• Title/Summary/Keyword: Metal Detection

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Integrated Microdisk Gold Electrode Modified with Metal-porphyrin and Metal-phthalocyanines for Nitric Oxide Determination in Biological Media

  • Kim, Il-Kwang;Bae, Hyun-Ok;Oh, Gi-Soo;Chung, Hun-Taeg;Kim, Young-Jin;Chun, Hyun-Ja
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1579-1584
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    • 2003
  • An integrated gold microdisk electrode was constructed and modified with metal-porphyrin or metal-phthalocyanines for NO determination in biological media. Microanalysis of NO using square wave anodic stripping voltammetry in $1\;{\times}\;10^{-2}$ M $HClO_4$ was optimal when the accumulation potential was 0.1 V, frequency 100 Hz, and the scan rate was 200 mV/s. When the electrode was modified with metal-porphyrin or metal-phthalocyanines, the anodic peak currents of NO increased due to the catalytic oxidation of NO. In case of Fe(II)-phthalocyanine modified electrode, the peak currents remarkably increased and the sensitivity was high. The calibration curve had good linearity in the range from $3.6\;{\times}\;10^{-5}$ M to $7.2\;{\times}\;10^{-7}$ M, and the detection limit was $5.7\;{\times}\;10^{-7}$ M. For the structural stability and increased sensitivity, Fe(II)-phthalocyanine modified gold microdisk electrode coated with Nafion was applied to determination of NO released from cultured macrophase.

A Coumarin-based Fluorescent Sensor for Selective Detection of Copper (II)

  • Wang, Jian-Hong;Guo, Xin-Ling;Hou, Xu-Feng;Zhao, Hui-Jun;Luo, Zhao-Yang;Zhao, Jin
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2400-2402
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    • 2014
  • Cu (II) detection is of great importance owing to its significant function in various biological processes. In this report, we developed a novel coumarin-based chemosensor bearing the salicylaldimine unit (2) for $Cu^{2+}$ selective detection. The results from fluorescence spectra demonstrated that the sensor could selectively recognize $Cu^{2+}$ over other metal cations and the detection limit is as low as $0.2{\mu}M$. Moreover, the confocal fluorescence imaging in HepG2 cells illustrated its potential for biological applications.

Flow Injective Determination of Thiourea by Amperometry

  • Lee Joon-Woo;Mho Sun-Il;Pyun Chong Hong;Yeo In-Hyeong
    • Bulletin of the Korean Chemical Society
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    • v.15 no.12
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    • pp.1038-1042
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    • 1994
  • The amperometric responses of thiourea were studied in 0.1 M NaOH by flow injection analysis. D. C. amperometric and pulsed amperometric detection methods were applied for the determination of thiourea at novel metal electrodes such as Pt and Au. Triple-step potential waveforms were adopted in the pulsed amperometric detection. With an optimized pulsed waveform, the current for the oxidation of thiourea was examined with the variation of flow rate of carrier solution and with the change in the amount of sample injected. Gold working electrode turned out to be better in sensitivity and signal to noise ratio than Pt electrode in the pulsed amperometric detection of thiourea. Detection limit is estimated to be 5.33 ${\times}$ 10$^{-5}$ M with this detection method.

A Study on the Development of Early Acetone Gas Detection to Prevent the Acetone Leakage Accident (아세톤 누출사고 예방을 위한 아세톤 가스 조기감지 기술개발에 관한 연구)

  • Seung Jin Jeon;Youngbo Choi
    • Journal of the Korean Society of Safety
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    • v.38 no.2
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    • pp.30-35
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    • 2023
  • Acetone is a widely used Volatile Organic Compound (VOC) in industries and laboratories. However, acetone affects human health adversely and causes fires and explosions. Early acetone detection and improved personnel training in safety and emergency management are necessary to prevent acetone-related accidents. The multi-VOC acetone detectors used currently have a sensitivity and selectivity limit. In this study, we discovered that Pt-loaded iron oxide (a metal oxide semiconductor) conversely, has high detection and selectivity for very low-levels of acetone gas. The loaded Pt catalyzes the reaction between the sensing materials' surface and the oxygen molecules in the air; this optimizes acetone detection and can decrease acetone-related illnesses, fires and explosions.

A Study on the Ground Following and Location Marking Method for Mine Detection System (지뢰 탐지를 위한 지면추종 및 탐지위치 표식에 관한 연구)

  • Lee, Myung-Chun;Shin, Ho-Cheol;Yoon, Jong-Hoon
    • Journal of the Korea Institute of Military Science and Technology
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    • v.14 no.6
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    • pp.1002-1008
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    • 2011
  • The mine-detection system, which is one of the various mission equipments for Ground Vehicle System, detects mine under the ground. The mine detection sensors comprised of Metal Detection(MD) sensor and Ground Penetration Radar(GPR) are attached on the end of the multi-DOF manipulator. The manipulator moves the sensor to sweep mine areas keeping the pre-determined distance between the sensor and ground to enhance mine detection performance. The detection system can be operated automatically, semi-automatically and manually. When the detection system is operated automatically, the sensor should avoid collisions with unexpected obstacles which may exist on the ground. Two types of ultra-sonic sensors were developed for the mine detection sensor system to keep the appropriate gap between sensor and the ground to avoid the obstacles. Also, mine place marking device was developed.

