• Title/Summary/Keyword: Metal correlation

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Magnetostriction of B2-structured FeX (X = Al, Si, Ni, Ga, Ge, and Sn) Alloys: A First-principles Study (B2 구조 FeX(X = Al, Si, Ni, Ga, Ge, Sn) 합금의 자기변형에 대한 제일원리계산)

  • Lee, Sunchul;Odkhuu, Dorj;Kwon, Oryong;Hong, Soon Cheol
    • Journal of the Korean Magnetics Society
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    • v.23 no.4
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    • pp.117-121
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    • 2013
  • In this study we investigated magnetism and magnetostriction of B2-structured FeX (X = Al, Si, Ni, Ga, Ge, and Sn) using a first-principles method, in order to survey the possibility of developing a transition metal based magnetostriction material. The Full-potential Linearized Augmented Plane Wave method was employed for solving the Kohn-Sham equation within the generalized gradient approximation for exchange-correlation interaction between electrons. FeX alloys are stabilized in ferromagnetic states except for the FeSi and FeGe alloys. Magnetostrcition coefficients of FeX (X = Al, Ni, Ga, and Sn) were calculated to be -5, +6, -84, -522ppm, respectively. It is noteworthy that the magnetostriction coefficient (-522ppm) of FeSn is larger than that (+400ppm) of Gafenol.

A Study on Optimum Mixing Ratio of Paper Wastes as Bulking Agent in Cornposting of Swine Feces (돈분의 퇴비화에 있어서 종이류 폐기물의 적정 배합량에 관한 연구)

  • 정문식;박석환;최경호;손현석;김성균;박지영
    • Journal of Environmental Health Sciences
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    • v.22 no.4
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    • pp.82-90
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    • 1996
  • This study was performed to find the optimum mixing ratio of paper waste in composting of mixture of swine feces and newspaper. Using the experimental setting of aeration rate which was found in the experiment carried out priorly, and moisture contents reported in other literature, just the initial C:N ratios were differentiated by mixing different amount of newspaper with the same amount of swine feces. This study was carried out by operating 4 experimental cornposting reactors of bench scale for 3 weeks. The followings are the conclusions that were derived from this study. 1. During composting reaction, the C:N ratio of each cornposter was decreased. Degree of decrease was in order of run 3, run 2, run 4, and run 1 of which initial C:N ratio was 30, 25, 35, and 20 respectively. All of the final composts were found to be completed composting reaction. 2. Ash contents of each reactor increased rapidly in order of run 3, run 2, run 4, and run 1. The absolute values of quadratic effect coefficients of each second order regression function was 0.059, 0.038, 0.032, and 0.030 respectively. Ash contents evolution trend had a linear correlation with the C:N ratio trend. (r=-0.96932, p<0.05) 3. The range of highest temperatures reached during composting was 47.2-53.5$\circ$C. Those were not significantly different from one another. Thermophilic temperatures were maintained in the range of 48-108 hours. 4. Contents of heavy metal detected in the final compost were lower than those of Korean and European standards. 5. Concentration range of Nitrogen in the final compost was 1.11-2.27%, and that of phosphorus was 8.40-10.70 mg/kg. 6. The optimum C:N ratio which has been proposed without the consideration of types of bulking agents should be re-examined. Biodegradabilities of each bulking agents was thought to be important factor when determining the optimum initial C:N ratio for cornposting.

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Studies on the Geological Environment of the Nanjido Waste Disposal Site: Gravity and Magnetic Investigations (난지도 매립지 및 그 주변의 지질환경 연구: 중력 및 자력탐사)

  • Kwon, Byung-Doo;Kim, Cha-Seop;Chung, Ho-Joon;Oh, Seok-Hoon
    • Economic and Environmental Geology
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    • v.28 no.5
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    • pp.469-480
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    • 1995
  • Gravity and magnetic surveys were carried out to investigate the three-dimensional configuration and characteristics of the landfills at Nanjido waste disposal site. For terrain correction and three-dimensional density inversion of gravity data an algorithm, which calculates the gravity effect of a three-dimensional body by using the solid angle method, is developed. This algorithm has been proved to give more accurate terrain correction values for the small survey area having varied topography like Nanjido site as compared with widely used methods such as Hammer's method and multiquadric equation method. Density inversion of gravity anomaly data gives very useful information about the lateral and vertical variation of the landfills, which can be used to discriminate the kinds of wastes. The average density of filled materials appears to be $1.7\;g/cm^3$ which is much higher than the value $(0.8\;g/cm^3)$ estimated by Seoul City. The lateral variation of density shows high correlation with the pattern of ongoing depression of the landfills. The northern region of the landfill no. 1, which shows low density and high depression, is closely associated with the industrial waste and sludge filled area. The magnetic anomaly data provide information about relative concentration of magnetic materials, which is also very useful to investigate characteristics of the fills. Several high positive anomaly regions on the reduced-to-pole magnetic anomaly map are appeared to be associated with the industrial waste fills, but certain industrial waste fills show low negative anomalies. This kind of magnetic information can be used in selecting drilling locations over landfills away from buried metal products during the stabilization process.

