• Advances in materials Research
• /
• v.5 no.1
• /
• pp.35-53
• /
• 2016

Flexural bending analysis of perfect and imperfect functionally graded materials plates under hygro-thermo-mechanical loading are investigated in this present paper. Due to technical problems during FGM fabrication, porosities and micro-voids can be created inside FGM samples which may lead to the reduction in density and strength of materials. In this investigation, the FGM plates are assumed to have even and uneven distributions of porosities over the plate cross-section. The modified rule of mixture is used to approximate material properties of the FGM plates including the porosity volume fraction. In order the elastic coefficients, thermal coefficient and moisture expansion coefficient of the plate are assumed to be graded in the thickness direction. The elastic foundation is modeled as two-parameter Pasternak foundation. The equilibrium equations are given and a number of examples are solved to illustrate bending response of Metal-Ceramic plates subjected to hygro-thermo-mechanical effects and resting on elastic foundations. The influences played by many parameters are investigated.

• 한국신재생에너지학회:학술대회논문집
• /
• 2008.05a
• /
• pp.560-563
• /
• 2008

A modified polyol process is developed to enhance Pt loading during the preparation of Pt/C catalysts. With the help of the zeta potential, the effect of pH on the electrostatic forces between the support and the Pt colloid is investigated. It is shown experimentally that the surface charge on the carbon support becomes more electropositive when the solution pH is changed from alkaline to acidic. However, this change does not affect the electronegative surface charge of Pt colloids already attained and stabilized by glycolate anions. This new behavior caused by the change in the solution pH accounts for the enhanced yield of the process and does not affect the Pt particle size. All our experimental results reveal that this simple modification is a cost effective method for the synthesis of highly Pt loaded Pt/C catalysts for fuel cells.

• Tribology and Lubricants
• /
• v.12 no.4
• /
• pp.52-59
• /
• 1996

The results of the electrical contact conductivity of multi-contact spots accounting the surface roughness and the non-conductive films of different origins such as air, water, cutting oil, and machining oil are presented. The array of metal spheres compressed between two flat plates has been used for simulation of the contact behavior of multiple contact of solids, under normal loading. Measurement of electrical contact resistance has been made using the equipment providing the adequate accuracy in the range of micro Ohms. The data on electrical contact resistance have been compared with theoretical predictions using the multiple contact model of constriction resistance. The effect of single spot number and array on conductivity of contact has been evaluated. The results of the experiments show that the contact resistance are closely related to the number of loading cycles, form of surface roughness, and presence of non-conductive films that reduce the size of the real electrical contact spots.

• Computers and Concrete
• /
• v.18 no.3
• /
• pp.389-404
• /
• 2016

In this study, effects of impact loads on reinforced concrete (RC) plates are examined analytically. During examination of RC plates, they were exposed to impact loading with two different support conditions in three different sizes. RC plates in different support conditions were analyzed with Concrete Damage Plasticity Model (CDP) and reinforcing steel was modeled with Classical Metal Plasticity Model (CMP) by ABAQUS finite element software. After the analysis it is found that impact loads, displacements, energy absorption capacities and damage patterns are changed due to support conditions and plate sizes. Results that are obtained from RC plate experiments in literature under impact loads are found to be similar with the results of numerical analysis with CDP material models.

• Journal of the Korean Society of Manufacturing Process Engineers
• /
• v.17 no.4
• /
• pp.64-69
• /
• 2018

This paper investigates the compressive deformation behavior of direct metal tooling (DMT), processing titanium alloy (Ti-6Al-4V) parts under high strain loading conditions. Split Hopkinson Pressure Bar (SHPB) experiments were performed to determine the flow stress and the coefficients of the Johnson-Cook model. This model is described as a function of strain, strain rate, and temperature. SHPB experiments were performed to characterize the deformation behavior of specimens made with 3D printers, using Ti-6Al-4V material under high temperature and dynamic loading.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.1
• /
• pp.100-103
• /
• 2010

In this study, NO reduction behaviors of copper-loaded mesoporous molecular sieves (Cu/MCM-41) have been investigated. The Cu loading on MCM-41 surfaces was accomplished by a chemical reduction method with different Cu contents (5, 10, 20, and 40%). $N_2/77$ K adsorption isotherm characteristics, including the specific surface area and pore volume, were studied by BET's equation. NO reduction behaviors were confirmed by a gas chromatography. From the experimental results, the Cu loading amount on MCM-41 led to the increase of NO reduction efficiency in spite of decreasing the specific surface area of catalysts. This result indicates that highly ordered porous structure in the MCM-41 and the presence of active metal particles lead the synergistical NO reduction reactions due to the increase in adsorption energy of MCM-41 surfaces by the Cu particles.

