• Title/Summary/Keyword: Metallic Materials

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Fabrication of Metallic Glass/metallic Glass Composites by Spark Plasma Sintering (방전플라즈마 소결법에 의한 비정질/비정질 복합재의 제조)

  • Lee, Jin-Kyu
    • Journal of Powder Materials
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    • v.14 no.6
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    • pp.405-409
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    • 2007
  • The Cu-based bulk metallic glass (BMG) composites containing Zr-based metallic glass phase have been consolidated by spark plasma sintering using the mixture of Cu-based and Zr-based metallic glass powders in their overlapped supercooled liquid region. The Zr-based metallic glass phases are well distributed homogeneously in the Cu-based metallic glass matrix after consolidation process. The successful consolidation of BMG composites with dual amorphous phases was corresponding to the sound viscous flow of the two kinds of metallic glass powders in their overlapped supercooled liquid region.

Effect of Metallic Binder Composition on Microstructure and Hardness of (W,Ti)C Cemented Carbides ((W,Ti)C계 초경합급의 미세조직 및 경도에 미치는 금속 결합재 조성의 영향)

  • Daoush, Walid M.;Lee, Kyong-H.;Park, Hee-S.;Jang, Jong-J.;Hong, Soon-H.
    • Journal of Powder Materials
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    • v.14 no.3 s.62
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    • pp.208-214
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    • 2007
  • The microstructure and hardness of (W,Ti)C cemented carbides with a different metallic binder composition of Ni and Co fabricated by powder technology were investigated. The densifications of the prepared materials were accomplished by using vacuum sintering at $1450^{\circ}C$. Nearly full dense (W,Ti)C cemented carbides were obtained with a relative density of up to 99.7% with 30 wt.% Co and 99.9% with 30 wt.% Ni as a metallic binder. The average grain size of the (W,Ti)C-Co and the (W,Ti)C-Ni was decreased by increasing the metallic binder content. The hardness of the dense (W,Ti)C-15 wt%Co and (W,Ti)C-15 wt%Ni, was greater than that of the other related cemented carbides; in addition, the cobalt-based cemented carbides had greater hardness values than the nickel-based cemented carbides.

Research for Solder Paste in Metallic Glass System for Thermoelectric Modules (고온열전모듈용 금속유리계 페이스트 연구)

  • Seo, Seung-Ho;Son, Geun Sik;Seo, Kang Hyun;Choi, Soon-Mok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.4
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    • pp.249-254
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    • 2018
  • We researched about a bulk metallic glass system as an additive to an Ag paste for high temperature thermoelectric modules. Bulk metallic glass (BMG) ribbons were produced by using a rapid solidification process (RSP) under a cooling rate condition higher than $10^{\circ}C/sec$. We investigated BMG characteristics of the ribbons by means of x-ray diffraction (XRD) and differential scanning calorimetry (DSC) in order to evaluate the glass transition temperature ($T_g$) and the recrystallization temperature ($T_x$) lower than $400^{\circ}C$. A milling process was also developed to apply the BMG ribbons to a commercial Al paste as an additive for lower sintering temperature.

Interatomic Potential Models for Ionic Systems - An Overview (이온 결합 물질에 대한 원자간 포텐셜 모델)

  • Lee, Byeong-Joo;Lee, Kwang-Ryeol
    • Korean Journal of Metals and Materials
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    • v.49 no.6
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    • pp.425-439
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    • 2011
  • A review of the development history of interatomic potential models for ionic materials was carried out paying attention to the way of future development of an interatomic potential model that can cover ionic, covalent and metallic bonding materials simultaneously. Earlier pair potential models based on fixed point charges with and without considering the electronic polarization effect were found to satisfactorily describe the fundamental physical properties of crystalline oxides (Ti oxides, $SiO_2$, for example) and their polymorphs, However, pair potential models are limited in dealing with pure elements such as Ti or Si. Another limitation of the fixed point charge model is that it cannot describe the charge variation on individual atoms depending on the local atomic environment. Those limitations lead to the development of many-body potential models(EAM or Tersoff), a charge equilibration (Qeq) model, and a combination of a many-body potential model and the Qeq model. EAM+Qeq can be applied to metal oxides, while Tersoff+Qeq can be applied to Si oxides. As a means to describe reactions between Si oxides and metallic elements, the combination of 2NN MEAM that can describe both covalent and metallic elements and the Qeq model is proposed.