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Dispersion, Speciation and Adsorption Treatment of Heavy Metals in the Vicinity of the Shi-Heung Cu-Pb-Zn Mine (시흥 Cu-Pb-Zn 광산 주변에서의 중금속원소들의 분산 및 존재형태와 흡착처리)

  • Hwang, Ho Song;Chon, Hyo Taek
    • Economic and Environmental Geology
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    • v.28 no.5
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    • pp.455-467
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    • 1995
  • In order to investigate the dispersion patterns and speciations of Cu, Pb, Zn and Cd in soils, stream sediments and stream waters, geochemical studies of soil, stream sediment and stream water samples collected in the vicinity of the Shi-Heung Cu-Pb-Zn mine was carried out Cation exchange capacity measurement, size analysis, X-ray diffraction analysis and batch test were performed to select applicable soil for adsorption treatment The average content of Cu, Pb, Zn and Cd in soils collected from tailings and ore dressing plant is 1084 ppm, 2292 ppm, 3512 ppm and 29.2 ppm, respectively, and therefore, tailings and ore dressing plant site may be the major contamination sources in this study area. The mean content of Cu, Pb, Zn and Cd in stream sediments is extremely high up to 794 ppm, 1633 ppm, 2946 ppm and 25.2 ppm, respectively. Tailing particles and heavy metal ions are dispersed along the tributary system. Results from the sequential extraction analysis indicate; (1) most of Cu is bound to organic matters and sulphides, (2) fraction of Pb is mainly bound to Fe and Mn oxides. Most of Zn is largely bound to Fe and Mn oxides and residual fraction. Ion exchangeable fraction of Cd is relatively higher than those of Cu, Pb and Zn. Batch test on soils collected from the kaolinite and/or pyrophyllite mines and from the control areas was carried out to select an applicable soil samples for adsorption treatment The sample, S10, collected from the control area 2 (clay content 33.2%) shows the highest $K_d$ (distribution coefficient). Organic content in soils and several clay minerals shows relatively good correlation with $K_d$. It means that applicable soils for adsorption treatment of heavy metals show high organic and clay content.

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Analysis of the Anionic Surfactants by Capillary Electrophoresis (모세관 전기영동 장치를 이용한 음이온계 계면활성제의 분석)

  • Jeong, Hyuk;Kim, Seung Sun;Lee, Byung Min;Kang, Ho-Cheol;Lee, Won;Kim, Hai-Dong
    • Analytical Science and Technology
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    • v.7 no.4
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    • pp.435-440
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    • 1994
  • Qualitative and quantitative analysis for the anionic surfactants used in the metal washing fluid (brand names are BFA and BCA) was performed by the capillary electrophoresis. Acetonitrile and sodium benzoate were mixed with the buffer solution which controlled at pH 10. Under the 18kV applied voltage, the electropherograms have shown the theoretical plates more than $10^4$. Determined as the concentration at the S/N~3, the typical detection limit was ~5 ppm and the calibration curves have shown the correlation coefficients higher than ~0.99. Based on these results, it was concluded that each components were octanoate, decanoate, dodecanoate, tetradecanoate, hexadecanoate and the relative ratio was 1.0 : 1.0 : 6.5 : 2.1 : 0.8 for the BFA.

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A study on selective hybrid-structure film fabricated by 355nm UV-pulsed laser processing (355nm UV 레이저를 이용한 선택적 하이브리드 구조 필름의 제작에 관한 연구)

  • Kim, Myung-Ju;Lee, Sang-Jun;Shin, Bo-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.5
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    • pp.2979-2984
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    • 2015
  • This paper has presented a new foaming technology of selective hybrid-structured polymer film with expanded pores. The porous structure of closed pore was firstly fabricated by applying the 355nm UV-pulsed laser to 0.1mm thick film that was uniformly mixed with PP pellets, copper powder, and CBA (Chemical Blowing Agent). In order to expand pore size of closed-cell shape, LAMO(Laser Aided Micro pore Opening) processing was conducted to heat the copper powder, and then the bigger pore size of closed-cell more than existing pore size was successfully formed because of rapid conduction of heated metal powder. From the experimental results, various process parameters such as laser fluence, intensity, scan rate, spot size and density of powder and CBA were considerably considered to reveal the correlation among the pore characteristics. In the future, a function experiment will be carried out to use the hybrid film of industrial applications.

Studies of Methane Oxidation Catalyst on H2-CNG Mixed Fuel Vehicles (수소-CNG 혼소연료 차량에서의 메탄 저감을 위한 산화촉매에 관한 연구)

  • Lee, Ung-Jae;Shim, Kyung-Sil;Yang, Jaechun;Kim, Tae-Min
    • Journal of the Korean Institute of Gas
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    • v.17 no.5
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    • pp.22-27
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    • 2013
  • HCNG engine is performed as a future engine because of high combustion efficiency and eco-friendly property, and is predicted to a brdge of hydrogen vehicles. As EURO-6 regulagion is due to be applied in 2014, consolidated regulations of methane gas that is exhausted from CNG and HCNG vehicles will come into effect. In this studies, methane oxidation catalyst is introduced to remove methane gas from HCNG emissions. Methane oxidation efficiency on catalyst was studied when it is driven long time. And characterization like metal dispersion, surface area was performed to investigate the correlation of catalyst efficiency and characteristics.

