• Membrane Journal
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• v.9 no.2
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• pp.107-113
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• 1999

Alcohol concentration via pervaporation process was performed by using commercial PDMS(polydimethylsiloxane) composite membrane and plasma treated PP(polypropylene) membranes. Effects of operating parameters of pcrvaporation process were examined. With the increase of butanol concentration in the feed, flux and selectivity increased due to the greater affinity of butanol with PDMS than that of water. As the operating temperature increased, free volume as well as the solubilities and diffusivities of alcohol and water increased to result in the greater flux and less selectivity of the membrane. As solubility parameter difference between alcohol and PDMS membrane decreased, high flux and good selectivity were obtained. When PP membrane was plasma treated with methanol, it has 6 times greater flux than PDMS membrane with equivalent separation factor. With the increase of plasma treatment time, flux and selectivity were enhanced. However, excess treatment time caused pore blocking to result in the flux decrease.

• Membrane Journal
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• v.15 no.1
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• pp.52-61
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• 2005

Permeate flux decline in a microfiltration was analyzed by measuring the permeability of bentonite colloidal solution through polyethylene capillary membranes. The flux decline with time was due to the growth of cake layer on the membrane surface and to the pore blocking by particles. As the time approaches to steady state, the permeate flux is almost controlled by the cake filtration model. Faster flux decline at high trans-membrane pressure was attributed to the formation of denser packed cake layer and pore blocking. The ratio of permeate flux to the initial permeate flux, J/J₁, decreased with increasing the trans-membrane pressure, from 45% for 0.5 kg/sub f//㎠ to 38% for 2.0 kg/sub f//㎠. In comparing the ratio of each fouling component to the total fouling for the 0.5 kg/sub f//㎠ TMP condition, complete blocking was 23.4%, standard blocking was about 14.6% and cake filtration was 62.0%, respectively. Permeate flux through the membrane increases with cross flow velocity, and the effect of the variation of velocity is more significant at 1.0 kg/sub f//㎠ rather than at 2.0 kg/sub f//㎠ of the operation pressure. Permeate flux for the membrane having the average pore diameter of 0.34 ㎛ was higher than that for the membrane of 0.24 ㎛ pore size, with the higher flux with the low concentration of feed. On the operation using the membrane of 0.34 ㎛ pore, the pore blocking in the low concentration of 200 ppm is negligible relative to the pore blocking in the 1000 ppm feed.

• Korean Membrane Journal
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• v.7 no.1
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• pp.19-27
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• 2005

PP hollow fiber membrane was hydrophilized by EVOH dip coating followed by low temperature plasma treatment and UV irradiation. EVOH coating attained high water flux without any prewetting but its stability did not guaranteed at high water permeation rate. At high water permeation rate, water flux declined gradually due to swelling and delamination of the EVOH coating layer causing pore blocking effect. However, plasma treatment reduces the swelling, which suppress delamination of the EVOH coating layer from PP support result in relieving the flux decline. Also, UV irradiation helped the crosslinking of the EVOH coating layer to enhance the performance at low water permeation rate. FT-IR and ESCA analyses reveal that EVOH dip coating performed homogeneously through not only membrane surface but also matrix. Thermogram of EVOH film modified plasma treatment and W irradiation show that crosslinking density of EVOH layer increased. Chemical modification by plasma treatment and UV irradiation stabilized the hydrophilic coating layer to increase the critical flux of the submerged membrane.

• Membrane and Water Treatment
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• v.10 no.5
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• pp.387-394
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• 2019

Membrane distillation (MD) is one of the water treatment processes which involves the momentum, heat and mass transfer through channels and membrane. In this study, CFD modeling has been used to simulate the heat and mass transfer in the direct contact membrane distillation (DCMD). Also, the effect of operating parameters on the water flux is investigated. The result shows a good agreement with the experimental result. Results indicated that, while feed temperature is increasing in the feed side, water flux improves in the permeate side. Since higher velocity leads to the higher mixing and turbulence in the feed channel, water flux rises due to this increase in the feed velocity. Moreover, results revealed that temperature polarization coefficient is rising as flow rate (velocity) increases and it is decreasing while the feed temperature increases. Lastly, the thermal efficiency of direct contact membrane distillation is defined, and results confirm that thermal efficiency improves while feed temperature increases. Also, flow rate increment results in enhancement of thermal efficiency.

• Journal of Korean Society of Water and Wastewater
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• v.27 no.1
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• pp.139-146
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• 2013

A process diagnosis method for membrane water treatment plant was developed using a constant flux membrane fouling model. This diagnosis method can be applied to a real-field membrane-based water treatment plant as an early alarming system for membrane fouling. The constant flux membrane fouling model was based on the simplest equation form to describe change in trans-membrane pressure (TMP) during the filtration cycle from a literature. The model was verified using a pilot-scale microfiltraton (MF) plant with two commercial MF membrane modules (72 m2 of membrane area). The predicted TMP data were produced using the model, where the modeling parameters were obtained by the least square method using the early plant data and modeling equations. The diagnosis was carried out by comparing the predicted TMP data (as baseline) and real plant data. As a result of the case study, the diagnsis method worked pretty well to predict the early points where fouling started to occur.

