• Title/Summary/Keyword: Metal Transfer

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Efficiency Improvement of Metal-Mesh Electrode Type Photoelectrochemical Cells by Oxides Layer Coatings (산화물박막 증착에 의한 금속 메쉬전극 구조 광전기화학셀의 효율 개선에 관한 연구)

  • Han, Chi-Hwan;Park, Seon-Hee;Sung, Youl-Moon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.3
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    • pp.584-587
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    • 2011
  • In this work, the $TiO_2$ and $SnO_2$ thin films as blocking layers were coated directly onto the metal-mesh electrode surface to prevent unnecessary inflow of back-transfer electrons from the electrolyte ($I^-/I_3^-$) to the metal-mesh electrode. The DSCs were fabricated with working electrode of SUS mesh coated with blocking $TiO_2$ and $SnO_2$ layers, dye-attached mesoporous $TiO_2$ film, gel electrolyte and counter electrode of Pt-deposited F:$SnO_2$. From the experimental result, it was ascertained that the efficiency of metal electrode coated with $TiO_2$ by Dip-coating was superior to that of metal electrode coated with $SnO_2$ by Dip-coating and screen printing with the results of experiments. The photo-current conversion efficiency of the cell obtained from optimum fabrication condition was 3% ($V_{oc}$=0.61V, $J_{sc}$=11.64 mA/$cm^2$, ff=0.64) under AM1.5, 100 mW/$cm^2$ illumination.

A Study on the Metal Transfer and Spatter Generation in High Current $CO_2$ Welding (고전류 $CO_2$용접에서의 금속이행 및 스패터 발생 현상에 관한 연구)

  • 김남훈;유회수;김희진;고진현
    • Journal of Welding and Joining
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    • v.21 no.3
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    • pp.51-57
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    • 2003
  • The metal transfer in $CO_2$ welding shows the transition of transfer mode from short-circuiting to repelled transfer will the increase of welding current. While the short-circuiting mode in $CO_2$ welding has been studied very extensively relating with droplet formation and spatter generation, the repelled transfer has little been understood. In this study, high current $CO_2$ welding has been performed with bead-on-plate welds along with the waveform analyzer and high speed camera. The image of high speed camera was synchronized with its waveform so that the moment of spatter generation could be realized during drop detachment. As a results of this study, it was found that welding arc changes its location either once or three times and thus single or double pulse signals were developed in the voltage waveform. Whenever the arc moved its location, new arc was developed in a explosive way and thus it caused spatter generation. Specially severe spattering took place when the waveform showed a double-peak pattern. As a consequence of these results, new waveform control techniques could be suggested for suppressing the spatter generation in the high-current $CO_2$ welding.

Simultaneous Transfer and Patterning of CVD-Grown Graphene with No Polymeric Residues by Using a Metal Etch Mask

  • Jang, Mi;Jeong, Jin-Hyeok;Trung, T.Q.;Lee, Nae-Eung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.642-642
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    • 2013
  • Graphene, two dimensional single layer of carbon atoms, has tremendous attention due to its superior property such as high electron mobility, high thermal conductivity and optical transparency. Especially, chemical vapor deposition (CVD) grown graphene has been used as a promising material for high quality and large-scale graphene film. Unfortunately, although CVD-grown graphene has strong advantages, application of the CVD-grown graphene is limited due to ineffective transfer process that delivers the graphene onto a desired substrate by using polymer support layer such as PMMA(polymethyl methacrylate). The transferred CVD-grown graphene has serious drawback due to remaining polymeric residues generated during transfer process, which induces the poor physical and electrical characteristics by a p-doping effect and impurity scattering. To solve such issue incurred during polymer transfer process of CVD-grown graphene, various approaches including thermal annealing, chemical cleaning, mechanical cleaning have been tried but were not successful in getting rid of polymeric residues. On the other hand, lithographical patterning of graphene is an essential step in any form of microelectronic processing and most of conventional lithographic techniques employ photoresist for the definition of graphene patterns on substrates. But, application of photoresist is undesirable because of the presence of residual polymers that contaminate the graphene surface consistent with the effects generated during transfer process. Therefore, in order to fully utilize the excellent properties of CVD-grown graphene, new approach of transfer and patterning techniques which can avoid polymeric residue problem needs to be developed. In this work, we carried out transfer and patterning process simultaneously with no polymeric residue by using a metal etch mask. The patterned thin gold layer was deposited on CVD-grown graphene instead of photoresists in order to make much cleaner and smoother surface and then transferred onto a desired substrate with PMMA, which does not directly contact with graphene surface. We compare the surface properties and patterning morphology of graphene by scanning electron microscopy (SEM), atomic force microscopy(AFM) and Raman spectroscopy. Comparison with the effect of residual polymer and metal on performance of graphene FET will be discussed.

