• 제목/요약/키워드: Merocyanine

검색결과 39건 처리시간 0.026초

Q.C.M.을 이용한 메로시아닌 색소 LB막의 광학적 특성 분석 (Analysis of Optical Properties of Merocyanine Dye LB Films by Using Q.C.M.)

  • 강기호;김정명;신훈규;장정수;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 전자세라믹스 센서 및 박막재료 반도체재료 일렉트렛트 및 응용기술
    • /
    • pp.130-133
    • /
    • 2000
  • The optical characteristics of merocyanine dyes have been investigated widely due to their possible application to the high efficiency photo-electric devices. The optical systems are mostly fabricated using vacuum evaporation. casting and Langmuir-Blodgett method and the arrangement and orientation of dye molecules is one of the most important factors in the study on the optical characteristics. In this study. we fabricated the molecular systems through the LB techniques and investigated the optical characteristics of merocyanine dye LB film using the oscillation characteristics of quartz crystal. It was quite interesting behavior that the resistance and frequency shift at the parallel resonance under the UV irradiation.

  • PDF

UV조사에 의한 메로시아닌 색소 LB막의 광반응 특성 (The Light Response Properties of Merocyanine Dye LB Film Using UV irradiation)

  • 강기호;김정명;신훈규;장정수;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2000년도 영호남학술대회 논문집
    • /
    • pp.47-50
    • /
    • 2000
  • The optical characteristics of merocyanine dyes have been investigated widely due to their possible application to the high efficiency photo-electric devices. The optical systems are mostly fabricated using vacuum evaporation, casting and Langmuir-Blodgett method and the arrangement and orientation of dye molecules is one of the most important factors in the study on the optical characteristics. In this study, we fabricated the molecular systems through the LB techniques and investigated the optical characteristics of merocyanine dye LB film using the oscillation characteristics of quartz crystal. It was quite interesting behavior that the resistance and frequency shift at the parallel resonance under the UV irradiation.

  • PDF

UV 조사에 의한 메로시아닌 색소 LB박막의 J-aggregation 특성 (J-aggregation Property of Merocyanine Dye LB Thin Film by UV Irradiation)

  • 양창헌;이지윤;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2008년도 춘계학술대회 논문집 센서 박막재료연구회 및 광주 전남지부
    • /
    • pp.123-124
    • /
    • 2008
  • We investigate characteristics of J-aggregation as take advantage of LB technic. In order to confirm the applications possible for the molecular electronic device, the morphological properties of merocyanine dye were investigated by AFM. $\pi$-A curves investigated the surface pressure of the LB film from a liquid to a solid state ranged between 90 and 100 mN/m. We observed aggregation and it's characteristics by using visible reflection spectroscopy. This paper focuses on results obtained in mercocyanide dye. When LB films of merocyanine dye are mixed with arachidic acid, J-aggregate formation is exhibited. J-aggregate formation has been serving as typical systems in revealing the physical and structural aspects of nano-sized molecular aggregates constructed as muiltilayers.

  • PDF

광 흡수 Sepectra 에 의한 메로시아닌 LB막의 구조제어 (Structure Control of Merocyanine LB Films by Optical Absorption Spectra)

  • 신훈규;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
    • /
    • pp.401-404
    • /
    • 1996
  • Optical absorption were performed on LB films of binary mixtures of three kinds of merocyanine dyes [DO], [DS], and [6Me-DS], where [DS] and [6Me-DS] from J-like aggregates but not [DO] in single component films. The observed optical absorption spectra of mixed films were markedly dependent on the combination of dyes. [DS]$_{1-x}$ [DO]$_{x}$ LB films show a sharp red shift J-like band peak in the while concentration range. We found the formation of J-aggregates in a mixed merocyanine dyes containing a non J-aggregate forming dye [DO], in a single component case. Further investigations on the present and other mixed dye films will be needed to clarify these points.ts.

  • PDF

수정진동자를 이용한 메로시아닌 색소 LB막의 광반응 특성 (The analysis of the optical response of merocyanine LB films using QCM)

  • 강기호;김정명;장정수;권영수
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
    • /
    • pp.434-436
    • /
    • 2000
  • In this study, we investigate the optical characteristics of merocyanine dye Langmuir-Blodgett(LB) film using the oscillation characteristics of quartz crystal. As results, the resistance and frequency shift at the parallel resonance under the UV irradiation is to be going down. This behaviour of resistance and frequency is different from the case of general mass adsorption into the organic film on the quartz crystal. Generally the frequency decrease of quartz crystal oscillator, which has been considered as mass loading, goes along with the resistance increase. Thus it has been suggested that the J-aggregate dissociation in merocyanine dye LB film by UV irradiation give rise to transformation of oscillation characteristics of quartz crystal.