Friction Characteristics of automotive friction materials containing different metallic fibers against Al-MMC and cast iron disk specimens (자동차용 마찰재에 사용되는 금속섬유의 종류에 따른 마찰특성의 변화에 관한 연구)

  • Lee, Jin-Soo;Jang, Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1999.06a
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    • pp.255-264
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    • 1999
  • Friction characteristics of automotive friction materials containing different metallic fibers rubbing against Al-MMC and cast iron disk specimens have been studied. Friction materials containing aluminum, copper or low steel carbon fiber were tested. Friction tests were composed of three different phases to investigate the effect of temperature, pressure, speed, and drag time. The results showed that the friction material containing Al fibers has lower friction force and wear amount than the others with Cu or Steel fiber. On the other hand, the wear of friction material was severe in the case of using Al-MMC rotors. These results showed that the thermal decomposition of solid lubricants (and organic components), formation of transfer layer, and SiC particles in the AI-MMC rotor play crucial roles in determining the friction characteristics.

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Influence of Graphite Epoxy Composite Material on the Electrochemical Galvanic Corrosion of Metals (금속재료의 전기화학적 갈바닉 부식에 미치는 GECM의 영향)

  • Yoo, Y.R.;Son, Y.I.;Shim, G.T.;Kwon, Y.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.8 no.1
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    • pp.27-39
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    • 2009
  • Non metallic composite materials, for example, GECM(graphite epoxy composite material) show high specific strength because of low density. These kinds of non metallic composite materials improved the structural effectiveness and operation economics. However, if these materials contacted several metals, corrosion can be arisen since non metallic composite materials have electrical conductivity. This paper dealt with galvanic corrosion between graphite epoxy composite material and several metals. Base on the electrochemical galvanic corrosion test between GECM and metals, corrosion current of carbon steel and aluminium increased with time but corrosion current of stainless steels and titanium decreased and galvanic potential increased. This behavior shows the galvanic corrosion depends upon the presence of passive film. Also, galvanic effect of GECM coupled with ferrous alloys and non-ferrous alloys was lower than that of 100% graphite, which is attributed to lower exposed area of graphite fiber in the GECM than apparent area of the GECM specimen used for the calculation of galvanic current in this work.

A NOTE ON NEW METALLIC BONDING ORBITAL

  • Oh, Hung-Kuk
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1994.11a
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    • pp.156-162
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    • 1994
  • The existence of the elastic anisotropic channeling is based on the experimental evidences. The rotating electron pairs orbits play the role of basic bonding orbitals. The abnormal signals from ligand domain and train-membrane in cancer cell, Deformation in fatigue and creep at low stress, con duction, superconduction and semiconduction are all from the new metallic bonding orbital.

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The Failure Analysis of Double Pipe for Insulation Used Power Plant by Grooving Corrosion (발전소용 이중보온용 강관의 홈부식(Grooving Corrosion)에 의한 파손 분석)

  • Ham, Jong-Oh;Park, Ki-Duck;Park, Sung-Jin;Sun, Il-Sik
    • Journal of Applied Reliability
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    • v.15 no.3
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    • pp.197-206
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    • 2015
  • Failure analysis of pre-insulated pipe (SPPS 380, 400A) transporting high temperature water ($95{\sim}110^{\circ}C$) for a plant was carried out. The damaged area (${\Phi}5mm$) of pre-insulated pipe was found only on welds. The chemical composition of damaged pipe meets specification of carbon steel pipes for pressure service (KS D 3562). As results of microstructure analysis, crack propagated from outer to inside after pitting corrosion occurred on the outside surface. The non-metallic inclusion existed on the end of crack. And the non-metallic inclusion continuously and linearly formed along with the bond line of welds. Based on SEM-EDS analysis, the nonmetallic inclusions have higher Manganese (Mn) and Oxygen (O) content but sulfur (S) was not detected. As results of water quality analysis, hydrogen ion concentration and minerals like Fe, Mg, Si were in low level. But the content of dissolved oxygen (11.2 ppm) was slightly higher than that of standard. It seems that the cause of damaged pipe is grooving corrosion due to MnO inclusion formed on bond line and corrosion took place nearby welds.

Recovery of Metallic Lithium by Room-Temperature Electrolysis: I. Effect of Electrode Materials (상온(常溫) 전해법(電解法)에 의한 리튬 금속(金屬)의 회수(回收): I. 전극물질(電極物質)의 영향(影響))

  • Lee, Jae-O;Park, Jesik;Lee, Churl Kyoung
    • Resources Recycling
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    • v.21 no.6
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    • pp.45-50
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    • 2012
  • The room-temperature electrodeposition of metallic lithium was investigated from ionic liquid, 1-methyl-1-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13TFSI) with lithium bis (trifluoromethanesulfonyl)imide (LiTFSI) as a lithium source. Cyclic voltammograms on gold working electrode showed the possibility of the electrodeposition of metallic lithium, and the reduction current on a gold electrode was higher than the value on platinum and copper. The metallic lithium could be electrodeposited on the gold electrode under potentiostatic condition at -2.4 V (vs. Pt-QRE) and was confirmed by analytical techniques including XRD and SEM-EDS. The dendrite-typed electrodeposits were composed of a metallic lithium and a alloy with gold substrate. And any impurity could be detected except for trace oxygen introduced during handling for the analyses.