• Title/Summary/Keyword: Melt Layer

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Superconductor characteristics of BSCCO spray films by Heat treatment (열처리에 따른 BSCCO 용사피막의 초전도특성)

  • Do, Hyeong-Jun;Park, Gyeong-Chae
    • Proceedings of the KWS Conference
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    • 2007.11a
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    • pp.282-284
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    • 2007
  • The superconductor characteristics of BSCCO spray films by Heat treatment was studied. $Bi_2Sr_2CaCu_2O_x$(Bi-2212) is high-Tc superconductor(HTS) coatings have been prepared by Heat treatment. Where high current carrying capabilities are required and therefore thick film and bulk material are called for, the Bi2Sr2Ca1Cu2O8-d(Bi-2212)compound has evoleved as one of the most promising. and the Bi-2212 HTS coating layer is synthesized through the peritectic reaction between Sr-Ca-Cu oxide coating layer and Bi-Cu oxide coating layer by partial melting process. The superconducting characteristics depends on the spray distance which was related to the spray particle melt. The Bi-2212 HTS layer consists of the whisker growth and secondary phase in 2212 layer were observed.

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Study on the characteristics of transition metals for TSSG process of SiC single crystal (SiC 단결정의 TSSG 공정을 위한 전이금속 특성 연구)

  • Lee, Seung-June;Yoo, Yong-Jae;Jeong, Seong-Min;Bae, Si-Young;Lee, Won-Jae;Shin, Yun-Ji
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.2
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    • pp.55-60
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    • 2022
  • In this study, a heat treatment experiment was conducted to select a new melt composition that can easily control the unintentionally doped nitrogen (N-UID) without degrading the SiC single crystal quality during TSSG process. The experiment was carried out for about 2 hours at a temperature of 1900℃ under Ar atmosphere. The used melt composition is based on either Si-Ti 10 at% or Si-Cr 30 at%, and also Co or Sc transition metals, which are effective for carbon solubility, were added at 3 at%, respectively. After the experiment, the crucible was cross-sectionally cut, and evaluated the Si-C reaction layer on the crucible-melt interface. As a result, with Sc addition, Si-C reaction layers uniformly occurred with a Si-infiltrated layer (~550 ㎛) and a SiC interlayer (~23 ㎛). This result represented that the addition of Sc is an effective transition metal with high carbon solubility and can feed carbon sources into the melt homogeneously. In addition, Sc is well known to have low reactivity energy with nitrogen compared to other transition metals. Therefore, we expect that both growth rate and Nitrogen UID can be controlled by Si-Sc based melt in the TSSG process.

Numerical Analysis of Residual Stresses and Birefringence in Injection/Compression Molded Center-gated Disks (II) - Effects of Processing Conditions - (사출/압축 성형 Center-gated 터스크에서의 잔류 응력과 복굴절의 수치 해석 (II) - 공정조건의 영향 -)

  • Lee, Young-Bok;Kwon, Tai-Hun;Yoon, Kyung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.11
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    • pp.2355-2363
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    • 2002
  • The accompanying paper, Part 1, has presented the physical modeling and basic numerical analysis results of both the flow-induced and thermally-induced residual stress and birefringence in injection molded center gated disks. The present paper, Part II, has attempted to investigate the effects of various processing conditions of injection/compression molding process on the residual stress and birefringence. The birefringence is significantly affected by injection melt temperature, packing pressure and packing time. Birefringence in the shell layer increases as melt temperature gets lower. The inner peak of birefringence increases with packing time and packing pressure. On the other hand, packing pressure, packing time and mold wall temperature affect the thermally-induced residual stress rather significantly in the shell layer, but insignificantly in the core region. Injection/compression molding has been found to reduce the birefringence in comparison with the conventional injection molding process. In particular, mold closing velocity and initial opening thickness in the compression stage of injection/compression molding process have significant effect on the flow-induced birefringence, but not on tile thermal residual stress and the thermally induced birefringence.

Morphology and Electrical Conductivity of PS/PMMA/SMMA Blends Filled with Carbon Black

  • Lee, Moo-Sung;Ha, Min-Gyu;Ko, Hyun-Jin;Yang, Kap-Seung;Lee, Wan-Jin;Park, Min
    • Fibers and Polymers
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    • v.1 no.1
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    • pp.32-36
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    • 2000
  • An alternative strategy to .educe the percolation threshold of carbon black (CB) in polymer blends was investigated using random copolymer ternary blends of polystyrene (PS), poly(methyl methacrylate)(PMMA), and a styrene-methyl methacrylate random copolymer (SMMA). The target morphology was to selectively locate CB particles in the encapsulating layer of SMMA during melt mixing. The CB used in this study is BP-2000 from Cabot and has a strong selective affinity to PS. Even when the CB was premixed with SMMA, it moves to the PS phase during the melt mixing. However, we also observed the CB particles located at the interface between SMMA and PS phases. Through this study it is found that the interaction between polymers and CB particles is critical for selectively localizing CB particles in multi-component polymer blends. Although appropriate processing condition may retard the movement of CB particles to the polymer phase with affinity, it cannot prevent it completely and locate them to the SMMA phase, which is not thermodynamically favored. To locate CB particles in an encapsulating layer of ternary polymer blends, first of all, polymers forming it should have selective affinity to CB.