• Korean Journal of Materials Research
• /
• v.15 no.1
• /
• pp.1-5
• /
• 2005

Copper-based leadframe sheets were immersed in two kinds of hot alkaline solutions to form brown-oxide or black-oxide layer on the surface. The oxide-coated leadframe sheets were molded with epoxy molding compound (EMC). After post mold curing, the oxide-coated EMC-leadframe joints were machined to form sandwiched double-cantilever beam (SDCB) specimens. The SDCB specimens were used to measure the fracture toughness of the EMC/leadframe interfaces under quasi-Mode I loading conditions. Fracture surfaces were analyzed by various equipment to investigate failure path. The present paper deals with the failure path, and the cause of the failure path formation with an adhesion model will be treated in the succeeding paper.

• Korean Journal of Materials Research
• /
• v.15 no.1
• /
• pp.6-13
• /
• 2005

Copper based leadframe sheets were immersed in two kinds of hot alkaline solutions to form brown-oxide or blackoxide layer on the surface. The oxide-coated leadframe sheets were molded with epoxy molding compound (EMC). After post mold curing, the oxide-coated EMC-leadframe joints were machined to form sandwiched double-cantilever beam (SDCB) specimens. The SDCB specimens were used to measure the fracture toughness of the EMC/leadframe interfaces under quasi-Mode I loading conditions. After fracture toughness testing, the fracture surface were analyzed by various equipment to investigate failure path. An adhesion model was suggested to explain the failure path formation. The adhesion model is based on the strengthening mechanism of fiber-reinforced composite. The present paper deals with the introduction of the adhesion model. The explanation of the failure path with the proposed adhesion model was introduced in the companion paper.

• Nuclear Engineering and Technology
• /
• v.53 no.5
• /
• pp.1642-1651
• /
• 2021

In this study, isophtalic neopentyl glycol polyester (NPG-PES) based composites with different loading ratios of pure tungsten metal (W), tungsten (VI) oxide (WO₃), tungsten boron (WB) and tungsten carbide (WC) composites were prepared as alternative shielding materials for ionizing electromagnetic radiation (IEMR) shielding. Structural characterizations of the composites were done. Gamma spectrometric analysis of composites for 80-2000 keV energy range was performed and their usability as IEMR shielding was discussed. As a result, the produced composites showed a shielding performance of 60-100% of the lead (the most widely used IEMR shielding material) depending on the reinforcement material, reinforcement loading rate and experimental conditions. Thus, it was reported that produced composites could be an alternative to lead shieldings that have several disadvantages as toxic properties, difficulty of processing and inelasticity.

• Applied Chemistry for Engineering
• /
• v.3 no.2
• /
• pp.266-272
• /
• 1992

Azacrownoalkyl phenylphosphinic acids were synthesized and their competitive solvent extraction characteristics from water to chloroform layer were investigated. Phosphinic acids were synthesized in good yields by one step reaction of phenylphosphinate, aldehyde, and monoazacrown ether and then basic hydrolysis of the resulting phosphinate dsters. These complexing agents revealed a wide effective pH range in extraction of alkali metal ions from water to the organic phase and total metal ion loading at pH 11 was about 75%. The selectivity of the cation extraction was determined mainly by the cavity size of the azacrown ethers, showing $Na^+$ >> $K^+$ > $Rb^+$ > $Li^+$ > $Cs^+$ for the alkyl phenylphosphinic acid ${\underline{2}}$, containing monoaza-15-crown-5 and $K^+$ >> $Rb^+$ > $Na^+$ > $Cs^+$ > $Li^+$ for the alkyl phenylphosphinic acid, ${\underline{3}}$, containing monoaza-18-crown-6 moiety. Applicable pH range of these azacrown ether phosphinic acids in solvent extraction of alkali metal cations was wider than a crownether carboxylic acid with similar selectivity, showing considerable amount of metal ion loading in slightly acidic or neutral media.