• 제목/요약/키워드: Metal-Loading

검색결과 553건 처리시간 0.025초

금속산화물을 이용한 이산화황과 산화질소의 동시재거( II ) -금속산화물과 이산화황의 반응- (Simultaneous Removal of SO$_2$ and NO by Using Metal Oxide( II ) -Oxidative Sorption of SO$_2$ by Metal Oxide-)

  • 신창섭
    • 한국안전학회지
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    • 제6권4호
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    • pp.26-33
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    • 1991
  • To remove SO$_2$ from flus gas, cupric oxide, manganese oxide and iron oxide were studied with varying loading value. The experiment was carried out in a flow reactor and the reactants were prepared by impregnation method using alumina. The reaction temperature was varied from 30$0^{\circ}C$ to 45$0^{\circ}C$. Experimental results showed that all of these metal oxides were effective on SO$_2$ removal reaction and cupric oxide was the best reactant. The sample with 10wt% loading value was better reactant than with 20wt% because in case of 20wt% loading, metal dispersion on the alumina surface was not uniform. And the SO$_2$ removal efficiency was increased with the reaction temperature.

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지르코니아 단일구조 전부도재관과 금속도재관의 파절강도 비교 (FRACTURE STRENGTH OF ZIRCONIA MONOLITHIC CROWNS AND METAL-CERAMIC CROWNS AFTER CYCLIC LOADING AND THERMOCYCLING)

  • 이상민;정희찬;전영찬
    • 대한치과보철학회지
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    • 제45권1호
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    • pp.12-20
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    • 2007
  • Purpose: The purpose of this study was to compare the fracture strength of the zirconia monolithic all-ceramic crowns according to the thickness (0.5mm, 0.8mm, 1.1mm) and metal-ceramic crowns (1.0mm, 1.5mm) Material and method: Twelve crowns for each of 3 zirconia crown groups were fabricated using CAD/CAM system (Kavo, Germany) and twelve crowns for each of 2 metal-ceramic crown groups were made by the conventional method. All crowns were luted to the metal dies using resin cement. Half of the specimens were exposed to thermocycling ($5-55^{\circ}C$, 1 Hz) and cyclic loading (300,000 cycles, 50N). Subsequently, all crowns were mounted on the testing jig in a universal testing machine. The load was directed at the center of crown with perpendicular to the long axis of each specimen until catastrophic failure occurred. Analysis of variance and Tukey multiple comparison test (P<.05) were used for statistical analysis of all groups, and paired t-test (P<.05) was followed for statistical comparison between each groups' fracture load before and after cyclic loading. Results: 1. The fracture strength of the zirconia monolithic crowns and the metal-ceramic crown increased as thickness increased (P<.05). 2. The cyclic loading and thermocycling significantly decreased the fracture strength of the zirconia monolithic crowns (P<.05). 3. The standard deviation of fracture strength of the zirconia monolithic crowns was very low. Conclusion: The fracture strength of the zirconia monolithic crowns for the posterior area tends to be higher with thickness increased and 0.8mm or over in thickness is recommended to have similar or over the fracture strength of metal-ceramic crowns.

특정용제 Target 형 활성금속첨착 활성탄소섬유의 개발 (Development of Metal Loaded Activated Carbon Fiber for Eliminating Targeted VOCs Originated from Solvent)

  • 최강용;김광수;김태원;전민기;박해경
    • 대한환경공학회지
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    • 제35권1호
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    • pp.31-37
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    • 2013
  • 기존 흡착제들보다 우수한 흡착성능을 확보하고, 특히 특정한 용제에 대한 흡착성능을 극대화하기 위하여 $1,100m^2/g$의 비표면적을 갖는 활성탄소섬유를 기본흡착제로 적용하였고, 여기에 활성금속을 첨착시켜 흡착성능과 선택성을 제고하고자 하였다. 활성금속은 screening 연구를 수행하여 최종적으로 Cu, Cr을 선정하였으며, 활성금속첨착 활성탄소섬유의 제조변수는 제조온도, 제조시간, 활성금속의 종류이었다. 물성측정 및 흡착반응실험을 통하여 금속을 $100^{\circ}C$에서 5시간 동안 첨착하였을 경우 acetone gas 흡착성능이 가장 높게 나타났으며, 기존 활성탄소섬유보다 2배 이상의 높은 흡착성능을 확인하였다. 한편, 활성금속첨착 활성탄소섬유의 확산 및 흡착에 필요한 최소 접촉시간은 최소한 0.5초 이상은 유지해야 함을 확인할 수 있었다.