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Analysis of Heat Transfer Characteristics Based on Design Factors for Determining the Internal Geometry of Metal Insulation in Nuclear Power Plant (원전용 금속단열재의 내부 형상결정을 위한 설계인자 별 열전달 특성 분석)

  • Song, Ki O;Yu, Jeong Ho;Lee, Tae Ho;Jeon, Hyun Ik;Ha, Seung Woo;Cho, Sun Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.11
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    • pp.1175-1181
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    • 2015
  • A heat insulating material used in the industrial site normally derives its heat insulating performance by using a low thermal conductivity material such as glass fiber. In case of the metal insulation for nuclear power plant, in contrast, only TP 304 stainless steel foil having high thermal conductivity is the only acceptable material. So, it is required to approach in structural aspect to ensure the insulation performance. In this study, the design factors related to the metal insulation internal structure were determined considering the three modes of heat transfer, i.e., conduction, convection, and radiation. The analysis of heat flow was used to understand the ratio of the heat transfer from each factor to the overall heat transfer from all the factors. Based on this study, in order to minimize the convection phenomenon caused by the internal insulation, a multiple foil was inserted in the insulation. The increase in the conduction heat transfer rate was compared, and the insulation performance under the three modes of heat transfer was analyzed in order to determine the internal geometry.

Effects of GMA Welding Conditions on the Bead Shape of Hardfacing Overlay Welding (하드페이싱 오버레이용접 비드형상에 미치는 GMA 용접조건의 영향)

  • Han, Kyu-Ho;Kim, Jun-Ki;Kim, Cheol-Hee;Kim, Jeong-Han;Nam, See-Hwan;Jeon, Chi-Jung
    • Journal of Welding and Joining
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    • v.25 no.5
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    • pp.58-63
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    • 2007
  • The relationship between GMA welding conditions and the bead shape of overlay weld was studied by using ${\Phi}1.6mm$ hypo-eutectic metal-cored wire designed for hardfacing against the severe metal-to-metal wear. As the welding voltage increased, the dilution also increased but the sudden drop of dilution was observed at $30{\sim}33V$. It was considered to be due to the decrease of penetration resulting from the change of transfer mode, from short circuit to spray. It was also found that the behavior of penetration with welding current was dependant on the transfer mode. The short circuit mode exerted the penetration to decrease while the spray mode did it to increase with increase of welding current. The former was considered to be responsible for the remarkable decrease in dilution at low welding voltage region. The change of transfer mode also had an effect on the behavior of bead width with welding current but it did not on the bead spreadability defined as W/H ratio. It was considered that the optimal welding conditions for multi-pass overlay welding could be obtained from the bead spreadability suitable for bead lapping and the dilution as low as possible in the spray transfer mode.

