• Transactions of the Korean Society of Automotive Engineers
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• v.3 no.2
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• pp.136-145
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• 1995

The aim of this study is to gain a better understanding of the effect of a flow motion on the flame development by means of an optically-accessible constant-volume combustion chamber and the visualization technique of a combustion flame. At first, the characteristics of a flame propagation are investigated in the combustion field of the two kinds of flow conditions such as a quiescent and a flowing condition, and methane-air mixture is used as fuel. Then the same investigation is performed in two flow configurations : bulk flow motion type and turbulence generating type. In this study, the combustion phenomena are analyzed by measuring the combustion pressure, flame propagation speed, mean velocity, turbulent intensity, and mass fraction burned.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.10a
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• pp.229-234
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• 2004

The objective of the present study is to conduct model combustion tests for double swirl coaxial injectors to identify their combustion stability characteristics. Gaseous oxygen and mixture of methane and propane have been used as simulant propellants. Two model chambers tuned to the If acoustic resonance mode of a full-scale thrust chamber were manufactured to be used as a combustion cylinder. The main idea of the experiment is that the mixing mechanism is considered as a dominant factor significantly affecting combustion instability in a full-scale thrust chamber. Self-excited dynamic pressure values in a model chamber show different combustion stability zones with respect to a recess number. Upon test results, couplings between combustion conditions and the IT acoustic resonance mode become strengthened with the increase of a recess length.

• Journal of the Korean Society of Combustion
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• v.21 no.4
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• pp.48-60
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• 2016

Experimental and numerical studies were conducted to investigate flame behaviors near flammable limits for downstream-interacting SNG-air premixed flames in a counter-flow configuration. The SNG fuel consisted of a methane, a propane, and a hydrogen with volumetric ratios of 91, 6, and 3%, respectively. The most appropriate priority for some reliable reaction mechanisms examined was given to the mechanism of UC San diego via comparison of lean extinction limits attained numerically with experimental ones. Flame stability map was presented with a functional dependencies of lower and upper methane concentrations in terms of global strain rate. The results show that, at the global strain rate of $30s^{-1}$, lean extinction boundary is slanted while rich extinction one is relatively less inclined because of the dependency of such extinction boundary shapes on deficient reactant Lewis number governed by methane mainly. Further increase of global strain rate forces both extinction boundaries to be more slanted and to be shrunk, resulting in an island of extinction boundary and subsequently one flame extinction limit. Extinction mechanisms for lean and rich, symmetric and asymmetric extinction boundary were identified and discussed via heat losses and chemical interaction.

• Journal of the Korean Society of Combustion
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• v.13 no.4
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• pp.47-53
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• 2008

The reaction mechanism of methane dry reforming has been investigated using an arc-jet reactor. The effects of input power, $CO_2/CH_4$ and added $O_2$ were investigated by product analysis, including CO, $H_2$, $C_{2}H_{Y}$ and $C_{3}H_{Y}$ as well as $CH_4$ and $CO_2$. In the process, input electrical power activated the reactions between $CH_4$ and $CO_2$ significantly. The increased feed ratio of the $CO_2$ to $CH_4$ in the dry reforming does not affect to the $CH_4$ conversion. but we could observe increase in CO selectivity together with decreasing $H_2$ generation. Added oxygen can also increase not only CO selectivity but also $CH_4$ conversion. However, hydrogen selectivity was decreased significantly due to a increased $H_{2}O$ formation.

• 한국연소학회:학술대회논문집
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• 2006.04a
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• pp.149-156
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• 2006

Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

• Korean Chemical Engineering Research
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• v.45 no.3
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• pp.209-214
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• 2007

Sr hexaaluminate($Sr_{1-x}La_xMnAl_{11}O_{19-\alpha}$) were prepared by sol-gel method of metal alkoxide with 1-butanol or ethylene glycol as a solvent. The physical properties of prepared hexaaluminates were examined by TG/DTA, XRD and $N_2$ adsorption. When ethylene glycol was used as a solvent, the decomposition reaction and dehydroxylation reaction was observed above $400^{\circ}C$ and the temperature of the formation of a crystal structure of hexaaluminate was also increased resulting in small specific surface area and low catalytic activity of methane compared to Sr-hexaaluminate with 1-butanol.

• 한국연소학회:학술대회논문집
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• 2005.10a
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• pp.64-68
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• 2005

Methane reforming processes to obtain hydrogen were investigated experimentally by using atmospheric plasma source. Among possible reforming processes, such as a $CO_2$ reforming(dry reforming), a partial oxidation (POx), a steam reforming(SR), and a steam reforming with oxygen(SRO or auto-thermal reforming), partial oxidation and the steam reforming with oxygen were considered. We choose a rotating arc plasma as an atmospheric plasma source, since it shows the best performances in our preliminary tests in terms of a methane conversion, a hydrogen production, and a power consumption. Then, the effects of a feeding flow-rate, an electrical power input to a plasma reaction, an $O_2/C$ ratio and a steam to carbon ratio in the case of SRO on the reforming characteristics were observed systematically. As results, at a certain condition almost 100% of methane conversion was obtained and we could achieve the same hydrogen production rate by consuming a half of electrical power which was used by the best results for other researchers.

• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.177-184
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• 2003

Stabilization mechanism of lifted flame in the near field of coflow jets has been investigated experimentally and numerically for methane fuel diluted with nitrogen. Lifted flames were observed only in the near field of coflow jets until blowout occurred in the normal gravity condition. To elucidate the stabilization mechanism for the stationary lifted flames in the near field of coflow jets for the diluted methane having the Schmidt number smaller than unity, the behaviors of the stationary lifted flame in microgravity and unsteady propagation phenomena were investigated numerically at various conditions of jet velocity. It has been founded that the buoyancy plays an important role for flame stabilization of lifted flame in normal gravity and the stabilization mechanism is due to the significant variation of the propagation speed of lifted flame edge compared to the local flow velocity at the edge.

• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.195-200
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• 2003

A two-dimensional "twin-jet counterflow" burner has been designed for the better understanding of the stability of turbulent flames. This flow system enables one to systematically investigate various effects on non-premixed flames, including the effects of curvature, negative strain, and non-premixed flame interactions. The objective of this study is comparing characteristics of extinction of non-premixed methane flames with that of non-premixed propane flames investigated previously. The extinction limit of non-premixed methane and propane flames can be extended compare to that for the conventional counterflow non-premixed flame because of the existence of petal shaped flame and have same structure. The hysteresis in transition between the petal shaped flame and the curved two-wing flames could be observed. We could find differences between non-premixed methane flame and non-premixe propane flame such as the position of one wing extinction and the regime of one wing extinction.

• Bulletin of the Korean Chemical Society
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• v.23 no.6
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• pp.799-803
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• 2002

Partial oxidation of methane has been conducted over $CeO_2$and it has been found that $CeO_2$has an extraordinary catalytic activity in the reaction. Its activity was strongly dependent on the $CH_4/CO_2$ ratio. Total combustion was dominant with stoichiometric feed ratio$(CH_4/O_2=$ 2.0) but partial oxidation was achieved between the $CH_4/O_2$ ration of 3.8 4.3 and the period depended upon the feed composition. The proposed raaction mechanism it that oxygen vacancies in raduced deria are supplied with oxygen molecules from the reactant, and then activate adsorbed oxygen, followed by releasing activated axygen species reacting with methane to produce $H_2$ and CO.