• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.47-52
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• 2003

This study was performed to investigate the flow behavior of fresh concrete. strength properties, and durability properties on the chloride penetration resistance of hardened concrete containing Meta-Kaolin(MK) in the range from common strength to high strength to facilitate the use. The results are compared with properties of concrete containing Si1ca Fume(SF). As a result. superplasticizer required in MK concrete was decreased by 8-28% compared to SF concrete with the same slump, but MK concrete became more sticky than SF concrete. It was also found that considering the strength, the optimal cement replacement ratio of MK was 15%, and MK had concrete durable and dense by decreasing the average pore diameter of concrete.

• 한국세라믹학회지
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• 제52권2호
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• pp.150-153
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• 2015

Recently, research on geopolymeric concrete that does not use cement as a binder has been actively investigated. Geopolymeric concrete is cement-free concrete. Masato, ocher and/or soil has been solidified into geopolymeric concrete by the reaction of specifically modified silicate as an alkali activator and inorganic binding materials such as blast furnace slag, fly ash or meta-kaolin, which is cured at room temperature to exhibit high compressive strengths. Based on the results, this study shows how geopolymeric concrete that uses specifically modified silicate and inorganic binding materials is implemented as eco-cement with no cement.

• 콘크리트학회논문집
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• 제26권5호
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• pp.607-614
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• 2014

본 논문에서는 품질확보를 위하여 혼합골재 입도분포를 적용한 부순모래 숏크리트에 플라이애시, 고로슬래그 미분말, 메타카올린, 실리카퓸을 종류 및 혼입률에 변동을 주어 혼입하여 숏크리트의 기초특성과 내구특성에 미치는 영향을 고찰하였다. 또한 각 혼화재료의 주요 혼입률을 선정하고 실제 숏팅을 실시 하여 숏팅 전 후의 기초특성과 내구특성을 분석하였다. 실내실험 결과 광물성 혼화재료 혼입률이 증가할수록 압축강도가 증가하는 경향을 보였다. 특히 메타카올린을 혼입한 경우 가장 우수한 강도 증진효과를 보였으며, 숏팅 후 압축강도 역시 코어링에 의한 강도감소 현상을 감안하여도 강도 발현이 우수한 혼화재료로 판단된다. 염소이온 침투저항성 시험과 황산저항성 시험 결과 광물성 혼화재료 혼입은 염소이온과 황산에 대한 저항성이 증진되는 경향을 보인다. 화상분석을 통한 공극구조 분석 결과 공기연행제를 사용하지 않아 소요의 간격계수와 비표면적을 얻는데 실패하였으며, 향후 공기연행제의 도입 후 실험이 진행될 필요성을 보이고 있다.

• 한국결정성장학회지
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• 제27권3호
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• pp.115-121
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• 2017

콘크리트는 열화요인에 의해 철근콘크리트구조물의 철근부식, 균열발생 및 구조내력저하 등 성능저하현상이 사회적 문제점으로 대두되고 있다. 특히 해수, 지하수 또는 오 폐수처리시설 및 하수도 등에 건설되는 콘크리트 구조물은 산 및 황산염에 의한 화학적 침식을 받는 경우 내구성이 크게 저하되어 대책이 필요하다. 따라서 본 연구는 폐유리 미분말과 메타카올린을 사용하여 강모래와 슬래그 잔골재를 비교하여 내황산염성 실험을 진행하였다. 평가 결과 강모래보다 슬래그 잔골재가 내황산염성이 우수하였으며, 폐유리 미분말은 3 % 치환에서 가장 우수한 성능을 발현하였다.

• 한국세라믹학회지
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• 제14권2호
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• pp.82-87
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• 1977

The material used in this experiment is Ha-Dong kaolin whichis composed of almost crystallographically pure meta-halloysite. It was grinded and passed through 250 mesh and 325 mesh. It was treated with oxalic acids and EDTA which are different in concentration. The samples in conical beaker were kept in laboratory incubator at $25^{\circ}C$ for a certain hours. The treated samples were stirred twice a day. The sample in the conditions as A-7 was kept in an autoclave under the pressure of 3 atmospheric. The samples suspended in each solution were kept for 1.5, 3 and 6 months. The transformation of crystals was detected by X-ray spectrometer, electron microscopy, and infrared spectrometer. The sample through 325 mesh compared with one through 250 mesh was transformed much more. It took for 6 months to transfer from halloysite to kaolinite in EDTA, and 3~4 months under 3 atms in autoclave at the same condition. In oxalic acids it took more than 6 months.

• 한국세라믹학회지
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• 제29권5호
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• pp.347-356
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• 1992

