• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2005년도 춘계 학술대회
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• pp.555-556
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• 2005

• Korean Chemical Engineering Research
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• 제61권3호
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• pp.472-478
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• 2023

본 연구에서는 공기청정기 필터용 활성탄의 아세트알데하이드 제거 특성이 금속 촉매 첨착 및 관능기 도입 방법을 사용하여 조사되었다. 야자각 차의 KOH 활성화를 통해 고 비표면적(1700 m²/g)과 미세기공이 발달한 활성탄을 제조하였으며, 금속촉매 첨착과 관능기 개질을 위해 침지 후 기공 내 건조조건에 따른 첨착 효율을 조사하였다. 제조된 활성탄의 물성은 비표면적 및 기공 분석(BET), 유도결합 플라즈마 분광 분석(ICP), 유기 원소 분석(EA) 및 푸리에변환 적외선 분광 분석(FT-IR) 등을 통해 분석하였으며, 활성탄 성능 확인을 위해 침지 농도에 따른 아세트알데하이드 흡착성능을 가스크로마토그래피(GC)로 분석하였다. 첨착용액의 농도가 증가함에 따라 금속촉매 첨착량은 증가하였으며, 비표면적은 감소하는 경향을 보였다. 각 금속촉매 첨착 및 표면개질 활성탄의 파과시험 결과 MgO10@AC, CaO10@AC, EU10@AC, H-U3N1@AC 조성에서 우수한 아세트알데하이드 흡착성능을 보여주었다. 흡착성능이 가장 뛰어난 MgO10@AC에 대해 파과 시간은 533.8 분, 흡착량은 57.4 mg/g으로 측정되었으며, 이는 활성탄에 나노 크기의 MgO 촉매를 첨착할 경우 아세트알데하이드의 카보닐기와 상호작용하여 흡착성능이 개선됨을 알 수 있었다.

• 상하수도학회지
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• 제34권6호
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• pp.425-435
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• 2020

Numerous chemical modifications on activated carbon such as acidic conditioning, thermal treatment and metal impregnation have been investigated to enhance adsorption capacities of micropollutants in water treatment plants. In this study, chemical modification including acidic, alkaline treatment, and iron-impregnation was evaluated for adsorption of 2,4-dichlorophenol (2,4-DCP). For Fe-impregnation, three concentrations of ferric chloride solutions, i.e., 0.2 M, 0.4 M, and 0.8 M, were used and ion-exchange (MIX) of iron and subsequent thermal treatment (MTH) were also applied. Surface properties of the modified carbons were analyzed by active surface area, pore volume, three-dimensional images, and chemical characteristics. The acidic and alkaline treatment changed the pore structures but yielded little improvement of adsorption capacities. As Fe concentrations were increased during impregnation, the active adsorption areas were decreased and the compositional ratios of Fe were increased. Adsorption capacities of modified ACs were evaluated using Langmuir isotherm. The MIX modification was not efficient to enhance 2,4-DCP adsorption and the MES treatment showed increases in adsorption capacities of 2,4-DCP, compared to the original activated carbon. These results implied a possibility of chemical impregnation modification for improvement of adsorption of 2,4-DCP, if a proper modification procedure is sought.

• 공업화학
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• 제32권6호
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• pp.671-678
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• 2021

암모니아의 흡착 성능을 향상할 목적으로 활성탄의 질산 처리 및 활성탄으로 금속 염화물의 첨착 효과를 연구하였다. 질산 처리에 의해 활성탄으로 하이드록시기 및 카르복실기와 같은 작용기들의 도입을 확인하였다. 이후 초음파 함침법을 사용하여 각 금속 염화물(NiCl₂, MgCl₂, CuCl₂, MnCl₂ 또는 CoCl₂)을 표면 개질 활성탄 위로 첨착하였다. 여러첨착된 활성탄들의 물리화학적 특성과 암모니아 흡착 성능을 관찰하였다. 금속 염화물은 초음파 처리에 의해 원활하게 분산되었으며 활성탄 표면 위에 고르게 분포되었다. 금속 염화물이 첨착된 표면 개질 활성탄은 감소된 비표면적 및 세공 부피에도 불구하고 매우 우수한 암모니아 흡착 성능을 나타내었다. 특히, NiCl₂를 첨착하여 제조한 HNO₃-NiCl₂ AC는 가장 우수한 암모니아 흡착능(3.736 mmol·g^-1)을 나타내었으며, 미처리된 활성탄(0.066 mmol·g^-1)과 비교하여 약 57배 향상되었다.

• 산업경영시스템학회지
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• 제46권spc호
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• pp.31-38
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• 2023

In this study, in order to develop a method to efficiently inject essential nutrients necessary for plant growth into wood chips, which are simply used as soil covering materials in the agriculture, landscaping and horticultural industries, the atmospheric pressure dipping method and the vacuum pressure impregnating method are used to improve the plant nutrients injectability and impregnation amount were comparatively analyzed. Nutrient ingredients and 8 major heavy metal contents of wood chips injected with nutrients were analyzed, and soil covering effects were examined by covering wood chips injected with nutrients on soil. Comparing the dipping method and the vacuum pressure impregnation method, it took about 48 hours or more to inject 1,500 g or more of the nutrient aqueous solution into 1 kg of wood chips in the dipping method, but the vacuum pressure impregnation method could be impregnated in about 5 minutes. Components of the impregnated nutrients were detected in proportion to the diluted concentration. As a result of covering the wood chips developed in this study on soil, they showed weakly acidic pH, and the heat insulation and moisturizing effects during the winter season were evaluated to be superior to those of uncovered soil. In the future, wood chips impregnated with nutrients are expected to contribute to the more efficient use of waste wood resources and the long-term supply of nutrients essential for plant growth, reducing excessive use of chemical fertilizers and reducing costs.

