• 한국수소및신에너지학회논문집
• /
• 제18권2호
• /
• pp.171-181
• /
• 2007

Blending effects of hydrogen and water vapor on flame structure and NOx emission behavior are numerically studied with detailed chemistry in methane-air counterflow diffusion flames. The composition of fuel is systematically changed from pure methane and pure hydrogen to the blending fuels of methane-hydrogen-water vapor through the molar addition of $H_2O$. Flame structure is changed considerably for hydrogen-blending methane flames and hydrogen-blending methane flames diluted with water vapor in comparison to pure methane flame. These complicated changes of flame structures also affect NOx emission behavior considerably. The changes of thermal NO and Fenimore NO are analyzed for various combinations of the fuel composition. Importantly contributing reaction steps to thermal NO and Fenimore NO are addressed in pure methane, hydrogen-blending methane flames, and hydrogen-blending methane flames diluted with water vapor.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
• /
• pp.73-78
• /
• 2006

The lifted oscillating flame has been studied using experiments of inverse diffusion flames that the air jet injected into a methane background. To find out the characteristics of inverse diffusion flames, fundamentally flame stabilized diagram is investigated with various air and fuel jet velocities. It has five regions - flame extinction, stable attached flame, anchored flame, liftoff flame and blow off region. In inverse diffusion flame, lifted flames were observed near the blow off region. As long as flames lift off, flames oscillate by periods. In this oscillating lifted flame region, the frequency of 1 and under were observed in various air and methane jet velocities. Characteristics of lifted flames are also examined by using the ICCD direct image. And intensity of flame chemiluminescence is very different in rising and falling period from photographs. For the present, it is predicted that the changes of flame structure are related with flame oscillation, but more experiments will be needed to make clear the phenomenon.

• International Journal of Safety
• /
• 제2권1호
• /
• pp.7-11
• /
• 2003

Structure of the counterflow nonpremixed flames were investigated by using Fire Dynamics Simulator(FDS) and OPPDIF to evaluate FDS for simulations of the diffusion flame. FDS, employed a mixture fraction formulation, were applied to the diluted axisymmetric methane-air nonpremixed counterflow flames. Fuel concentration in the mixture of methane and nitrogen was considered as a numerical parameter in the range from 20% to 100% increasing by 10% by volume at the global strain rates of $a_g = 20S^{-l} and 80S^{-1}$ respectively. In all the computations, the gravity was set to zero since OPPDIF is not able to compute the buoyancy effects. It was shown by the axisymmetric simulation of the flames with FDS that increasing fuel concentration increases the flame thickness and decreases the flame radius. The centerline temperature and axial velocity, and the peek flame temperature showed good agreement between the both methods.

• 대한기계학회논문집
• /
• 제19권5호
• /
• pp.1333-1339
• /
• 1995

Recently developed technique of measuring minor species concentration by using the modulation dip in broadband CARS has been applied to the flame structure study of methane/air premixed flames in a counterflow. This method used the modulation dip from the cold band CO Q-branch resonant signal superimposed on the nonresonant background. The measured CO concentration profile in a symmetric and unsymmetric methane/air premixed flames together with the velocity and temperature by using LDV and CARS have been compared with the numerical results adopting detailed chemistry modeling. The results show that there is a satisfactory agreement between the experimental data and numerical results for velocities, temperatures and CO concentrations. And the modulation dip technique of measuring minor species, such as CO is a viable tool for a quantitative measurement in a flame.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
• /
• pp.159-165
• /
• 2003

Self-excited noise generation from laminar flames in thin annular jets of methane/air premixture has been investigated experimentally. Various flames were observed in this flow configuration, including conical shape flames, ring shape flames, steady crown shape flames, and oscillating crown shape flames. Self-excited noise with the total sound pressure level of about 70dB was generated from the oscillating crown shape flames for the equivalence ratio larger than 0.95. Sound pressure and $CH^{\ast}$ chemiluminescence were measured by using a microphone and a photomultiplier tube. The frequency of generated noise was measured as functions of equivalence ratio and premixture velocity. A frequency doubling phenomena have also been observed. The measured $CH^{\ast}$ chemiluminescence data were analyzed from which the corresponding sound pressure has been calculated. By comparing the data with those of measured ones, the noise source can be attributed to the flame front fluctuation near the edge of the oscillating crown-shape flames. The flame stability regime was influenced sensitively to the supplying air through the inner tube.