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PHASE FIELD MODELING OF CRYSTAL GROWTH

  • Sekerka, Robert F.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.139-156
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    • 1996
  • The phase field model is becoming the model of choice for the theoretical study of the morphologies of crystals growth from the melt. This model provides an alternative approach to the solution of the classical (sharp interface) model of solidification by introducing a new variable, the phase field, Ø, to identify the phase. The variable Ø takes on constant values in the bulk phases and makes a continuous transition between these values over a thin transition layer that plays the role of the classically sharp interface. This results in Ø being governed by a new partial differential equation(in addition to the PDE's that govern the classical fields, such as temperature and composition) that guarantees (in the asymptotic limit of a suitably thin transition layer) that the appropriate boundary conditions at the crystal-melt interface are satisfied. Thus, one can proceed to solve coupled PDE's without the necessity of explicitly tracking the interface (free boundary) that would be necessary to solve the classical (sharp interface) model. Recent advances in supercomputing and algorithms now enable generation of interesting and valuable results that display most of the fundamental solidification phenomena and processes that are observed experimentally. These include morphological instability, solute trapping, cellular growth, dendritic growth (with anisotropic sidebranching, tip splitting, and coupling to periodic forcing), coarsening, recalescence, eutectic growth, faceting, and texture development. This talk will focus on the fundamental basis of the phase field model in terms of irreversible thermodynamics as well as it computational limitations and prognosis for future improvement. This work is supported by the National Science Foundation under grant DMR 9211276

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The Effects of AI-Alloying Elements on the Melt Oxidation - III. Oxidation Behavior of Pentad Alloy- (AI 합금의 원소가 용융산화에 미치는 영향 -lll. 오원계 합금의 산화거동-)

  • Ha, Yong-Soo;Kim, Chul-Soo;Kang, Chung-Yun;Kim, Il-Soo;Cho, Chang-Hyun
    • Korean Journal of Materials Research
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    • v.8 no.8
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    • pp.672-677
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    • 1998
  • The following work examines the growth rate and microstructure of the $AI_2O_3$-composite formation by melt oxdation of pentad AI-alloys. The I weight % of each metal elements Cu and Ni were added to AI-IMg-3Si-3Zn and AI-IMg- 3Si-5Zn alloys. The diffenent pentad AI-alloys were oxidized 20 hours long at 1373K and 1473K. The oxidation rates were determined by observing the weight gain. The macro- and microstructure of formed oxide layer were examined by optical microscopy. The AI-IMg-3Si-5Zn-lCu alloy revealed the best oxidation behavior, but formedoxide layer was inhomogeneous.The oxidation rate were accelerated, and the uniform growth of the oxide layer with fine microstructure were obtained by putting a thin layer of $SiO_2$ on the surface of the alloy.

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A Study on the Combustion Characteristics of the Automotive Interior Materials (자동차 내장재의 연소 특성에 관한 연구)

  • Kim, H.;Kang, Y.G.;Park, H.J.
    • Journal of the Korean Society of Safety
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    • v.13 no.2
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    • pp.88-95
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    • 1998
  • Five parts of the automotive interior materials were sampled to determine their combustion characteristics. Oxygen Indexer, Smoke chamber, Differential Scanning Calorimeter(DSC) were used as the analysis apparatus. All LOI values of samples appear less than 21. The combustion phenomena of the interior materials primarily depends on properties of each layer material. The amount of generated smoke are reached the maximum value within 30 - 90sec after ignition. The experimental results of combustion characteristics and DSC of H/Line also indicated that the layer of foam was melt first and it caused the propagation of flame through the sample. The combustion characteristics of multi-layer materials primarily depends on thermal characteristics of single layer material.

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Frozen Layer Effect on Internal Cavity Pressure during Injection Molding (사출성형 공정에서 고화층이 캐비티 압력에 미치는 영향)

  • Lee H.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.474-479
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    • 2005
  • Experimental and theoretical studies of internal cavity pressure during injection molding of a spiral tube cavity were carried out. The frozen layer thickness and the evolution of internal cavity pressure were calculated using a commercial software (C-MOLD). The evolution of the internal cavity pressure was recorded during injection molding of polystyrene into a spiral tube mold. To explain the differences observed between the calculated and measured internal cavity pressure, a pressure correction factor (PCF) was introduced based on the plane stress theory. This factor was determined by analyzing the stress state in the melt and calculating the frozen layer thickness near the mold wall. The corrected and experimental pressures have been compared to validate the applicability of the pressure correction factor.

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The combustion characteristics of vehicle upholsteries

  • Park, Hyung-Ju;Kang, Young-Goo;Kim, Hong
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.211-218
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    • 1997
  • Five parts of vehicle upholsteries were sampled to determine its combustion characteristics. Oxygen Indexer, Smoke chamber, Differential Scanning Calorimetry(DSC) are applied as the analysis apparatus. All LOI values of samples appear less than 21. The combustion phenomena of vehicle upholster primarily depends on properties of each layer material. The amount of smoke generated is the experiment reached the maximum value within 30-90sec after ignition. The experimental results of combustion characteristics and DSC of H/Line also indicated that the layer of foam was melt first and it caused the propagation of flame through the sample. The combustion characteristics of multi layer materials primarily depend on thermal characteristic of single layer material.

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