An Experimental Study on the Metal Surface Temperature and Heat Transfer by Improving Gasoline Engine Cooling Passages (가솔린엔진의 냉각계 유로 변경을 통한 금속면 온도 및 전열에 관한 실험적 연구)

  • 이재헌;류택용;신승용;최재권
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.1
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    • pp.1-8
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    • 2002
  • Metal surface temperatures around the combustion chamber in a gasoline engine directly affect thermal durability and performance of the engine. Metal surface temperatures are influenced by many cooling factors such as drilled water passage, deflector, combustion chamber wall thickness, pillar, and coolant flow pattern. The object of this study is to learn how the coolant passages and coolant flow pattern in an engine influence to the engine metal surface temperature at engine full load and speed. From the test result, it is suggested a plan to reinforce the engine stiffness and to reduce the thermal stress simultaneously. Also, approaches are introduced to reduce the thermal load on the engine by adjusting the discharging direction from the water pump and by optimizing the water transfer holes in the cylinder head gasket. These methods and the optimized engine cooling system, which were suggested in this paper, were adapted for an engine in progress to eliminate the exhaust valve seat wear.

Effect of Coolant Flow Pattern on Metal Temperature of Combustion Chamber (엔진 내 냉각수 유동형태가 연소실 벽면온도에 미치는 영향에 관한 연구)

  • 민병순;최재권
    • Transactions of the Korean Society of Automotive Engineers
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    • v.1 no.1
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    • pp.14-21
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    • 1993
  • The effect of coolant flow pattern on the metal temperature of the combustion chamber was studied in 1.5L and 1.8L gasoline engines. One of the main important points in the design of the water jacket is the increase of the coolant flow velocity. In this paper, the water jackets of the cylinder head and the cylinder block were visualized for the purpose of improving the coolant flow pattern. By the use of this technique, the optimal design of the size and th location of the water transfer fole was possible. And, to lower the metal temperatures of the thermally critical parts, the drilled water passages were employed. To investigate of effect of the improved flow pattern and the drilled water passages, the metal temperatures of the combustion chamber were measured. As a result of the temperature measurement, it was found out that both the change of flow pattern and the drilled water passages have significant effect on the reduction of the peak metal temperature.

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A Numerical Study on a Prediction of Performance of the Metal Hydride Thermal Conversion System through the Propagation Phenomena of Superadiabatic Thermal Waves (초단열 열파동의 전파현상을 활용하는 수소저장합금 열변환 시스템의 성능예측을 위한 수치해석적 연구)

  • Kim, Gyu-Jeong;Kim, Gwan-Yeong;Chae, Jae-U
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.4
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    • pp.572-582
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    • 2001
  • A method of metal-hydride thermal conversion that is an alternative to the traditional method is proposed and investigated. The unit heat pump consists of reactors of two different metal-hydrides are distributed inside parallel channels filled with porous media. The channels are blown through with a heat-transfer agent. Thermal conversion develops as a set of successive heat waves. By a numerical-modeling method it is shown that the maximum thermal effect is attained in synchronous motion of the heat wave and the heat source (or sink) that accompanies the phase transition in the succession of unit metal-hydride pumps. The results are presented in a form convenient for prediction of the thermal and energy efficiency of the proposed thermal-conversion method in real devices.

A Study on the Variation of Elements Loss of Wires and Oxygen Content of Weld Metal in GMAW (GMA용접에서 와이어 탈산원소 손실 및 용접금속 산소 변화 연구)

  • 방국수;장웅성
    • Journal of Welding and Joining
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    • v.16 no.2
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    • pp.93-99
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    • 1998
  • The effects of welding conditions of gas metal arc welding on the elements loss of solid wire, oxygen content and impact toughness of weld metals were studied. Deoxidizing elements loss was increased with increase of arc voltage in both short-circuit transfer mode and globular transfer mode. It is believed that increase of arc voltage results in increase of reaction time between elements in the droplet and surrounding gas at the end of wire and in the arc column. Based on the thermodynamic equilibrium model, the oxygen content of weld metal can be predicted with the content of silicon and manganese as following : [%O] = $K([%Si][%Mn])^{-0.25}$, K = -15518/T+6.01. The equilibrium temperature was dependent on shielding gas, and it was 187$0^{\circ}C$ for $CO_2$ gas and 180$0^{\circ}C$ for 20%$CO_2$-80%Ar gas. The oxygen content of weld metal which shows maximum impact toughness was varied with deoxidizing alloy system of wires, 0.041 wt% for Si-Mn type wire and 0.026 wt% for Si-Mn-Ti type wire.

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