• Title/Summary/Keyword: Melting Range

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Evaluation for Al/Cu bonding by liquefaction after solid phase diffusion in the air

  • Kawakami, Hiroshi;Suzuki, Jippei;Fujiwara, Masanori;Nakajima, Junya;Kimura, Keiko
    • Proceedings of the KWS Conference
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    • 2005.06a
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    • pp.393-395
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    • 2005
  • The bonding for Aluminum and Copper in the air is investigated in this study. This bonding method does not include the special process of removing aluminum oxide films. In case of this bending, each metal Is heated at bonding temperature where is above eutectic temperature of Al-Cu system and below melting point of Aluminum. The liquefaction around the bonding surface occurs after the diffusion at solid state of each metal. This phenomenon is predicted by the temperature range above eutectic temperature of Al-Cu equilibrium phase diagram.

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Production of Ag- Ni fine powder by coprecipitation (공침법을 이용한 Ag-Ni 초미분 제조)

  • Kim, Bong-Seo;Woo, Byung-Chul;Byun, Woo-Bong;Lee, Hee-Woong
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1342-1344
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    • 1994
  • Silver-Nickel alloy has been used as a electrical contact material for low voltage, low current. Since the solubility between Ag and Ni is very low, it is difficult to produce Ag-Ni alloy by using conventional melting method and disperse Ni powder homogeneously in Ag matrix. In this study we have been produced fine Ag-Ni alloy powder by using coprecipitation method. Firstly, we have produced silver-nickel nitrate solution by dissolving the Ag and Ni ingot in nitric acid solution and then, coprecipitate (Ag, Ni)carbonate dropping Ag-Ni nitrate solution to sodium carbonate solution. (Ag, Ni) carbonate is heat-treated in $H_2$ atmosphere, $400^{\circ}C$ and it has been analysed by TGA, SEM, XRD, ICP. It is represented Silver-Nickel alloy powder in the particle range of $0.1{\sim}0.5{\mu}m$.

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The Surface Tension of Liquid Iodine (액체 요오드의 표면장력)

  • Kim Sungwan;Chang Seihun
    • Journal of the Korean Chemical Society
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    • v.9 no.2
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    • pp.110-112
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    • 1965
  • The surface tension of liquid iodine was measured by differential capillary rise method at various temperatures above the melting point. A paraffin bath with mercury regulator was used to maintain constant temperature. The height of the meniscus of liquid iodine in the capillary tube was measured by a travelling microscope. The measured values of surface tensions at $125.0^{\circ},135.0^{\circ}, 145.0^{\circ}$ and $155.0^{\circ}$ were 36.88, 35.87, 34.83 and 34.04 dyne/cm, respectively. Calculated Eotvos constant from the surface tension, data. experimentally obtained, were consistent through the temperature range.

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A Partition Function for Liquid Metals (液體金屬의 常態和)

  • Kim, Wan-Kyue
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.36-46
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    • 1962
  • The author assumes that pure liquid metal is composed of molecular oscillators whose energy states are classified into two subgroups, i.e., A and B states, each being accesible to either one of the two sorts of lattice sites. The partition function involves constants characteristic of substance, which are obtainable from the Debye characteristic temperature assigned to its solid state. Calculation has been made for the various thermodynamic properties such as the vapor pressure, the entropy, and the heat capacity of liquid metals of GroupⅠelements over the temperature range from the melting points to the boiling points. The theoretical values thus obtained are in good accordances with those observed, within experimental error, although a slight derivation is observed in the atomic heat capacity.

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Fabrication of Low Temperature Cofired Ceramic (LTCC) Chip Couplers for High Frequencies ; II. Effect of Sintering Process on Ag Diffusion (고주파용 저온 동시소성 세라믹(LTCC)칩 커플러 제조: II. Ag 이온 확산에 대한 소결공정의 영향)

  • 이선우;김경훈;심광보;구기덕
    • Journal of the Korean Ceramic Society
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    • v.36 no.5
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    • pp.490-496
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    • 1999
  • The sintering behavior of LTCC (low temperature cofired ceramics) chip couplers was investigated in relation with Ag diffusion at the interface of glass ceramic substrate-Ag electrode. Sintering temperature was in the range of 825$^{\circ}C$-975$^{\circ}C$. The commercial green sheet and silver electrode were used. Below 875$^{\circ}C$ the diffusion of the Ag ion into the substrate and the penetration of glassy phases into the electrode occurred due to an increase of fluidity. Thus the lectrode line was severely deformed and damaged. At 975$^{\circ}C$ the transformation of crystalline phases into glassy phases and the melting of the Ag electrode resulted in the diffusion of the considerable amount of Ag ions.