Theoretical Investigation of Water Adsorption Chemistry of CeO2(111) Surfaces by Density Functional Theory (전자밀도함수이론을 이용한 세륨 산화물의 (111) 표면에서 일어나는 물 흡착 과정 분석)

  • Choi, Hyuk;Kang, Eunji;Kim, Hyun You
    • Korean Journal of Materials Research
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    • v.30 no.5
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    • pp.267-271
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    • 2020
  • Cerium oxide (ceria, CeO2) is one of the most wide-spread oxide supporting materials for the precious metal nanoparticle class of heterogeneous catalysts. Because ceria can store and release oxygen ions, it is an essential catalytic component for various oxidation reactions such as CO oxidation (2CO + O2 2CO2). Moreover, reduced ceria is known to be reactive for water activation, which is a critical step for activation of water-gas shift reaction (CO + H2O → H2 + CO2). Here, we apply van der Waals-corrected density functional theory (DFT) calculations combined with U correction to study the mechanism of water chemisorption on CeO2(111) surfaces. A stoichiometric CeO2(111) and a defected CeO2(111) surface showed different water adsorption chemistry, suggesting that defected CeO2 surfaces with oxygen vacancies are responsible for water binding and activation. An appropriate level of water-ceria chemisorption energy is deduced by vdW-corrected non-local correlation coupled with the optB86b exchange functional, whereas the conventional PBE functional describes weaker water-ceria interactions, which are insufficient to stabilize (chemisorb) water on the ceria surfaces.

CONCEPTUAL DESIGN OF THE SODIUM-COOLED FAST REACTOR KALIMER-600

  • Hahn, Do-Hee;Kim, Yeong-Il;Lee, Chan-Bock;Kim, Seong-O;Lee, Jae-Han;Lee, Yong-Bum;Kim, Byung-Ho;Jeong, Hae-Yong
    • Nuclear Engineering and Technology
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    • v.39 no.3
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    • pp.193-206
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    • 2007
  • The Korea Atomic Energy Research Institute has developed an advanced fast reactor concept, KALIMER-600, which satisfies the Generation IV reactor design goals of sustainability, economics, safety, and proliferation resistance. The concept enables an efficient utilization of uranium resources and a reduction of the radioactive waste. The core design has been developed with a strong emphasis on proliferation resistance by adopting a single enrichment fuel without blanket assemblies. In addition, a passive residual heat removal system, shortened intermediate heat-transport system piping and seismic isolation have been realized in the reactor system design as enhancements to its safety and economics. The inherent safety characteristics of the KALIMER-600 design have been confirmed by a safety analysis of its bounding events. Research on important thermal-hydraulic phenomena and sensing technologies were performed to support the design study. The integrity of the reactor head against creep fatigue was confirmed using a CFD method, and a model for density-wave instability in a helical-coiled steam generator was developed. Gas entrainment on an agitating pool surface was investigated and an experimental correlation on a critical entrainment condition was obtained. An experimental study on sodium-water reactions was also performed to validate the developed SELPSTA code, which predicts the data accurately. An acoustic leak detection method utilizing a neural network and signal processing units were developed and applied successfully for the detection of a signal up to a noise level of -20 dB. Waveguide sensor visualization technology is being developed to inspect the reactor internals and fuel subassemblies. These research and developmental efforts contribute significantly to enhance the safety, economics, and efficiency of the KALIMER-600 design concept.

Hair Heavy Metal Contents in Mentally Retarded Children IV - In Association with Copper - (정신지체아 두발 중 중금속 함량 IV - 구리와의 관련성 -)

  • Kim, Doo-Hie;Nam, Sang-Soong;Park, Soon-Woo
    • Journal of Preventive Medicine and Public Health
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    • v.22 no.4 s.28
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    • pp.518-527
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    • 1989
  • The relationship between copper content in scalp hair and mental retardation was investigated. Samples of scalp hair were collected from 297 mentally retarded children who were students in one of two schools providing special educational services, one, consisted of children living in an orphan home, the other, children living with parents. For comparison, 117 scalp hair samples were collected from the children who had got average or above average academic achivement in a regular elementary school. Hair samples were taken from the nape of the neck and the copper content was determined by an atomic absorption spectrophotometer (IL 551). There was no statistically significant difference in scalp copper levels across different age groups except female orphan group, but no trend or correlation between copper conents and age was found. The hair copper contents of the mentally retarded children groups were significantly lower than that of control groups. But there was no dose-response relationship between degree of mental retardation and hair copper level. The hair copper contents of the group accompanied by Down's syndrome and unknown group were significantly lower than that of control group in both sex, and in the case of accompanied by epilepsy or autism, lower than control group in male. Although the results of this study show no evidence that mental retardation has owed to copper deficiency, the possibility of copper deficiciency in their fetal or infant age could not be ruled out. Thus further study is needed to determine whether mental retardation could be attributed to copper deficiency, through the examinations about their living environments, dietary pattern, eating habit and the impact of copper deficiency on brain development.

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