Various kaolin samples with different alumina content were prepared from calcined admixture of kaolin and ammonium sulfate by varying the treatment time in sulfuric acid. Samples were nitridated under N2 or N2-H2 atmosphere with changing the amount of added carbon, the reaction time and temperature. As the alumina content lowered, the size of kaolin particles decreased and the specific surface area increased. XRD analysis indicated that ${\alpha}$-quartz remained by decomposition of halloysite and meta-halloysite. Experimental results of nitridation behavior are summerized as follows; 1) Nitridation under N2 atmosphere. With the increase of C/SiO2 ratio and with the decrease of Al2O3 content, disappearance of XRD pattern peaks of mullite, ${\alpha}$-quartz and ${\alpha}$-Al2O3 were accelerated at 1300$^{\circ}C$. SiC was the main phase in the reaction product of acid-treated kaolin samples nitridated at 1300$^{\circ}C$ for 10 hours regardless of C/SiO2 ratio. But the XRD peak intensities of ${\beta}$-Si3N4, ${\beta}$-sialon and SiC did not show much difference when untreated raw kaolin was fired at the same condition. When the ratio of C/SiO2 was 3.5, ${\beta}$-sialon and ${\beta}$-Si3N4 existed in the reaction product of about 22% alumina containing kaolin sample fired at 1350$^{\circ}C$ for 7 hours. Only ${\beta}$-sialon existed in the same sample fired at 1400$^{\circ}C$ for 10 hours. ${\beta}$-sialon was obtained from all of the acid-treated kaolin samples fired at 1400$^{\circ}C$ for 40 hours, but AlN and SiC remained in the untreated kaolin sample. Z value of the ${\beta}$-sialon obtained from the 22% alumina containing kaolin sample fired at 1400$^{\circ}C$ for 40 hours was about 1.3(XRD) and 1.5(EDS). 2) Nitridation under 80N2+2OH2 mixed gas atmosphere with the C/SiO2 ratio of 1 Mullite was not found, but ${\alpha}$-Si3N4, and ${\beta}$-sialon were present in the reaction product of about 22% alumina containing kaolin sample fired at 1300$^{\circ}C$ for 10 hours. When untreated kaolin sample was nitridated at the same condition, mullite remained. AlN and SiC were not found in the reaction product of about 22% alumina containing kaolin sample fired at 1350$^{\circ}C$ for 5 hours. On the other hand, AlN and SiC remained in the product of untreated kaolin fired at the same condition.

• Applied Microscopy
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• 제43권4호
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• pp.155-163
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• 2013

Meta-kaolin (MK) and blast furnace slag (BS) were used as raw materials with NaOH and sodium silicate as alkali activators for making geo-polymers. The compressive strength with respect to the various pre-curing conditions was investigated. In order to improve the recycling rate of BS while still obtaining high compressive strength of the geo-polymers, it was necessary to provide additional CaO to the MK by adding BS. The specimens containing greater amounts of BS can be applied to fields that require high initial compressive strength. Alkali activator(s) are inevitably required to make geo-polymers useful. High temperature pre-curing plays an important role in improving compressive strength in geo-polymers at the early stage of curing. On the other hand, long-term curing produced little to no positive effects and may have even worsened the compressive strength of the geo-polymers because of micro-structural defects through volume expansion by high temperature pre-curing. Therefore, a pre-curing process at a medium range temperature of $50^{\circ}C$ is recommended because a continuous increase in compressive strength during the entire curing period as well as good compressive strength at the early stages can be obtained.

• 한국디지털건축인테리어학회논문집
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• 제12권4호
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• pp.87-95
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• 2012

Autoclaved lightweight concrete (ALC), also known as autoclaved aerated concrete (AAC), is a lightweight, precast building material that simultaneously provides structure, insulation. ALC is a unique building material. Because of its cellular nature, it is lightweight, self-insulating, as well as sound and fireproof. ALC products include blocks, wall panels, floor and roof panels, and lintels. Recently, the use of ALC has became increasingly popular. However, ALC have high water absorption, low compressive strength and popout the origin of the low surface strength in its properties. Thus, this study is to improve the fundamental strength by controls of increasing of admixtures and chemical reactants. Admixtures make use of meta kaolin and silica fume, chemical reactants make use of sodium silicate and sodium hydroxide. From the test result, the ALC using admixtures and chemical reactants have a good fundamental properties compared with plain ALC. These good fundamental properties is caused by the admixtures and chemical reactants of ALC by the reason of the micro filling effect and chemical binding of C-S-H gel, tobermolite and quartz.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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• pp.29-32
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• 2005

In this study, the experiment was carried out to investigate and analyze the strenth properties and flowability of ultra-high strength concrete accroding to types of mineral admixtures. The main experimental variables were water/binder ratio 25.0, 27.5 and 30.0$\%$, water content 155, 160, 165, and 170kg/$m^{3}$ and mineral admixtures such as fly ash, silica fume and meta kaolin. According to the test results, the principle conclusions are summarized as follows. 1) In case of using admixtures, superplasticizer amount need more than plain concrete. 2) According to kinds of admixtures, the viscosity of concrete show much difference. 3) The compressive strength of concrete that use admixtures becomes low in early-age strength, but appeared by higher than plain concrete in long-term strength. 4) Meta kaolin is excellent in side but has viscosity enlargement efficiency a little. But, problem estimates that is not to make design strength 600 and 700kgf/$cm^{2}$ if use mixing condition with water-binder ratio properly.

• 한국광물학회지
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• 제12권1호
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• pp.11-22
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• 1999

Thermal behavior of dickite was studied by thermal analysis, X-ray diffraction analysis, electron microprobe analysis, and scanning electron microscopy, Dickite has an endothermic peak at about$ 650^{\circ}C$ and an exothermic one at $960^{\circ}C$ in the differential thermal analysis. The endothermic reaction is assigned to the decomposition of dickite to meta-dickite. Hydroxyl radicals are removed from dickite structure by the reaction, resulting in the weight loss about 10.5~14.5% and appearance of a 14$\AA$ phase different from other kaolin minerals. The reaction slowly proceed in the range of $200^{\circ}C$. As the completion of decomposition, aciclular mullite forms at the expense of meta-dickite plates with random crystallographic relationship. Mullites have diverse silica versus alumina ratio. The exothermic reaction without weight loss seems to be due to the formation of spinel and amorphous silica. The spinel phase shows cryptocrystalline globular morphology accompanying a little amount of silica. From spinel phase shows cryptocrystalling globular morphology accompanying a little amount of silica. From this work, it is suggested that mullite is formed from meta-dickite much lower temperature than the reported one in the previous works.