Optimal Metal Dose of Alternative Cathode Catalyst Considering Organic Substances in Single Chamber Microbial Fuel Cells

  • Nam, Joo-Youn;Moon, Chungman;Jeong, Emma;Lee, Won-Tae;Shin, Hang-Sik;Kim, Hyun-Woo
    • Environmental Engineering Research
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    • 제18권3호
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    • pp.145-150
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    • 2013
  • Optimal preparation guidelines of a cathode catalyst layer by non-precious metal catalysts were evaluated based on electrochemical performance in single-chamber microbial fuel cells (MFCs). Experiments for catalyst loading rate revealed that iron(II) phthalocyanine (FePc) can be a promising alternative, comparable to platinum (Pt) and cobalt tetramethoxyphenylporphyrin (CoTMPP), including effects of substrate concentration. Results showed that using an optimal FePc loading of $1mg/cm^2$ was equivalent to a Pt loading of $0.35mg/cm^2$ on the basis of maximum power density. Given higher loading rates or substrate concentrations, FePc proved to be a better alternative for Pt than CoTMPP. Under the optimal loading rate, it was further revealed that 40 wt% of FePc to carbon support allowed for the best power generation. These results suggest that proper control of the non-precious metal catalyst layer and substrate concentration are highly interrelated, and reveal how those combinations promote the economic power generation of single-chamber MFCs.

다른 하중속도 조건에서 압입에 의한 벌크 금속유리의 변형거동 (Deformation Behavior of Zr-based Bulk Metallic Glass by Indentation under Different Loading Rate Conditions)

  • 신형섭;장순남
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.42-47
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    • 2004
  • Metallic glasses are amorphous meta-stable solids and are now being processed in bulk form suitable for structural applications including impact. Bulk metallic glasses have many unique mechanical properties such as high yield strength and fracture toughness, good corrosion and wear resistance that distinguish them from crystalline metals and alloys. However, only a few studies could be found mentioning the dynamic response and damage of metallic glasses under impact or shock loading. In this study, we employed a small explosive detonator for the dynamic indentation on a Zr-based bulk amorphous metal in order to evaluate the damage behavior of bulk amorphous metal under impact loading. These results were compared with those of spherical indentation under quasi-static and impact loading. The interface bonded specimens were adopted to observe the appearances of subsurface damage induced during indentation under different loading conditions.

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특정용제 Target 형 활성금속첨착 활성탄소섬유의 개발(II) (Development of Metal Loaded Activated Carbon Fiber for Eliminating Targeted VOCs Originated from Solvent(II))

  • 최강용;김광수;김태원;전민기;박해경
    • 대한환경공학회지
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    • 제35권7호
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    • pp.472-478
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    • 2013
  • 기존 흡착제들보다 우수한 흡착성능을 확보하고, 특히 특정한 용제에 대한 흡착성능을 극대화하기 위하여 활성탄소섬유를 기본흡착제로 적용하였고, 여기에 활성금속을 첨착시켜 흡착성능과 선택성을 제고하고자 하였다. 선행 연구를 통하여 선정된 Cu, Cr을 기본 활성금속으로 하고 여기에 활성보조금속으로서 Pt, Pd를 복합 첨착시킨 활성탄소섬유를 첨착온도 및 시간을 변수로 하여 제조하였다. 복합첨착 활성탄소섬유의 흡착 성능이 단일첨착 활성탄소섬유와 비교하여 향상되었으며, 첨착온도 $100^{\circ}C$, 첨착시간 5시간 조건에서 최상의 흡착 성능을 확인할 수 있었다. Cu-Cr-Pt-Pd 복합첨착 활성탄소섬유가 가장 뛰어난 흡착성능을 보였으며, 기존 활성탄소섬유보다 2배 이상의 높은 흡착성능을 확인하였다. 한편, 활성금속첨착 활성탄소섬유상에의 확산 및 흡착에 필요한 최소 접촉시간은 0.5초 이상은 유지해야 함을 확인 할 수 있었다.