• Journal of Korean Society on Water Environment
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• v.18 no.2
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• pp.113-122
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• 2002

A bench-scale anoxic membrane bioreactor (MBR) system, consisting of a bioreactor coupled to a ceramic crossflow ultrafiltration module, was evaluated to treat a synthetic wastewater containing alkaline hydrolysis byproducts (hydrolysates) of RDX, The wastewater was formulated the same as RDX hydrolysates, and consisted of acetate, formate, formaldehyde as carbon sources and nitrite, nitrate as electron accepters. The MBR system removed 80 to 90% of these carbon sources, and approximately 90% of the stoichiometric amount of nitrate, 60% of nitrite. The reactor was also operated over a range of transmembrane pressures, temperatures, suspended solids concentration, and organic loading rate in order to maximize treatment efficiency and permeate flux. Increasing transmembrane pressure and temperature did not improve membrane flux significantly. Increasing biomass concentration in the bioreactor decreased the permeate flux significantly. The maximum volumetric organic loading rate was $0.72kg\;COD/m^3/day$, and the maximum F/M ratio was 0.50 kg N/kg MLSS/day and 1.82 kg COD/kg MLSS/day. Membrane permeate was clear and essentially free of bacteria, as indicated by heterotrophic plate count. Permeate flux ranged between 0.15 and $2.0m^3/m^2/day$ and was maintained by routine backwashing every 3 to 4 day. Backwashing with 2% NaOCl solution every fourth or fifth backwashing cycle was able to restore membrane flux to its original value.

• Journal of Korean Society of Water and Wastewater
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• v.31 no.6
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• pp.501-510
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• 2017

In this study, it is estimated that ceramic membrane process which can operate stably in harsh conditions replacing existing organic membrane connected with coagulation, sedimentation etc.. Jar-test was conducted by using artificial raw water containing kaolin and humic acid. It was observed that coagulant (A-PAC, 10.6%) 4mg/l is the optimal dose. As a results of evaluation of membrane single filtration process (A), coagulation-membrane filtration process (B) and coagulation-sedimentation-membrane filtration process (C), TMP variation is stable regardless of in Flux $2m^3/m^2{\cdot}day$. But in Flux $5m^3/m^2{\cdot}day$, it show change of 1-89.3 kpa by process. TMP of process (B) and (C) is increased 11.8, 0.6 kpa each. But, the (A) showed the greatest change of TMP. When evaluate (A) and (C) in Flux $10m^3/m^2{\cdot}day$, TMP of (A) stopped operation being exceeded 120 kpa in 20 minutes. On the other hand, TMP of (C) is increased only 3 kpa in 120 minutes. Through this, membrane filtration process can be operated stably by using the linkage between the pretreatment process and the ceramic membrane filtration process. Turbidity of treated water remained under 0.1 NTU regardless of flux condition and DOC and $UV_{254}$ showed a removal rate of 65-85%, 95% more each at process connected with pretreatment. Physical cleaning was carried out using water and air of 500kpa to show the recovery of pollutants formed on membrane surface by filtration. In (A) process, TMP has increased rapidly and decreased the recovery by physical cleaning as the flux rises. This means that contamination on membrane surface is irreversible fouling difficult to recover by using physical cleaning. Process (B) and (C) are observed high recovery rate of 60% more in high flux and especially recovery rate of process (B) is the highest at 95.8%. This can be judged that the coagulation flocs in the raw water formed cake layer with irreversible fouling and are favorable to physical cleaning. As a result of estimation, observe that ceramic membrane filtration connected with pretreatment improves efficiency of filtration and recovery rate of physical cleaning. And ceramic membrane which is possible to operate in the higher flux than organic membrane can be reduce the area of water purification facilities and secure a stable quantity of water by connecting the ceramic membrane with pretreatment process.

• Membrane Journal
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• v.22 no.4
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• pp.258-264
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• 2012

In this study, to research effect of coagulation bath and composition of dope solution, polysulfone flat sheet membrane was fabricated by phase inversion method. PEG and PVP were used as additive. Concentration of polymer and additive, composition of coagulation bath was controlled to prepare flat sheet membrane. And then the morphology and water flux of prepared membrane were measured by FE-SEM and water flux testing apparatus. The highest value of water flux was measured at the membrane prepared under a 15 wt% PSF, 25 wt% PEG conditions, and water as coagulation bath. The pure water flux of the membrane composed of PSf/PEG was drastically decreased with increasing amount of DMAc. We confirmed that change of amount in additive and composition in coagulation bath influence the morphology and water flux performance of the membrane.

• Membrane Journal
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• v.26 no.2
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• pp.166-172
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• 2016

In this study critical permeation flux was measured by the flux-step method with respect to aeration rate. The hollow fiber membrane module which has $85cm^2$ of effective area and $0.4{\mu}m$ nominal pore size was submerged in the activated sludge solution of MLSS 5,000 mg/L. The critical flux for without aeration was measured of $15.2L/m^2{\cdot}h$. However, the critical flux increased from 20.6 to $32.5L/m^2{\cdot}h$ as the aeration rate increased from 100 to 1,000 mL/min.

• Korean Chemical Engineering Research
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• v.45 no.5
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• pp.523-528
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• 2007

The objectives of this research are to investigate the mechanism of coagulation affecting UF, find out the effect of metal salt coagulant on membrane fouling. Either rapid mixing + UF or slow mixing + UF process caused much less flux decline. For PACl coagulant, the rate of flux decline was reduced for both hydrophilic and hydrophobic membrane than alum due to higher formation of flocs. In addition, the rate of flux decline for the hydrophobic membrane was significantly greater than for the hydrophilic membrane, regardless of pretreatment conditions. In general, Coagulation pretreatment significantly reduced the fouling of the hydrophilic membrane, but did little decrease the flux reduction of the hydrophobic membrane. When an Al(III) salt is added to water, monomers, polymers, or solid precipitates may form. Different Al(III) coagulants (alum and PACl) show to have different Al species distribution over a rapid mixing condition. During the rapid mixing period, for alum, formation of dissolved Al(III) (monomer and polymer) increases, but for PACl, precipitates of $Al(OH)_{3(s)}$ increases rapidly. This experimental results pointed out that precipitates of $Al(OH)_{3(s)}$ rather than dissolved Al(III) formation is major factor affecting flux decline for the membrane.