• Membrane Journal
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• v.13 no.4
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• pp.291-299
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• 2003

Polymer membranes such as poly(1-trimethylsilyl-1-propyne)-polyetherimide (PTMSP-PEI) and poly(dimethylsiloxane)- polyetherimide (PDMS-PEI) composite membrane were prepared by solution casting method. To investigate the characteristics of these membranes, the analytical methods such as FT-IR, $^1H-NMR,$ DSC, TGA, GPC, and SEM have been utilized. The number-average (equation omitted) and weight-average (equation omitted) molecular weight of PTMSP were 477,920 and 673,329 respectively. The glass transition temperature ($T_g$) of PTMSP was $224^{\circ}C.$ The separation of the gas mixture ($H_2/N_2$) through the composite membranes were studied as a function of pressure. The separation factor (${\alpha}, {\beta},$ quation omitted) of the composite membranes used in this work increased as the pressure of permeation cell increased. The real separation factor (${\alpha}$), head separation factor (${\beta}$), and tail separation factor (equation omitted) of PTMSP-PEI composite membrane were 2.28, 1.17, and 1.96 respectively at ${\Delta}P$ 30psi and $25^{\circ}C.$ (${\alpha}, {\beta}$ and equation omitted of PDMS-PEI composite membrane were 3.70, 1.53, and 2.42 respectively at ${\Delta}P$ 30psi and $25^{\circ}C$.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05b
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• pp.147-152
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• 2004

Gas separation membrane technology is useful for a variety of applications [1, 2]. such as hydrogen recovery from reactor purge gas, nitrogen and oxygen enrichment, water vapor removal from air, stripping of carbon dioxide from natural gas. etc. Although membrane separations are attractive because of low energy costs and simple operation, low permeabilities and/or selectivity often limit membrane applications [3, 4].(omitted)

• Proceedings of the Membrane Society of Korea Conference
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• 1995.09a
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• pp.21-22
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• 1995

Gas separation science and technology is among the most rapidly growing areas involving membrane-based processes. Nitrogen enrichment of air, hydrogen recovery from a broad array of stream types, and removal of acid gases from natural gases are typical of the applications in this field. Great progress has been made in the discovery of guidelines optimization of polymer structures with simultaneously high permeabilities and selectivities for these important gas pairs. The development of thin-skinned asymmetric hollow fibers have also provided structures with extremely high permeation fluxes. Especially in the case of O$_{2}$/N$_{2}$ separations, the rate of improvements in new polymeric materials for gas separations appears to be slowing to a halt. Evidence will be presented, however, that the practical tradeoff between membrane permeability and selectivity has not been reached.

• Membrane Journal
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• v.24 no.5
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• pp.409-415
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• 2014

This study is aimed to separate propylene and propane using membrane process instead of NCC(Naphtha Cracking Center) $C_3$ splitter. Membrane process is a low energy consumption and eco-friendly process while $C_3$ splitter requires high energy consumption in petrochemical processes. In this study, high performance facilitated transport membrane (FTM) is used for propylene/propane separation. FTM module was prepared on top of porous polyetherimide hollow fiber using PVP/$AgBF_4$/TCNQ. We developed simulation program predicting the membrane separation properties under operation conditions. Separation properties of FTM module for propylene and propane were obtained from the simulation program based on the pure gas permeation data. Based on these results, it is predicted that an one-stage membrane process provides 99.5% of propylene at permeate side from a binary gas mixture of 95/5 vol% $C_3H_6$ / vol% $C_3H_8$ supplied as a feed gas.

• Membrane Journal
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• v.10 no.2
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• pp.55-65
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• 2000

The porous silica membrane was prepared from Si(${OC}_2H_5)_4-H_2O$ system by sol-gel method. To investigate the characteristics of gels and porous silica membrane, we examined gels and porous silica membrane using TG-DTA, X-ray diffractometer, IR spectrophotometer, BET, SEM and TEM. The optimum mole ratio of Si(OC$_2$H$_{5}$)$_4$ : $H_2O$ $C_2$H$_{5}$OH for porous silica membrane was 1 : 4.5 : 4. The porous silica membrane was obtained by heat treatment of the gel above 700 $^{\circ}C$. The specific surface area of sintered gel was 3.8 $m^2$/g to 902.3 $m^2$/g at 100 $^{\circ}C$ to 1100 $^{\circ}C$ The pore size of sintered gel was in the range 20 $\AA$~ 50$\AA$. The particle size of sintered gel was 15 nm to 30 nm at 30$0^{\circ}C$ to 700$^{\circ}C$. The performance of the porous silica membrane was investigated for the separation of $H_2$/$N_2$ gas mixture. Gas separation through porous silica membrane depends upon Knudsen flow and surface flow. The veal separation factor($\alpha$) of $H_2$/$N_2$ was 5.17 at 155.15 cmHg and $25^{\circ}C$. The real separation factor($\alpha$), head separation factor($\beta$), and tail separation factor( $\bar{B}$) increased as the pressure of permeation cell Increased.sed.