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Viscoelastic and Gelation Studies of SEBS Thermoplastic Elastomer in Different Hydrocarbon Oils

  • Kim Jin-Kuk;Paglicawan Marissa A.;Balasubramanian Maridass
    • Macromolecular Research
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    • v.14 no.3
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    • pp.365-372
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    • 2006
  • Poly[styrene-b-(ethylene-co-butylene)-b-styrene](SEBS) triblock copolymer was studied by dissolving the ethylene butylene midblock in selective hydrocarbon oils. These oils differ in their aromatic, paraffinic and naphthenic content. Dynamic rheological studies showed that the storage modulus (G') exceeded the loss modulus (G') for all the gels over the entire range of frequency, thereby confirming them as physical gels. However, the behavior of G' and G' as a function of frequency depended primarily on the oil type. The gelation melting temperature decreased drastically with increased oil aromaticity. Small angle X-ray scattering studies revealed that the maximum interdomain interference shifted to a higher angle depending on the composition and type of hydrocarbon oil.

Synthesis of Blue Emission Hydrazone Derivatives for Organic Electroluminescence (유기 EL용 청색 발광 히드라존 유도체의 합성)

  • Chung, Pyung-Jin;Lim, Hoi-Deuk
    • Korean Journal of Materials Research
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    • v.13 no.8
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    • pp.514-518
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    • 2003
  • As a fundamental study on organic electroluminescence(EL), blue emitting materials were synthesized and characterized. Individual blue colored hydrazone derivatives were synthesized from the reaction of aldehydes (phthalaldehyde, isophthalaldehyde) with the corresponding amnios (1-methyl -1-phenylhydrazine, 1,1-diphenylhydrazine hydrochloride). Recrystallization of hydrazones from chloroform revealed the melting temperature within $142∼156^{\circ}C$. Photoluminescence(PL) analysis on each hydrazone showed that emission range were blue(458∼478 nm). The structure of obtained hydrazones were elucidated by FT-IR, $^1$H-NMR and C, H, N elemental analyzer.

Effects of sintering conditions of (Cd+Te) films on the properties of sintered CdS/CdTe solar cells ((Cd+Te)막의 소결조건이 CdS/CdTe 태양전지의 특성에 미치는 영향)

  • 노재성;임호빈
    • Electrical & Electronic Materials
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    • v.1 no.1
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    • pp.26-34
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    • 1988
  • Sintered CdS/CdTe solar cells have been farbricated by coating a (Cd+Te) slurry on sintered CdS films followed by the sintering at 625.deg.C for one hour with various heating rates. When cadmium and tellurinm powders are used instead of CdTe powder to form CdS/CdTe junction, CdTe is formed in the temperature range of 290.deg.C-400.deg.C. The microstructure of the CdTe films depends strongly on the heating rate of the sintering due to the low melting temperature and the high vapor pressure of the elemental Cd and Te. An optimum heating rate obtain CdTe films with uniform and dense microstructure which, in turn, improves the efficiency of the sintered CdS/CdTe solar cells. All-polycrystalline CdS/CdTe solar cells with an efficiency of 9.57% under 50mW/cm$^{2}$ tungsten light have been farbricated by using a heating rate of 14.deg.C/min.

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Characteristics of a superconductive fuse according to applied voltages (초전도 퓨즈의 전압별 특성)

  • Choi, Hyo-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05b
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    • pp.169-172
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    • 2004
  • We present the basic properties of a superconducting current limiting fuse (SCLF) based on YBCO/Au films. The SCLFs consists of YBCO stripes covered with Au layers for current shunt. Under the source voltage of 100 $V_{rms}$, the longer the duration time of fault current was, the shorter its discharge time was. The duration time of fault current and its discharge time were reduced by increased voltages in the range of 200 - 300 $V_{rms}$. We thought that this was because the quench propagation was limited by local melting generated with higher voltage.

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A New Trend in the Sol-Gel Method and Thin Films from Metal Alkoxides

  • Soh, Deawha;Korobova, N.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.814-819
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    • 2000
  • The progress in the field of electronic materials has been especially significant for applications involving a range of electrical properties. Its importance is increasing with the increasing demand for integrated circuits. The sol-gel technique has been used for many years, and the metal alkoxides have featured prominently as source materials. The method consist of making a homogeneous solution of the component metal alkoxides in a suitable solvent, usually the parent alcohol; and then causing the hydrolysis under controlled conditions to produce a gel containing the hydrated metal oxide. The gel is then dried, and fired to produce a ceramic or glassy material at a temperature much lower than that required by the conventional melting process. This project consists of important theoretical considerations, processing techniques and applications related to electrophoresis derived thin films. In the electrophoretic process a metal alkoxide solution is gelled through hydrolysis-polymerization and converted the gel thin layer to an oxide by heating at relatively low temperatures.

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