• Title/Summary/Keyword: Metal anode

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Fabrication and Electrochemical Characterization of All Solid State Thin Film Micro-Battery by in-situ sputtering (In-situ 스퍼터링을 이용한 마이크로 박막 전지의 제작 및 전지 특성 평가)

  • 전은정;신영화;남상철;조원일;손봉희;윤영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.159-162
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    • 1999
  • All solid state thin film micro-batteries consisting of lithium metal anode, an amorphous LiPON electrolyte and cathode of vanadium oxide have been fabricated and characterized, which were fabricated with cell structure of Li/LiPON/V$_2$O$\sub$5/Pt. The vanadium oxide thin films were formed by d.c. reactive sputtering on Pt current collector. After deposition of vanadium oxide films, in-situ growths of lithium phosphorus oxynitride film were conducted by r.f. sputtering of Li$_3$PO$_4$ target in mixture gas of N$_2$ and O$_2$. The pure metal lithium film was deposited by thermal evaporation on thin film LiPON electrolyte. The cell capacity was about 45${\mu}$Ah/$\textrm{cm}^2$ $\mu\textrm{m}$ after 200 cycle. No appreciable degradation of the cell capacity could be observed after 50 cycles .

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Surface observation of Ni(OH)2 nanosheets fabricated by electrodeposition method (전착법에 의해 제작된 Ni(OH)2 나노 시트의 표면 관찰 및 분석)

  • Kim, Dong Yeon;Son, Injoon;Choi, Mun-Hyun
    • Journal of Surface Science and Engineering
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    • v.54 no.3
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    • pp.152-157
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    • 2021
  • The pseudocapacitor has a high energy density characteristic because it accumulates charges through a paradic redox reaction. However, due to its strong insulation properties, metal hydroxides should be designed as structural systems optimized for charge transfer to support fast electron transport. Also, Nickel material is weak to heat and is easily deformed when used as a cathode material, so stability must be secured. In this study, nickel hydroxide was produced by electrodeposition to secure the stability of nickel. Electrodeposition is a synthetic method suitable for growing optimized nickel hydroxide because it allows fine control. Nickel hydroxide (Ni(OH)2) is a metal hydroxide used as a pseudocapacitor anode due to its high capacitance, electrical conductivity and resistance. Therefore, in order to determine how Ni(OH)2 nanosheets are formed and what are the optimization conditions, various measurement methods were used to focus on structural growth of nanosheets produced by electrodeposition.

MINERAL PROCESSING and COPPER EXRACTIVE METALLURGY Complete Metal Recovery

  • Kim, J.Y.
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.22-34
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    • 2003
  • Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and Dore furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyre-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

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Transient trap density in thin silicon oxides

  • Kang, C.S.;Kim, D.J.;Byun, M.G.;Kim, Y.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.6
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    • pp.412-417
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    • 2000
  • High electric field stressed trap distributions were investigated in the thin silicon oxide of polycrystalline silicon gate metal oxide semiconductor capacitors. The transient currents associated with the off time of stressed voltage were used to measure the density and distribution of high voltage stress induced traps. The transient currents were due to the discharging of traps generated by high stress voltage in the silicon oxides. The trap distributions were relatively uniform near both cathode and anode interface in polycrystalline silicon gate metal oxide semiconductor devices. The stress generated trap distributions were relatively uniform the order of $10^{11}$~$10^{12}$ [states/eV/$\textrm{cm}^2$] after a stress. The trap densities at the oxide silicon interface after high stress voltages were in the $10^{10}$~$10^{13}$ [states/eV/$\textrm{cm}^2$]. It was appeared that the transient current that flowed when the stress voltages were applied to the oxide was caused by carriers tunneling through the silicon oxide by the high voltage stress generated traps.

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Linear Ion Beam Applications for Roll-to-Roll Metal Thin Film Coatings on PET Substrates

  • Lee, Seunghun;Kim, Do-Geun
    • Applied Science and Convergence Technology
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    • v.24 no.5
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    • pp.162-166
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    • 2015
  • Linear ion beams have been introduced for the ion beam treatments of flexible substrates in roll-to-roll web coating systems. Anode layer linear ion sources (300 mm width) were used to make the linear ion beams. Oxygen ion beams having an ion energy from 200 eV to 800 eV used for the adhesion improvement of Cu thin films on PET substrates. The Cu thin films deposited by a conventional magnetron sputtering on the oxygen ion beam treated PET substrates showed Class 5 adhesion defined by ASTM D3359-97 (tape test). Argon ion beams with 1~3 keV used for the ion beam sputtering deposition process, which aims to control the initial layer before the magnetron sputtering deposition. When the discharge power of the linear ion source is 1.2 kW, static deposition rate of Cu and Ni were 7.4 and $3.5{\AA}/sec$, respectively.

