• Title/Summary/Keyword: Metal Composites

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Hydrogen Storage Behaviors of Carbon Nanotubes/Metal-organic Frameworks-5 Hybrid Composites

  • Park, Soo-Jin;Lee, Seul-Yi
    • Carbon letters
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    • v.10 no.1
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    • pp.19-22
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    • 2009
  • In this work, the hydrogen storage behaviors of carbon nanotubes (CNTs)/metal-organic frameworks-5 (MOF-5) hybrid composites (CNTs/MOF-5) were studied. Hydrothermal synthesis of MOF-5 was conducted by conventional convection heating using 1-methyl-2-pyrrolidone (NMP) as a solvent. Morphological characteristics and average size of the CNTs/MOF-5 were also obtained using a scanning electron microscopy (SEM). The pore structure and specific surface area of the CNTs/MOF-5 were analyzed by N2/77 K adsorption isotherms. The capacity of hydrogen storage of the CNTs/MOF-5 was investigated at 298 K/100 bar. As a result, the CNTs/MOF-5 had crystalline structures which were formed by hybrid synthesis process. It was noted that the CNTs/MOF-5 can be potentially encouraging materials for hydrogen adsorption and storage applications at room temperature.

Mechanical Properties of Carbon Nanotube/Cu Nanocomposites Produced by Powder Equal Channel Angular Pressing (분말 ECAP 공정으로 제조된 탄소나노튜브/Cu 나노복합재료의 기계적 성질)

  • Yoon, Seung-Chae;Jeong, Young-Gi;Kim, Hyoung-Seop
    • Transactions of Materials Processing
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    • v.15 no.5 s.86
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    • pp.360-365
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    • 2006
  • Carbon nanotubes (CNTs) have been the subject of intensive studies for applications in the fields of nano technologies in recent years due to their superior mechanical, electric, optical and electronic properties. Because of their exceptionally small diameters (${\appros}\;several\;nm$) as well as their high Young's modulus (${\appros}1\;TPa$), tensile strength (${\appros}\;200\;GPa$) and high elongation (10-30%) in addition to a high chemical stability, CNTs are attractive reinforcement materials for light weight and high strength metal matrix composites. Although extensive researches have been performed on the electrical, mechanical and functional properties of CNTs, there are not many successful results on the mechanical properties of CNT dispersed nanocomposites. In this paper, we applied equal channel angular pressing for consolidation of CNT/Cu powder mixtures. We also investigated the hardness and microstructures of CNT/Cu nanocomposites used experimental for metal matrix composites.

Effect of Polymer Content on Synthesis Process and Microstructure of Alumina-Zirconia Composite (알루미나-지르코니아 복합체의 제조공정 및 미세구조에 미치는 폴리머 첨가의 영향)

  • 이상진;권명도;이충효;조경식
    • Journal of Powder Materials
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    • v.10 no.5
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    • pp.310-317
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    • 2003
  • Two-component ceramic (alumina-zirconia) composites were fabricated by a soft-solution process in which polyethylene glycol (PEG) was used as a polymeric carrier. Metal salts and PEG were dissolved in ethyl alcohol without any precipitation in 1:1 volume ratio of alumina and zirconia. In the non-aqueous system, the flammable solvent made explosive, exothermic reaction during drying process. The reaction resulted in formation of volume expanded, porous precursor powders by a vigorous decomposition of organic components in the precursor sol. The PEG content affected the grain size of sintered composites as well as the morphology of precursor powders. The difference of microstructure in sintered composite was attribute to the solubility and homogeneity of metal cations in precursor sol. At the optimum amount of the PEG polymer, the metal ions were dispersed effectively in solution and a homogeneous polymeric network was formed. It made less agglomerated particles in the precursor sol and affected on uniform grain size in sintered composite.

Ionic polymer-metal composite as energy harvesters

  • Tiwari, Rashi;Kim, Kwang J.;Kim, Sang-Mun
    • Smart Structures and Systems
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    • v.4 no.5
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    • pp.549-563
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    • 2008
  • The ability of an electroactive polymer, IPMC (Ionic Polymer Metal Composites,) to produce electric charge under mechanical deformations may be exploited for the development of next generation of energy harvesters. Two different electrode types (gold and platinum) were employed for the experiments. The sample was tested under dynamic conditions, produced through programmed shaking. In order to evaluate the potential of IPMC for dry condition, these samples were treated with ionic liquid. Three modes of mechanical deformations (bending, tension and shear) were analyzed. Experimental results clearly indicate that IPMCs are attractive applicants for energy harvesting, with inherent advantages like flexibility, low cost, negligible maintenance and virtually infinite longevity. Besides, preliminary energy harvesting model of IPMC has been formulated based upon the work of previous investigators (Newbury 2002, Newbury and Leo 2002, Lee, et al. 2005, Konyo, et al. 2004) and the simulation results reciprocate experimental results within acceptable error.

Thixoforging Process and the Problems of Hollow Type Metal Matrix Composite Part (중공형 금속 복합 재료 부품의 Thixoforging 공정과 문제점)

  • 이승후;허재찬;강충길
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.808-811
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    • 1997
  • MMC has excellent mechanical properties in many ways in automotive industrial, and get into the spotlight as a light materials substituted for iron and steel. But the know-how about MMC research lack, MMC is expensive and difficult to apply the sound parts. Especially it is difficult to produce the hollow type parts composed with MMC. Therefore, hollow type parts of metal composites by using thixoforming process which as co-existing solidus-liquidus phase, it is very important to obtain forming condition. In this study, MMC billet producted by electro-magnetic stirring and mechanical stirring process is formed to hollow type parts of thixoforming process and inspected of suitability for application. It is optimized production condition, and applied to experiment. After variable materials were produced for thixoforming process, it were inspected of suitability for application by comparsion with mechanical properties. In this study, used materials were A357, A380 10%vol, and 20%vol SiCp, and the size of particultes were 14$\mu\textrm{m}$ and 5.5$\mu\textrm{m}$.

