• 제목/요약/키워드: Metal contamination

검색결과 693건 처리시간 0.028초

부산 사하구지역 지하수의 수질 연구 (A Study on the Quality of Groundwater in Sahagu, Busan, Korea)

  • 임현철
    • 지구물리
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    • 제7권3호
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    • pp.217-224
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    • 2004
  • 20 groundwater samples in Sahagu Busan were analyzed to understand the characteristics of groundwater quality of the area. Using the data, physical and chemical property, mineral contents, water-rock reaction of the groundwater carried out. The water type in the area is Ca2+-HCO3- and Ca2+-(Cl-+SO42-). Average EC value of the groundwater is 540μS/cm, but in the case of several samples influenced by eawater, the value is up to 4,140μS/cm. Some samples are exceeding the drinking water tandard in NO3-N and NH4-N. On the other hand, contamination by heavy metal is not found.

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지구 통계학적 방법에 의한 충남 탄전 지역 하상퇴적물의 미량원소 오염조사 (Investigation of trace element contamination in steam sediments in the Chungnam coal mine area using geostatistical approach)

  • 황춘길
    • 자원환경지질
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    • 제32권1호
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    • pp.63-72
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    • 1999
  • In order to examine the contamination levels of trace elements in stream sediments in the Chungnam coal mine area, stream sediment and water samples were collected and analyzed for trace elements. The pH of stream water was neutral or weak-alkaline and the mobility of metal in stream sediments was supposed to be low. From the result of cluster analysis, non-polluted sampling stations can be distinguished from polluted sampling stations influenced by mining activities. The trace element concentrations in sediments from non-polluted zone were considered to be the natural backround concentrations of this area. The trace element concentrations in sediment samples from the mining area were higher than those from non-polluted area, and contaminated area of enriched trace element levels need to be properly managed. From the results of discriminant and regression analyses, concentrations of Cd, Cu, Pb AND zN and predicted values of Be, Mo, and Ni in Chungnam coal mine area were found to be lower than those in metal mining areas in Korea.

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알루미늄 합금의 용접특성 - part I : 균열 및 기공 (Weldability of Al Alloys,Part I ;Cfacking and Porosity)

  • 이창희;장래웅
    • Journal of Welding and Joining
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    • 제10권3호
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    • pp.1-12
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    • 1992
  • A literature review was conducted to survey informations available on the welding metallurgy of aluminum alloys and its effect on fusion weldability, especially on solidification cracking and pore formation. Solidification cracking behavior of Al weld is a complicate matter as compared to other high alloys, where a relatively simple Fe-X(most detrimental elements S, P, B, Si, etc) binary diagram can be successfully applicable. Both additive and synergistic effects of elements should be considered together. A same element play a different role from system to system. Porosity, caused by hydrogen contamination of the weld is one of the most troublesome welding problems. The primary sources of hydrogen are believed to be an absorbed moisture on the filler metal or base metal and in the shielding gas. It is extremely important that reliable quality-control procedures be employed to eliminate all possible sources of hydrogen contamination. Selection of proper process and parameters is sometimes more important than controlling of alloying elements in order to make a defect-free weld.

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실리콘 실험실에 구리 오염을 방지 할 수 있는 고밀도/고균일의 Solder Bump 형성방법 (Fabrication Method of High-density and High-uniformity Solder Bump without Copper Cross-contamination in Si-LSI Laboratory)

  • 김성진;주철원;박성수;백규하;이희태;송민규
    • 마이크로전자및패키징학회지
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    • 제7권4호
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    • pp.23-29
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    • 2000
  • 사용되는 metal구분 없이 반도체 공정장비들을 사용함으로써 cross-contamination을 유발시킬 수 있다. 특히, copper(Cu)는 확산이 쉽게 되어 cross-contamination에 의해 수 ppm정도가 wafer에 오염되더라도 트랜지스터의 leakage current발생 요인으로 작용할 수 있기 때문에 Si-IC성능에 치명적인 영향을 미칠 수 있는데, Si-LSI 실험실에서 할 수 있는 공정과 Si-LSI 실험실을 나와 할 수 있는 공정으로 구분하여 최대한 Si-LSI 장비를 공유함으로써 최소한의 장비로 Cu cross-contamination문제를 해결할 수 있다. 즉, 전기도금을 할 때 전극으로 사용되어지는 TiW/Al sputtering, photoresist (PR) coating, solder bump형성을 위한 via형성까지는 Si-LSI 실험실에서 하고, 독립적인 다른 실험실에서 Cu-seed sputtering, solder 전기도금, 전극 etching, reflow공정을 하면 된다. 두꺼운 PR을 얻기 위하여 PR을 수회 도포(multiple coaling) 하고, 유기산 주석과 유기산 연의 비를 정확히 액 조성함으로서 Sn:Pb의 조성비가 6 : 4인 solder bump를 얻을 수 있었다. solder를 도금하기 전에 저속 도금으로 Cu를 도금하여, PR 표면의 Cu/Ti seed층을 via와 PR표면과의 저항 차를 이용하여 PR표면의 Cu-seed를 Cu도금 중에 etching 시킬 수 있다. 이러한 현상을 이용하여 선택적으로 via만 Cu를 도금하고 Ti층을 etching한 후, solder를 도금함으로써 저 비용으로 folder bump 높이가 60 $\mu\textrm{m}$ 이상 높고, 고 균일/고 밀도의 solder bump를 형성시킬 수 있었다.