  • PDF

메로시아닌 색소 LB막의 온도영향에 의한 수정진동자 거동특성조사 (The Investigation on Merocyanine Dye of Thermal Behavior Using QCM)

  • 윤회찬;김정명;장정수;권영수
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
    • /
    • pp.128-130
    • /
    • 2001
  • In this study, we investigate the deposition characteristics of merocyanine dye(MD) Langmuir-Blodgett(LB) film using quartz crystal microbalance (QCM). The MD optical system mixed with fatty acid was fabricated using LB method. And their optical characteristics were investigated using UV spectroscopy. The optical behavior of MD LB film was investigated asto thermal treatment. The resonant frequency and admittance was measured during dissociation of J-aggregate of MD LB film. As a result, it has been suggested that the J-aggregate dissociation in MD LB film by thermal treatment give rise to transformation of oscillation characteristics of quartz crystal.

  • PDF

Cyanine 및 Merocyanine색소의 분광특성 및 광전특성에 대한 전자구조의 상관관계(II) (Interrelation on the Electronic Structure and Spectroscopic-Photoeletric Characteristics in the Cyanine and Merocyanine Dye(II))

  • 손세모
    • 한국인쇄학회지
    • /
    • 제13권2호
    • /
    • pp.1-17
    • /
    • 1995
  • Organic thin film electroluminescene devices were fabricated using by molecularly doped method with N,N`-diphenyl-N,N`-bis(3-methylphenyl)-1,1`-biphenyl-4,4`-diamine(TPD) as a hole transport material, tris(8-quinolinolate) aluminium(III)(Alq3) as an emitting and electron transport agent, fluorescent squarylium(SQ) dye as a dopant, and poly(methylmethacrylate) as polymer materials. A cell structure of ITO/TPD-PMMA/Alq3-dopant/Mg was employed. The EL spectrum covers a wide range of the visible region and orange emission os observed. Two peaks at 520 and 660nm correspond to the emissions 620nm Alq3 and SQ dye, respectively.

  • PDF

Photoacid Catalyzed Reaction of Phenol with Styrene

  • Kim, Vicna;Shin, Eun Ju;Chung, Minchul;Ahn, Hogeun;Kwak, Wonbong
    • Rapid Communication in Photoscience
    • /
    • 제5권1호
    • /
    • pp.13-15
    • /
    • 2016
  • The reaction of styrene with phenol using photoacid catalyst has been investigated. Upon irradiation with 450 nm light, protonated merocyanine photoacid converts into spiropyran form with releasing proton. The reaction of styrene with phenol has been conducted under irradiation with 450 nm light using merocyanine photoacid catalyst at room temperature in comparison with the results using some selected catalysts including $H_2SO_4$ or $FeCl_3$ at the reaction temperature of $120^{\circ}C$.

전자 스핀 공명을 이용한 메로시아닌 색소 LB막의 특성 (Characteristics of Meroeyanine Dye LB Films Using Electron Spin Resonance Spectroscopy)

  • 신훈규;권영수
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1996년도 하계학술대회 논문집 C
    • /
    • pp.1569-1571
    • /
    • 1996
  • The role of ESR spectroscopy in the characterization of functional LB films is discussed. Optical absorption were performed on LB films of binary mixtures of three kinds of merocyanine dyes where DS and 6Me-DS form J-like aggregates but not DO in single component films. The observed optical absorption spectra of mixed films were markedly dependant on the combination of dyes. We found the formation of J-aggregates in a mixed merocyanine dyes containing a non J-aggregate forming dye DO, in a single component case. In structural studios, ESR is of particular important in the analysis of molecular orientation of LB films. Development of new functional LB films may provide more cases where ESR spectroscopy will clarify the nature of such films.

  • PDF

혼합 매로시아닌 LB막의 광흡수 스펙트라 (Optical Absorption Spectra of Mixed Merocyanine Dye LB films)

  • 신훈규;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
    • /
    • pp.35-42
    • /
    • 1996
  • In this Paper, optical absorption were performed on LB films of binary mixtures of three kinds of merocranine dyes DO, DS, and 6Me-BS, where DS and 6Me-DS form J-like aggregates but not DO in single component films. The observed optical absorption spectra of mixed films were markedly defendent on the combination of dyes. [6Me-DS]$\sub$1-x/[DOl]$\sub$x/ LB films show a sharp red shifted J-like band peak in the whole concentration range. We found the formation of f aggregates in a mixed merocyanine dyes containing a non J-aggregate forming dye DO, in a single component case. Farther investigations on the present and other mixed-dye films will be needed to clarify these points.

  • PDF