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The Effect of the Load Resistance on Dispersion Characteristics of Metal-Fiber Composites (금속섬유 복합재료의 부하저항에 따른 분산특성)

  • Seo, Dong-Wook
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.49 no.3
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    • pp.75-81
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    • 2012
  • In this paper, an efficient means to estimate the dispersion characteristics of active FSS (or ESS) is presented. We numerically investigate the effective permittivity and the transmission coefficient of 2D metal-fiber composites using linear-lumped impedance loading. We modify the GEC method which is applied to 2D fiber composite material with arbitrary fiber orientation. We show that by varying the impedance value it is possible to control the resonance frequency of the array as well as the bandwidth.

A Micromechanical Analysis on the Elastic Behavior in Discontinuous Metal Matrix Composites (불연속 금속복합체에서의 탄성거동에 관한 미세구조역학적 해석)

    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.6 no.3
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    • pp.58-64
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    • 1997
  • A micromechanics model to describe the elastic behavior of fiber or whisker reinforced metal matrix composites was developed and the stress concentrations between reinforcements were investigated using the modified shear lag model with the comparison of finite element analysis (FEA). The rationale is based on the replacement of the matrix between fiber ends with the fictitious fiber to maintain the compatibility of displacement and traction. It was found that the new model gives a good agreement with FEA results in the small fiber aspect ratio regime as well as that in the large fiber aspect ratio regime. By the calculation of the present model, stress concentration factor in the matrix and the composite elastic modulus were predicted accurately. Some important factors affecting stress concentrations, such as fiber volume fraction, fiber aspect ratio, end gap size, and modulus ratio, were also discussed.

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Characterization of the Ni and Ni-Cr Porous Metal Reinforced AC4C Matrix Composites Fabricated by Squeeze Casting (용탕단조법에 의한 Ni, Ni-Cr 다공질 발포금속 강화 AC4C 합금기 복합재료에 관한 연구)

  • Kim, Eok-Soo
    • Journal of Korea Foundry Society
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    • v.25 no.2
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    • pp.80-87
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    • 2005
  • The microstructure and mechanical property of the Ni and Ni-Cr porous metal reinforced AC4C matrix composites fabricated by squeeze casting were investigated. In this study Ni, Ni-Cr porous metals which are estimated to be easy to fabricate by squeeze casting are used as strengtheners for composite materials. As a matrix material, Al-7wt.%Si-0.3wt.%Mg(AC4C) has been used. In case of Ni/AC4C and Ni-Cr/AC4C composite, $750^{\circ}C$ melt temperature and minimum 25MPa squeezing pressure are needed to produce sound composite materials. The observation of interfacial reaction zone at various heat treatment condition shows that atsolutionizing temperature of above $520^{\circ}C$, the interfacial reaction zone increases proportionally with heat treatment time and the reaction products formed by interfacial reactions are mainly composed by $Al_{3}Ni$ and $Al_{3}Ni_{2}$ phases.

Microstructure and Mechanical Properties of Reaction-Bonded Sintering TiC-Based Composite Prepared by Ni-Ti Metal Infiltration (Ni/Ti 금속침투에 의한 반응결합소결 TiC계 복합체의 미세구조 및 기계적 특성)

  • 한인섭;우상국;김홍수;양준환;정윤중
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.995-1002
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    • 1996
  • The TiC-(Ni/Ti) composites were prepared by reaction bonding between TiC preforms and the melted mixture of Ni/Ti metal the atomic ratio of which were the ranges of 0.3 to 3. And their microstructures phase composi-tions and mechanical properties were investigated. During reaction bonding Ni/Ti metal mixture had a good wettability an permeability with TiC preforms and pore-free and fully dense sintered bodies were fabricated. TiC particle shape changed from spherical to angular platelet-like and grain size was grown with Ni/Ti atomic ratio increasing from 0.3 to 1. whereas grain growth of TiC particle was restrained and its shape changed gain from angular platelet-like to spherical when Ni/Ti atomic ratio was more than 2. Maximum bending strength and fracture toughness were obtained at the Ni/Ti atomic ratio being 1 their values were 582 MPa and 11.1 MPa.m1/2 respectively.

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Development of Textile Metal Matrix Composites for Electronic Packaging (전자 패키징용 직조형 금속복합재료 개발)

  • 이상관;김진봉;홍순형
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.11a
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    • pp.183-186
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    • 2000
  • A new textile metal matrix composite fur electronic packaging was developed and characterized. The thermal management materials consist of a plain woven carbon fabric as reinforcement and pure aluminum as matrix. The finite element method has been utilized in the analysis of thermal stress between the constituent components of packaging. The prototype part was manufactured by the liquid pressurizing method. The composite has CTE values of 4 to $5{\times}10^{-6}\;^{\circ}C^{-1}$10 in the range of $25^{\circ}C$ ~ 175$^{\circ}C$, resulting in good agreement with electronic materials such as Si and GaAs.

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