• Title/Summary/Keyword: Melt-spinning

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Effects of Spinning Speed and Heat Treatment on the Mechanical Property and Biodegradability of Polylactic Acid Fibers (제사속도와 열처리에 따른 polylactic acid 섬유의 물성 및 생분해성 변화)

  • Park Chung-Hee;Hong Eun-Young
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.4 s.152
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    • pp.607-614
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    • 2006
  • This study was carried out to suggest the optimal spinning process condition which provides a proper range of tenacity and biodegradability as textile fibers. The effects of the melt spinning speed and heat treatment on the mechanical property and biodegradability of polylactic acid fiber were investigated. Polylactic acid(PLA) was spun in a high spinning speed of $2000{\sim}4000m/min$. Each specimen was heat-treated at $100^{\circ}C$ during 30min. Mechanical properties such as breaking stress and the degree of crystallinity were evaluated using WAXS. Biodegradability was estimated from the decrease of breaking stress, weight loss, and the degree of crystallinity after soil burial. Experimental results revealed that heat treated specimens showed higher breaking stress than untreated specimens, but the increase was not so high as was expected from the remarkable change of crystallinity by heat treatment. It was concluded that breaking stress was more influenced by spinning speed than heat treatment. In the soil burial test, however biodegradability calculated from weight loss was more influenced by heat treatment than spinning speed.

Effects of Spinning Conditions on Properties of Polyester Yarn Prepared using an Ultra-high-speed Melt Spinning Technique Equipped with a Steam Chamber

  • Ho, Yo-Seung;Kim, Hak-Yong;Jin, Fan-Long;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3252-3258
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    • 2010
  • In this study, the effects of the various parameters of spinning and drawing processes on the properties of polyester full drawn yarn (FDY) prepared by steam processing during high-speed spinning were investigated using several techniques. The wet shrinkage ratio of the FDY was able to be manipulated by controlling the temperature and draw ratio. The FDY made using the steam high speed spinning technique exhibited identical properties (such as tenacity, elongation, and wet shrinkage ratio) to that of regular FDY, made using the spin-draw process. FDY prepared using the steam process during high-speed spinning showed excellent dyeability. The dye pick-up of the polyester yarn spun at high-speed spinning was found to be improved when dyed under an atmospheric pressure of $100^{\circ}C$. This result was the same as regular FDY dyed under a high pressure of $130^{\circ}C$.

A Study on the Microstructures and High Temperature Tensile Properties of Ni-base Superalloy Melt-Spun Ribbons (Ni 기 초합금 급냉응고 리본의 미세구조와 고온 인장특성에 관한 연구)

  • Han, Chang-Suk
    • Journal of the Korean Society for Heat Treatment
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    • v.27 no.4
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    • pp.180-184
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    • 2014
  • In order to make clear relationship between high temperature tensile properties and fine microstructure of rapidly solidified cast-type Ni-base superalloys without heat treatment required for consolidation process, tensile test was carried out by changing strain rate from $5{\times}10^{-5}s^{-1}$ to $2{\times}10^{-2}s^{-1}$ and test temperature from $900^{\circ}C$ to $1050^{\circ}C$ using IN738LC and Rene'80 melt-spinning ribbons by twin roll process which were superior to ribbons by single roll process from the viewpoint of structure homogeneity. The dependence of tensile strength on strain rate and test temperature was studied and strain rate sensitivity, m, were estimated from tensile test results. From this study, it was found that tensile strength was influenced by ${\gamma}^{\prime}$ particle diameter, test temperature and strain rate, and m of ribbons exhibited above 0.3 over $950^{\circ}C$.

Effects of Annealing on Structure and Properties of TLCP/PEN/PET Ternary Blend Fibers

  • Kim, Jun-Young;Seo, Eun-Su;Kim, Seong-Hun;Takeshi Kikutani
    • Macromolecular Research
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    • v.11 no.1
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    • pp.62-68
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    • 2003
  • Thermotropic liquid crystalline polymer (TLCP)/poly(ethylene 2,6-naphthalate) (PEN)/poly(ethylene terephthalate) (PET) ternary blends were prepared by melt blending, and were melt-spun to fibers at various spinning speeds in an effort to improve fiber performance and processability. Structure and property relationship of TLCP/PEN/PET ternary blend fibers and effects of annealing on those were investigated. The mechanical properties of ternary blend fibers could be significantly improved by annealing, which were attributed to the development of more ordered crystallites and the formation of more perfect crystalline structures. TLCP/PEN/PET ternary blend fibers that annealed at 18$0^{\circ}C$ for 2 h, exhibited the highest values of tensile strength and modulus. The double melting behaviors observed in the annealed ternary blend fibers depended on annealing temperature and time, which might be caused by different lamellae thickness distribution as a result of the melting-reorganization process during the DSC scans.

Fabrication of PLA/TiO2 nanofibers using melt-electro-spinning (용융전기방사를 이용한 PLA/TiO2 나노섬유의 개발)

  • Hwang, Ji-Young;Kim, Hui-Jin;Park, No-Hyung;Huh, Hoon;Park, Choon-Keun;Yoon, Jong-Won
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.3
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    • pp.124-128
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    • 2011
  • Electrospun webs have been widely investigated for applying to drug delivery system (DDS) because of their high specific surface area and high porosity. In this study, the composite webs of PLA (poly(lactic acid)) and $TiO_2$ were fabricated by melt-electro-spinning method for applying to drug delivery system. The morphologies of PLA/$TiO_2$, webs were observed using scanning electron microscope (SEM) and field emission transmission electron microscope (FE-TEM). The crystal structures of PLA/$TiO_2$ composite webs were confirmed by X-ray diffractometer (XRD).