• 폴리머
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• 제26권1호
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• pp.105-112
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• 2002

연구는 electro-active polymer(EAP)의 특성을 가지는 ion-exchange polymer metal composite(IPMC)을 이용하여 지능형 대장내시경 개발에 목적을 두고 있다. IPMC는 낮은 구동전압과 빠른 반응속도로 인하여 매우 매력적인 물질이다. 본 연구에서는 IPMC구동기의 전극을 무전의 도금 방법을 이용하여 용액함침-환원방법(impregnation-reduction method)으로 제조하였으며 코팅된 백금전극의 횟수에 따라 변위와 변화를 측정하였다. 구동특성을 알아보기 위하여 길이, 주파수에 대한 변위, 힘을 측정하였으며, 주파수 대역은 저주파 대역과 공명주파수 대역을 사용하는 것이 적합하다는 결론을 얻었다. 또한 다양한 구동적 특성과 수분의 함량에 따른 영향에 대해 고전적 적층 이론 (classical laminate theory, CLT)을 이용하여 이방성 IPMC의 응력분포와 수분이동에 따른 모멘트, 변형률, 곡률(cuvature)을 모델링 하였다.

• 한국수소및신에너지학회논문집
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• 제17권1호
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• pp.47-54
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• 2006

Activated carbon fibers (ACFs) with high surface area and pore volume were modified with metal Ni impregnation and fluorination and investigated hydrogen storage properties by volumetric method. Micropore volume values of ACFs obtained from surface modification with Ni impregnation and fluorination were decreased 9 and 35 %, respectively. Hydrogen storage capacities of fluorinated ACFs were slightly changed, on the other hand, that of Ni impregnated ACF was considerably increased. It means that hydrogen was not only adsorbed on ACF surface, but also on Ni metal surface by means of dissociation. Although the microphone volume of ACF modified with fluorination was decreased, its hydrogen storage were found not to be changed compared with fresh ACF. These results indicated that the surface of ACF after fluorination modification may be strongly attracted hydrogen due to high electronegativity of fluorine. Therefore, it was proven that hydrogen storage capacity was related with micropore volume and surface property of carbon materials as well as specific surface area.

• 한국대기환경학회지
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• 제25권4호
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• pp.316-324
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• 2009

Carbon based sorbents for $CO_2$ adsorption were prepared by impregnation with alkali metals ($Li^+$, $K^+$) and alkaline earth metals ($Ca^{2+}$, $Mg^{2+}$). BET surface area of test sorbents was lower than the intrinsic activated carbon. In particular, impregnation of $Ca^{2+}$ or $Mg^{2+}$ resulted in lower surface area of specific adsorption sites than that of $Li^+$ or $K^+$. While the adsorption capacity for $CO_2$ was high in the sorbents containing $Ca^{2+}$ and $Mg^{2+}$, strong interaction with $CO_2$ would cause to drop the capacity after regeneration. The adsorption was found high relatively in the flow with a high concentration of $CO_2$ and in a low flow rate. The adsorption isotherm for the present modified AC sorbents fits well with the Freundlich model.

• 대한환경공학회지
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• 제37권11호
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• pp.642-648
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• 2015

수계에 존재하는 인산염의 흡착제거 용량을 향상시키기 위하여, 참나무 기반 활성탄을 제조하였으며, 이때 $Fe^{3+}$와 $Al^{3+}$이온의 혼합물을 흡착제 표면에 담지 하였다. 금속담지 활성탄의 인산염의 흡착용량은 금속이온으로 표면을 개질 하지 않은 활성탄에 비해 약 8배 높게 나타났다. 흡착평형량은 흡착반응의 온도가 증가할수록 증가하였으며, Langmuir 흡착등온식의 경향과 일치하였다. 제조된 금속담지 활성탄의 인산염 흡착제거공정은 흡열의 자발반응으로 진행되었음을 확인하였다. 흡착공정의 거동과 제거속도를 평가하기 위하여, 세공확산모델을 통해 내부 확산계수를 산출하였으며, 이는 실험결과와 매우 일치하였다.

• 한국안전학회지
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• 제6권4호
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• pp.26-33
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• 1991

To remove SO$_2$ from flus gas, cupric oxide, manganese oxide and iron oxide were studied with varying loading value. The experiment was carried out in a flow reactor and the reactants were prepared by impregnation method using alumina. The reaction temperature was varied from 30$0^{\circ}C$ to 45$0^{\circ}C$. Experimental results showed that all of these metal oxides were effective on SO$_2$ removal reaction and cupric oxide was the best reactant. The sample with 10wt％ loading value was better reactant than with 20wt％ because in case of 20wt％ loading, metal dispersion on the alumina surface was not uniform. And the SO$_2$ removal efficiency was increased with the reaction temperature.