Studies on the Corrosion Inhibitor (Ⅱ) (Inhibitor에 관한 硏究 (Ⅱ))

  • Lee Kae Soo
    • Journal of the Korean Chemical Society
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    • v.13 no.2
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    • pp.137-140
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    • 1969
  • This investigation was made to evaluate the corrosion inhibiting effects of urotropine for mild steel in HCl. 1) Formaldehyde produced by the decomposition of urotropine also showed positive inhibiting effects. 2) In the presence of the ions, such as $Cu^+$, $Cu^{++}$, $Fe^{+++}$, $SO_3^=$, $SO_4^=$, $NO_2^-$, $NO_3^-$, $Cr_2O_7^=$, the inhibiting capacity of the urotropine was decreased. Alkali and alkaline-earth metal ions had no effects but the halogen ions improved it. 3) From measurements of polarization curves, it was assumed that the anode reaction was more retarded by the urotropine and the halogen.

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Electrochemical Properties of Additive-Free Nanostructured Cobalt Oxide (CoO) Lithium Ion Battery Electrode (첨가제 없이 제작된 나노구조 코발트 산화물 리튬이온 배터리 전극의 전기 화학적 특성)

  • Kim, Juyun;Park, Byoungnam
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.5
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    • pp.335-340
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    • 2018
  • Transition metal oxide materials have attracted widespread attention as Li-ion battery electrode materials owing to their high theoretical capacity and good Li storage capability, in addition to various nanostructured materials. Here, we fabricated a CoO Li-ion battery in which Co nanoparticles (NPs) are deposited into a current collector through electrophoretic deposition (EPD) without binding and conductive agents, enabling us to focus on the intrinsic electrochemical properties of CoO during the conversion reaction. Through optimized Co NP synthesis and electrophoretic deposition (EPD), CoO Li-ion battery with 630 mAh/g was fabricated with high cycle stability, which can potentially be used as a test platform for a fundamental understanding of conversion reaction.

Analysis of Blanking Process for Aluminium Foil by FEM (유한요소법에 의한 초박판 알루미늄 블랭킹 공정해석)

  • Lee, S.K.;Kim, J.;Kang, B.S.
    • Proceedings of the KSME Conference
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    • 2001.06c
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    • pp.498-501
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    • 2001
  • Blanking is one of the most frequently used processes in sheet metal forming. In this paper, attention is paid to the blanking simulation of aluminium foil with $20{\mu}m$ thickness which is used an anode in lithium-ion polymer battery. In order to study the shearing mechanism for the metallic foil, finite element analysis with Crockroft and Latham fracture criterion was performed. The objective of the present work is to evolve a methodology to obtain the optimum punch-die clearance for a given aluminium foil by the simulation of the blanking process using a general purpose FEM code.

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The effect of temperature and relative humidity on concrete slab specimens with impressed current cathodic protection system

  • Jeong, Jin-A;Jin, Chung-Kuk
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.3
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    • pp.260-265
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    • 2013
  • Impressed current cathodic protection (ICCP) system is one of the most promising corrosion protection methods. The Effect of ICCP system can be changed at diverse conditions. Particularly, temperature and relative humidity plays a crucial role in CP (Cathodic Protection) effect. Thus, in this study, the influence of temperature and relative humidity on concrete specimens was investigated. Specimens were concrete slab type with a base of $400mm{\times}400mm$ and height of 70mm. To enhance the effect of CP system, seawater was used as an electrolyte. Used anode for ICCP system was mixed metal oxide (MMO) titanium. Test factors were natural potential, CP potential, CP current, and 4-hour depolarization potential. From this study, it could be confirm that CP potential and current were highly influenced by temperature and relative humidity.

The Characteristics Evaluation of the Gas Diffusion Layer for a PEM Fuel Cell by Computational Fluid Dynamics (CFD 해석을 이용한 PEMFC 용 기체확산층의 특성평가)

  • Kim B.H.;Choi J.P.;Jeon B.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.207-210
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    • 2005
  • In this paper, a two-dimensional cross-channel model was applied to investigate influence of the gas diffusion layer(GDL) property and flow field geometry in the anode side for proton exchange membrane fuel cell(PEMFC). The GDL is made of a porous material such as carbon cloth, carbon paper, or metal wire mesh. To the simplicity, the GDL is represented as a block of material containing numerous pathways through which gaseous reactants and liquid water can pass. The purpose of present work was to study the effect of the GDL thickness and the porosity, and flow field geometry by computational fluid dynamics(CFD)

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