• 한국안전학회지
• /
• 제19권1호
• /
• pp.124-130
• /
• 2004

수치법을 검증하고 번형률과 연료농도가 무중력 확산화염 구조에 미치는 영향을 파악하기 위해, 무중력에서의 비예혼합 메탄-공기 대향류 화염의 구조를 FDS의 축대칭 모사로 조사하였다. 연료 중의 메탄 몰분율 $X_m$=20, 50, 80%와 각각의 몰분율에서 변형률 $a_g$=20, 50, $90s^{-1}$의 계산결과를 1차원 화염코드인 OPPDIF의 결과와 비교하였다. 축대칭 모사로 계산한 온도와 축방향 유속의 분포가 1차원 모사 결과와 잘 일치하였다. 화염의 두께와 위치, 정체점을 잘 예측함으로써 FDS를 넓은 범위의 변형률과 연료농도의 대향류 화염에 적응할 수 있음을 확인하였다.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
• /
• pp.83-86
• /
• 2015

The Laminar lifted methane jet flames diluted with helium and nitrogen in co-flow air have been investigated experimentally. The chemiluminescence intensities of $OH^{\ast}$ and $CH_2O^{\ast}$ radicals and the radius of curvature for tri-brachial flame were measured using an intensified charge coupled device (ICCD) camera, monochromator and digital video camera. The product of $OH^{\ast}$ and $CH_2O^{\ast}$ is used as a excellent proxy of heat release rate. These methane jet flames could be lifted in buoyancy and jet dominated regimes despite the Schmidt number less than unity. Lifted flames were stabilized due to buoyancy induced convection in buoyancy-dominated regime. It was confirmed that increased $OH^{\ast}$ and $CH_2O^{\ast}$ concentration caused an increase of edge flame speed via enhanced chemical reaction in buoyancy dominated regime. In jet momentum dominated regime lifted flames were observed even for nozzle exit velocities much higher than stoichiometric laminar flame speed. An increase in radius of curvature in addition to the increased $OH^{\ast}$ and $CH_2O^{\ast}$ concentration stabilizes such lifted flames.

• 대한기계학회논문집B
• /
• 제31권4호
• /
• pp.384-391
• /
• 2007

Hydrogen-blending effects in flame structure and NO emission behavior are numerically studied with detailed chemistry in methane-air counterflow diffusion flames. The composition of fuel is systematically changed from pure methane to the blending fuel of methane-hydrogen through $H_2$ molar addition up to 30%. Flame structure, which can be described representatively as a fuel consumption layer and a $H_2$-CO consumption layer, is shown to be changed considerably in hydrogen-blending methane flames, compared to pure methane flames. The differences are displayed through maximum flame temperature, the overlap of fuel and oxygen, and the behaviors of the production rates of major species. Hydrogen-blending into hydrocarbon fuel can be a promising technology to reduce both the CO and $CO_2$ emissions supposing that NOx emission should be reduced through some technologies in industrial burners. These drastic changes of flame structure affect NO emission behavior considerably. The changes of thermal NO and prompt NO are also provided according to hydrogen-blending. Importantly contributing reaction steps to prompt NO are addressed in pure methane and hydrogen-blending methane flames.

• 한국가시화정보학회:학술대회논문집
• /
• 한국가시화정보학회 2004년도 Proceedings of 2004 Korea-Japan Joint Seminar on Particle Image Velocimetry
• /
• pp.147-155
• /
• 2004

Self-excited noise generation from laminar flames in thin annular jets of methane/air premixture has been investigated experimentally. Various flames were observed in this flow configuration, including conical shape flames, ring shape flames, steady crown shape flames, and oscillating crown shape flames. Self-excited noise with the total sound pressure level of about 70dB was generated from the oscillating crown shape flames for the equivalence ratio larger than 0.95. Sound pressure and $CH^*$ chemiluminescence were measured by using a microphone and a photomultiplier tube. The frequency of generated noise was measured as functions of equivalence ratio and premixture velocity. A frequency doubling phenomena have also been observed. The flame shape during flame oscillation was reconfirmed by a synchronized PIV experiment. The velocity and pressure field were obtained from PIV. The minimum pressure was formed near the edge of flame representing circulation. By comparing the results of sound pressure, flame luminosity and PIV, the noise source can be attributed to the flame front fluctuation near the edge of the oscillating crown-shape flames.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
• /
• pp.131-138
• /
• 1998

Flame characteristics in a double concentric burner has been studied experimentally. Air is supplied through a central nozzle, methane/air premixture is supplied in a inner annular part, and coflowing shield air is supplied to minimize outside disturbances. Depending on flow rate and concentration, various flame shapes can be observed. As the flow rate difference between central air jet and annular premixed jet is varied, several distinctive flames are observed. Conditions of partially premixed flames are further investigated; nozzle attached rich premixed flame, inner lifted flame, and outer lifted flame. Using the Abel transformation of digitized images of flames, cross- sectional images of flames can be obtained, from which overall structure of flames can be identified. PLIF measurement of OR radical was also conducted. OR radicals were mainly distributed in diffusion flame region. From the difference of OR distribution between nozzle attached and lifted flames, similarity of OR distribution between tribrachial flame and lifted flames in this study are observed.