해양구조물용 TMCP강의 피로균열진전거동에 미치는 용접이방성 및 과대하중의 영향 (The effect of the excessive loading and welding anisotropy on the fatigue crack propagation behavior of TMCP steel for offshore structure)

  • 최성대;이종형
    • 한국생산제조학회지
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    • 제9권6호
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    • pp.82-88
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    • 2000
  • The effect of the welding for the offshore structure in the TMCP steel on the fatigue crack propagation rate and crack opening-and-closure behavior was examined. The welding anisotropy of the TMCP steel and crack propagation characteristics of the excessive loading were reviewed. (1) It seemed that a heat which was generated by the welding made a compressive residual stress over the base metal, so fatigue crack propagation rate was placed lower than in case of the base metal. (20 In the base metal, an effect of the anisotropy which has an effect of fatigue crack propagation rate of the excessive load and the constant amplitude laos was not found but in the welding material case, fatigue crack propagation rate of the excessive load in the specimen of the width direction was located in the retard side as compared with a specimen rolling direction. (3) A crack opening ratio of the used TMCP stel in this study was not changed after excessive loading but a retard phenomenon of crack propagation was observed. Consequently, it was thought that all of the retard phenomenon of crack propagation did not only a cause of the crack opening-and-closure phenomenon.

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Effects of Temperature Amplitude and Loading Frequency on Alternating Current - Induced Damage in Cu Thin Films

  • Park Yeung-Bae
    • 마이크로전자및패키징학회지
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    • 제12권2호
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    • pp.135-140
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    • 2005
  • Although it was recently observed that severe fatigue damage was formed in Al or Cu interconnects due to the cyclic temperatures generated by Joule heating of the metal lines by the passage of alternating currents (AC), AC loading frequency effect on the damage evolution characteristics are not known so far. This work focused on the effect of AC loading frequency (100 Hz vs. 10 kHz) on the thermo-mechanical fatigue characteristics by using polycrystalline sputtered Cu lines with temperature cycles with amplitudes from 100 to $300^{\circ}C$. It was consistently observed that higher loading frequency accelerated damaged grain growth and led to earlier failure irrespective of Cu grain sizes. The frequency effect is believed to result from differences in the concentration of defects created by the deformation-induced motion of dislocations to the grain boundaries.

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Experimental and numerical investigation of expanded metal tube absorber under axial impact loading

  • Nouri, M. Damghani;Hatami, H.;Jahromi, A. Ghodsbin
    • Structural Engineering and Mechanics
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    • 제54권6호
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    • pp.1245-1266
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    • 2015
  • In this research, the cylindrical absorber made of expanded metal sheets under impact loading has been examined. Expanded metal sheets due to their low weight, effective collapse mechanism has a high energy absorption capacity. Two types of absorbers with different cells angle were examined. First, the absorber with cell angle ${\alpha}=0$ and then the absorber with angle cell ${\alpha}=90$. Experimental Study is done by drop Hammer device and numerical investigation is done by finite element of ABAQUS software. The output of device is acceleration-time Diagram which is shown by Accelerometer that is located on the picky mass. Also the output of ABAQUS software is shown by force-displacement diagram. In this research, the numerical and experimental study of the collapse type, force-displacement diagrams and effective parameters has been investigated. Similarly, the comparison between numerical and experimental results has been observed that these results are matched well with each other. From the obtained results it was observed that the absorber with cell angle ${\alpha}=0$, have symmetric collapse and had high energy absorption capacity but the absorber with cell angle ${\alpha}=90$, had global buckling and the energy absorption value was not suitable.

Short-term cyclic performance of metal-plate-connected wood truss joints

  • Gupta, Rakesh;Miller, Thomas H.;Freilinger, Shawn M. Wicks
    • Structural Engineering and Mechanics
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    • 제17권5호
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    • pp.627-639
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    • 2004
  • The objective of this research was to evaluate the performance of metal-plate-connected truss joints subjected to cyclic loading conditions that simulated seismic events in the lives of the joints. We also investigated the duration of load factor for these joints. We tested tension splice joints and heel joints from a standard 9.2-m Fink truss constructed from $38-{\times}89-mm$ Douglas-fir lumber: 10 tension splice joints for static condition and for each of 6 cyclic loading conditions (70 joints total) and 10 heel joints for static condition and for each of 3 cyclic loading conditions (40 joints total). We evaluated results by comparing the strengths of the control group (static) with those of the cyclic loading groups. None of the cyclic loading conditions showed any strength degradation; however, there was significant stiffness degradation for both types of joint. The results of this research show that the current duration of load factor of 1.6 for earthquake loading is adequate for these joints.