conversion was found to be close to theoretical equilibrium conversion. It was also found that the CO selectivity slightly decreased with excess steam ratio. Finally, the conversion of methane decreased significantly with space velocity of reactants.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.761-764
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• 2009

The thermocatalytic decomposition of methane is an environmentally attractive approach to $CO_2$-free production of hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbon from the reactor. The usage of carbon black was reported as stable catalyst for decomposition of methane. Therfore, carbon black (DCC-N330) is used as catalyst. A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was selected for the thermo-catalytic decomposition. The porpane-containg methnae decomposition reaction was operated at the temperature range of 850-900 $^{\circ}C$ methane gas velocity of 1.0 $U_{mf}$ and the operating pressure of 1.0 atm. In this work, propane was added as reactant to make methane conversion higher. Therefore we compared with methane conversion and pre-experiment methane conversion that using only methane as reactant. The carbon black, after experiment, was measured in particle size and surface area and analyzed surface of the carbon black by TEM.

• Journal of the Korean Applied Science and Technology
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• v.17 no.2
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• pp.139-143
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• 2000

There appeared enhancements of the conversion of methane by adding a small amount of CO in the aromatization reaction of methane using the Mo-zeolite catalyst. In case of adding $CO_{2}$, $CO_{2}$ changed to CO first, and then the conversion reaction occurred. It was observed by using isotopes as reactants that CO is related to the aromatization reaction of methane.

• Journal of the Korea Organic Resources Recycling Association
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• v.6 no.1
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• pp.31-42
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• 1998

A fundamental study on methane conversion for the collection organic wastes of agriculture, forestry and fishers was performed in a laboratory scale. As a result, selected Run B sample were obtained 18.41 C/N Ratio and 168.96 mg/L TCOD; Under the biochemical methane potential test, theoretical and actual methane generation was 313.6 mg/L VS added and 234.2 mg/L VS added, respectively; However, methane conversion from Run B were occurred 74% by anaerobic digestion. By the first order reaction kinetics, kinetic constant were $0.2476d^{-1}$ for Run B. Three steps fill-up filter reactor was evaluated methane content 16% up to promote than blank reactor; TCOD and SCOD have reduced 44.7% and 44.2%, respectively.

• Journal of Microbiology and Biotechnology
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• v.24 no.12
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• pp.1597-1605
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• 2014

Methane is considered as a next-generation carbon feedstock owing to the vast reserves of natural and shale gas. Methane can be converted to methanol by various methods, which in turn can be used as a starting chemical for the production of value-added chemicals using existing chemical conversion processes. Methane monooxygenase is the key enzyme that catalyzes the addition of oxygen to methane. Methanotrophic bacteria can transform methane to methanol by inhibiting methanol dehydrogenase. In this paper, we review the recent progress made on the biocatalytic conversion of methane to methanol as a key step for methane-based refinery systems and discuss future prospects for this technology.

• Journal of Microbiology and Biotechnology
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• v.25 no.3
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• pp.375-380
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• 2015

Recently, methane has attracted much attention as an alternative carbon feedstock since it is the major component of abundant shale and natural gas. In this work, we produced methanol from methane using whole cells of Methylosinus trichosporium OB3b as the biocatalyst. M. trichosporium OB3b was cultured on NMS medium with a supply of 7:3 air/methane ratio at 30℃. The optimal concentrations of various methanol dehydrogenase inhibitors such as potassium phosphate and EDTA were determined to be 100 and 0.5 mM, respectively, for an efficient production of methanol. Sodium formate (40 mM) as a reducing power source was added to enhance the conversion efficiency. A productivity of 49.0 mg/l·h, titer of 0.393 g methanol/l, and conversion of 73.8% (mol methanol/mol methane) were obtained under the optimized batch condition.

• Bulletin of the Korean Chemical Society
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• v.31 no.1
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• pp.120-124
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• 2010

Monometallic, bimetallic and trimetallic particles consisting of different weight compositions of Pt-Pd-Rh over pure alumina wash coats have been synthesized and their catalytic performance on methane conversion was studied from 150 to $600^{\circ}C$. Different catalyst formulations with variable Pt, Pd and Rh contents for bimetallic and trimetallic systems were tried and $Pt_{(1.5)}Rh_{(0.3)}/Al_2O_3$ and $Pt_{(1.0)}Pd_{(1.0)}Rh_{(0.3)}/Al_2O_3$ shows low $T_{50}$ and $T_{90}$ temperatures. Bimetallic and trimetallic particle synergism acts as three way catalysts and therefore, all the catalysts show 100% methane conversion. The effect of supports such as $ZrO_2$ and $TiO_2$ on methane combustion was investigated; from $T_{50}$ and $T_{90}$ results both $Al_2O_3$ and $ZrO_2$ are suitable supports for low temperature methane combustion.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.1
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• pp.1-7
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• 2022

Interest in hydrogen productions that do not emit carbon dioxide and can produce hydrogen at a low price is increasing. Reforming and electrolysis are widely used, but they have limitations, such as carbon dioxide problems and costs. The methane can be decomposed as hydrogen and solid carbon without carbon dioxide emission at high temperatures. In this research, the methane pyrolysis experiment was conducted at 1,200℃ and 1,400℃ in a ceramic tube. The composition of the produced gas was measured by gas chromatography before carbon blocked the tube. The methane conversion rate and hydrogen selectivity were calculated based on the results. The hydrogen selectivity was derived as 60% and 55% at the highest point at 1,200℃ and 1,400℃, respectively. The produced solid carbon was expected to be carbon black and was analyzed using scanning electron microscope.

• Applied Chemistry for Engineering
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• v.9 no.6
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• pp.878-883
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• 1998

The methane combustion reaction was conducted over Pb-ZSM-5 catalysts. ZSM-5 synthesized at low temperature and atomospheric pressure was used as a support. The change of methane conversion with $SiO_2/Al_2O_3$ molar ratio was tested. The methane conversions of the synthesized Pb-ZSM-5 catalyst was compared with those of a commercial Pd-ZSM-5(PQ Co.) and $PdO/{\gamma}-Al_2O_3$. The methane conversion increased with the decrease in $SiO_2/Al_2O_3$ molar ratio. The combustion rate of methane also increased with the decrease in $SiO_2/Al_2O_3$ molar ratio. The synthesized Pb-ZSM-5 showed better methane conversion than that of the commercial one. It is found that a crucial factor in methane combustion reaction is oxygen adsorption strength on the catalysts.