Synthesis of Metal Oxide Semiconductor Nanostructures and Their Gas Sensing Properties (금속 산화물 반도체 나노구조의 합성과 가스 감응 특성)

  • Choi, Kwon-Il;Lee, Jong-Heun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.8
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    • pp.632-638
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    • 2012
  • The prepartion of various metal oxide nanostructures via hydrothermal method, hydrolysis, thermal evaporation and electrospinning and their applications to chemoresistive sensors have been investigated. Hierarchical and hollow nanostructures prepared by hydrothermal method and hydrolysis showed the high response and fast responding kinetics on account of their high gas accessibility. Thermal evaporation and electrospinning provide the facile routes to prepare catalyst-loaded oxide nanowires and nanofibers, respectively. The loading of noble metal and metal oxide catalyst were effective to achieve rapid response/recovery and selective gas detection.

Design of Network-based Automation System for Detecting Metallic Objects in Food and Livestock (식품 및 축산물 금속검출기를 위한 네트워크 기반 자동화 시스템 설계)

  • Hang-Seok Cho;Dongik Lee
    • IEMEK Journal of Embedded Systems and Applications
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    • v.18 no.3
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    • pp.109-116
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    • 2023
  • This paper presents a network-based automation system for the detection of metallic objects in food and livestock. A metal detector is a core equipment used for the inspection required by HACCP. Since the existing metal detectors are manufactured as a single-body equipment, it is difficult to take into account various user requirements for the system. In order to overcome the drawback, this study presents a network-based automation system for metal detector utilizing an industrial fieldbus and modular components. The proposed system can effectively consider the various customer requirements and control schemes. The proposed system can also achieve the improvement in speed and success rate of detecting metallic objects. The effectiveness of the proposed system is demonstrated through a various experiments.

CHARACTERIZATION OF METALLIC CONTAMINATION OF SILICON WAFER SURFACES FOR 1G DRAM USING SYNCHROTRON ACCELERATOR

  • Kim, Heung-Rak;Kun-Kul, Ryoo
    • Journal of Surface Science and Engineering
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    • v.32 no.3
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    • pp.239-243
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    • 1999
  • At Present, 200mm wafer technology is being applied for commercial fabrications of 64, 128, and 256 M DRAM devices, and 300mm technology will be evolved for 1G DRAM devices in the early 21th century, recognizing limitations of several process technologies. In particular recognition has been realized in harmful effects of surface contamination of trace metals introduced during devicing processes. Such a guide line for surface metal contamination has been proposed as 1E9 and 1E10 atoms/$\textrm{cm}^2$ of individual metal contamination for wafering and devicing of 1G DRAM, respectively, and so its measurement limit should be at least 1E8 atoms/$\textrm{cm}^2$. The detection limit of present measurement systems is 2E9 atoms/$\textrm{cm}^2$ obtainable with TRXFA(Total Reflection X-Ray Fluorescence Analysis). TRXFA is nondestructive and the simplest in terms of operation, and it maps the whole wafer surfaces but needs detection improvement. X-Ray intensity produced with synchrotron accelerator is much higher than that of conventional X-ray sources by order of 4-5 magnitudes. Hence theoretically its reactivity with silicon surfaces is expected to be much higher than the conventional one, realizing improvement of detection limit. X-ray produced with synchrotron accelerator is illuminated at a very low angle with silicon wafer surfaces such as 0.1 degree and reflects totally. Hence informations only from surface can be collected and utilized without overlapping with bulk informations. This study shows the total reflection phenomenon and quantitative improvement of detection limit for metallic contamination. It is confirmed that synchrotron X-ray can be a very promising alternative for realizing improvement of detection limit for the next generation devices.

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Metal Surface Defect Detection and Classification using EfficientNetV2 and YOLOv5 (EfficientNetV2 및 YOLOv5를 사용한 금속 표면 결함 검출 및 분류)

  • Alibek, Esanov;Kim, Kang-Chul
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.4
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    • pp.577-586
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    • 2022
  • Detection and classification of steel surface defects are critical for product quality control in the steel industry. However, due to its low accuracy and slow speed, the traditional approach cannot be effectively used in a production line. The current, widely used algorithm (based on deep learning) has an accuracy problem, and there are still rooms for development. This paper proposes a method of steel surface defect detection combining EfficientNetV2 for image classification and YOLOv5 as an object detector. Shorter training time and high accuracy are advantages of this model. Firstly, the image input into EfficientNetV2 model classifies defect classes and predicts probability of having defects. If the probability of having a defect is less than 0.25, the algorithm directly recognizes that the sample has no defects. Otherwise, the samples are further input into YOLOv5 to accomplish the defect detection process on the metal surface. Experiments show that proposed model has good performance on the NEU dataset with an accuracy of 98.3%. Simultaneously, the average training speed is shorter than other models.