• Proceedings of the Membrane Society of Korea Conference
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• 1997.10a
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• pp.83-84
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• 1997

1. INTRODUCTION : Polyimides containing siloxane moiety(poly(imide siloxane), or polysiloxaneimide) have been synthesized because of their some merits over polyimide itseft. Polyimides have excellent thermal and mechanical properties but their poor solubility and processibility in their fullly imidized form give disadvantages in applications. Incorporation of siloxane units make it possible to increase solubility and processibility, and also impart impact resistance, low moisture uptake, low dielectric constant, thermo-oxidative resistance, good adhesion properties to substrate and etc.. Incorporation methods of siloxane groups into the polyimide was mainly copolymerization or terpolymerization between oligomeric dimethylsiloxane and aromatic dianhydride. A few methods of introducing siloxane units in functional groups of polyimide was reported. In our laboratory poly(amideimide siloxane) and poly(imide siloxane) were prepared and the study about their thermal kinetics was performed. In separation membrane area, polysiloxaneimides was utilized in pervaporation and gas separation. Polyimides in gas separation show high selectivity and very low permeability, and introduction of siloxane segments increase permeability with low decrease in selectivity. We aimed to introduce silicone segments into poly(amic acid) state and synthesize polymer partially imidized, and also show the gas separation characteristics of the synthesized polymer.

• Membrane Journal
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• v.2 no.2
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• pp.135-143
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• 1992

Separation of $N_2-SO_2$ mixed gas by polymer membranes, SEPA-97(CA), TFC, and FT-30 membrane, was investigated by varying pressure and temperature. The permeability coefficients and the separation factors of mixed gases were measured, and the influence of various factors on the gas permeability characteristics and separation performance were investigated. The range of pressure was 0.1~1.0 MPa, and that of temperature was 283~303 K. The experimental results showed that the permeability coefficients and the separation factors were increased with an increase in pressure, but they were deereased with increasing temperature. Among the examined membranes, FT-30 possessed the best gas-separating characteristics.

• Membrane Journal
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• v.30 no.2
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• pp.124-130
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• 2020

Climate change is getting worse in the 21st century. So, water shortages are expanding worldwide. Carbon dioxide generated from the use of fossil fuels is 80% of the total green house gas. Because it occupies, it has become a factor of global warming. Therefore, the importance of water treatment membrane, gas separation membrane, and secondary battery separation membrane is increasing, but it occupies technology in developed countries such as the United States, Japan, and Germany. Therefore, the advancement of membrane technology is urgently required. So, although the country supports a lot of research budgets, We will analyze the results using NTIS data. As a result of the analysis used, it is supported mainly for short-term tasks, and the research budget is small compared to other technical fields, so the basic material field technology is weak. Therefore, when we invest a lot of long-term tasks, with a lot of budget, and universities, membrane technology has been improved and competitiveness has been strengthened.

• Proceedings of the Membrane Society of Korea Conference
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• 2000.11a
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• pp.29-36
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• 2000

No Abstract, See Full Text

• Membrane Journal
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• v.31 no.4
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• pp.268-274
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• 2021

One of the chronic problems in the issue of global warming is the emission of greenhouse gases. Carbon dioxide (CO₂), which accounts for the highest proportion of various greenhouse gases, has been continuously researched by humans to separate it. From this point of view, a poly(vinyl alcohol) (PVA)-based copolymer with acrylic acid monomer was utilized in a gas separation membrane in this study. We employed a free radical polymerization to fabricate PVA-g-PAA (VAA) graft copolymer. It was utilized in the form of a composite membrane on a polysulfone substrate. The proper amount of acrylic acid reduced the crystallinity of PVA and increased CO₂ solubility in separation membranes. In this perspective, we suggest the novel approach in CO₂ separation membrane area by grafting and solution-diffusion.