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폐금속 광산지역 비소 및 중금속 오염에 대한 인체위해성평가 및 복원농도 설정 (Human Risk Assessment of Arsenic and Heavy Metal Contamination and Estimation of Remediation Concentration within Abandoned Metal Mine Area)

  • 이상우;김정진;박미정;이상환;김순오
    • 한국광물학회지
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    • 제28권4호
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    • pp.309-323
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    • 2015
  • 본 연구에서는 폐금속 광산에 특화된 인체위해성평가 방법을 제시하고, 국내 폐금속 광산지역으로부터 도출된 다양한 노출인자 값을 적용하여 폐금속 광산지역의 주민(성인 남자, 성인 여자, 어린이)에 대하여 인체위해성평가를 수행하였다. 또한 인체위해성평가의 결과로부터 중금속 오염에 의한 주민의 건강이 우려되는 경우, 위해성에 기반한 각 매체(토양, 지하수, 지표수)별 복원기준을 제시하고자 하였다. 본 연구 결과, 발암위해도와 비발암위해도를 지시하는 총 초과발암위해도(TCR)와 위험지수(HI)는 지하수섭취와 농작물섭취에 의한 경로로 노출되는 비소에 의해 각각 허용 가능한 수준인 1.00E-6과 1을 크게 초과하는 것으로 나타나서 연구대상 지역의 인체위해성이 큰 것으로 평가되었다. 위해도 저감을 위한 복원농도 산정 결과, 발암위해도 기준 계산 시 As 6.83~6.85 mg/kg, Pb 18.41~18.46 mg/kg, 비발암위해도 기준 계산 시 Cu 17.38 mg/kg, As 9.13 mg/kg의 수준으로 토양정화가 필요한 것으로 나타났다.

여천공단 주변 토양의 중금속함량에 관한 연구 (Heavy Metal Concentrations in the Soil of Yoecheon Industrialized Complex Area)

  • 윤연흠;박돈희;김용웅;조완현;박천영;윤정한
    • 자원환경지질
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    • 제33권5호
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    • pp.379-389
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    • 2000
  • This study was focused on the investigation for the heavy metal contamination of soils derived from Yoecheon Industrial Complex in Chonnam Province. Total 201 soil samples including farmland, paddy, forest and playground soils were collected, extracted by 0.1N HCl and analyzed for Cd, Cu, Cr, Fe, Mn and Zn using AAS. Most pH values in soils were weak acidic ranges of 4-6, while some of them were over 8.0. Concentrations of Cd, Cu, Fe and Zn in the soils tend to be relatively high around the Au-Ag mine area, railroad stations and oil station, however, those of Cr, Mn and Pb show high at the northside of Pohang Steel Co (POSCO). Cadmium-Zn couples, and Cd-Zn and Zn-Cr couples have relatively good correlations in the farmland soils and paddy soils, respectively. Concentrations of Cd, Fe and Zn with depth tend to be higher in the top soils than in the bottom soils, but those of Cu and Pb do not show regular variations with depth.

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광산폐수 속의 중금속의 분석과 특성 (Analysis and Characteristics of Heavy Metals in Mines Waste Water)

  • 이경호
    • 동굴
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    • 제92호
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    • pp.9-18
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    • 2009
  • A number of closed metal mines act as point sources of contamination on nearby streams, soils and plants in our country. The contamination of twelve decomposed samples had earned from nine closed metal mines had been evaluated by TEA-3000. The contents of heavy metal with ion fraction exchange and carbonate fraction forms had been showed that the speciation of heavy metals represented with easy solubility, mobility and bioavailable of plants, and in case of sulfide compounds and organic residuals forms are related with the speciation of metals which may be stable forms because of strong bindable capacity. Also heavy metals elements in mosts of mines got with relative stable within crystal lattice, but results of trace element analyser showed that, in the most of tailings from mine areas, large portions of concentration of heavy metals were explained as stable from, sulfides/ organics and residual. In tailing from Imchun mines, the concentrations extracted by water were relatively high as compared with other mine areas whose total concentrations were very high because of large quantities of exchangeable ions and carbonates and low soil pH. Danger Index (D.I.) suggested in this study was based on the cumulative concentrations of step 1 and 2 from the result of trace element analyser. When the soil pH was considered, this index became better indicator to determine the priority for the remediation of mine area.

방사성오염 금속폐기물의 재활용 연구 (A Study on the Recycling of Radioactively Contaminated Metal Waste)

  • 문제권;박상윤;정종헌;이정원;오원진
    • 자원리싸이클링
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    • 제6권3호
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    • pp.22-27
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    • 1997
  • 방사성 금속폐기물을 재활용하므로써 방사성 폐기물의 처분부피를 감축할 수 있을 뿐만 아니라, 자원활용의 극대화를 꾀할 수 있으며, 또한 방사성 폐기물의 감량으로 환경에 미치는 위해도를 최소화시킬 수 있다. 방사성 금속폐기물의 재활용은 여러 단계를 복잡한 공정을 거치면서 이루어지지만, 오염 방사능 물질을 제거하는 표면제염 공정이 핵심이며, 그 오염 특성 및 폐기물에 따라 물리적, 화학적 그리고 전기화학적 방법이 활용된다. 본 연구에서는 이러한 관점에서 표면제염기술의 특성을 고찰하였으며, 실제 방사성 금속폐기물을 이용해 SC 화학제염법 및 전해제염법으로 시험한 결과, 거의 자연 방사능 수준까지 제염시킬 수 있었다.

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