• Title/Summary/Keyword: Matrix structures

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Gradient Structures and Surface Composition of Polypropylene/Ethylene-Propylene Rubber Blends (폴리프로필렌/에틸렌-프로필렌 고무 블렌드 경사구조 및 표면조성)

  • Kim, Seog Je;Lee, Sung-Goo;Lee, Jae Heung;Choi, Kil-Yeong
    • Journal of Adhesion and Interface
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    • v.2 no.4
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    • pp.24-31
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    • 2001
  • Polypropylenes(PP) with different melt index values were mixed with ethylene-propylene rubber(EPR) or ethylene-propylene diene monomer rubber(EPDM) and an ethylene copolymer containing carboxylic acid group in a twin screw extruder. Then test specimens were prepared from the pellets of the blends with an injection molding machine. The mechanical properties and morphology of fractured surfaces were measured. Relative peak intensities of carboxylic acid group on the specimen surface were measured with an attennuated total reflection infrared spectrometer (ATR-IR) and compared with each other. The blend specimens were found to have the gradient morphology of rubber domains in PP matrix in the core region and PP skin layer. The blends containing PP of higher melt index showed greater content of ethylene copolymer containing carboxylic acid on the surface when the relative peak intensities of ATR-IR for carboxylic acid were compared. As the melt index values were increased, the decrease tendency in mechanical propeties such as tensile strength and impact strength was more significant for PP/EPR blends than PP/EPDM blends.

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Identification of a novel triterpene saponin from Panax ginseng seeds, pseudoginsenoside RT8, and its antiinflammatory activity

  • Rho, Taewoong;Jeong, Hyun Woo;Hong, Yong Deog;Yoon, Keejung;Cho, Jae Youl;Yoon, Kee Dong
    • Journal of Ginseng Research
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    • v.44 no.1
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    • pp.145-153
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    • 2020
  • Background: Panax ginseng Meyer (Araliaceae) is a highly valued medicinal plant in Asian regions, especially in Korea, China, and Japan. Chemical and biological studies on P. ginseng have focused primarily on its roots, whereas the seeds remain poorly understood. This study explores the phytochemical and biological properties of compounds from P. ginseng seeds. Methods: P. ginseng seeds were extracted with methanol, and 16 compounds were isolated using various chromatographic methods. The chemical structures of the isolates were determined by spectroscopic data. Antiinflammatory activities were evaluated for triterpene and steroidal saponins using lipopolysaccharide-stimulated RAW264.7 macrophages and THP-1 monocyte leukemia cells. Results: Phytochemical investigation of P. ginseng seeds led to the isolation of a novel triterpene saponin, pseudoginsenoside RT8, along with 15 known compounds. Pseudoginsenoside RT8 exhibited more potent antiinflammatory activity than the other saponins, attenuating lipopolysaccharide-mediated induction of proinflammatory genes such as interleukin-1β, interleukin-6, inducible nitric oxide synthase, cyclooxygenase-2, and matrix metalloproteinase-9, and suppressed reactive oxygen species and nitric oxide generation in a dose-dependent manner. Conclusion: These findings indicate that pseudoginsenoside RT8 has a pharmaceutical potential as an antiinflammatory agent and that P. ginseng seeds are a good natural source for discovering novel bioactive molecules.

Effects of Carbide Morphology and Heat Treatment on Abrasion Wear Resistance of Chromium White Cast Irons (합금크롬주철의 탄화물형상 및 열처리가 내마모성에 미치는 영향)

  • Yu, Sung-Kon;Matsubara, Yasuhiro
    • Korean Journal of Materials Research
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    • v.12 no.5
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    • pp.407-413
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    • 2002
  • Eutectic high chromium cast irons containing 17%Cr and 26%Cr were produced for this research by making each of them solidify unidirectionally. Abrasion wear test against SiC or $Al_2$O$_3$bonded paper was carried out using test pieces cut cross-sectionally at several distances from the chill face of castings. The wear resistance was evaluated in connection with the parameters such as eutectic colony size($E_w$), area fraction of boundary region of the colony($S_B$) where comparatively large massive chromium carbides are crystallized and, average diameter of chromium carbides in the boundary region($D_c$). The wear rate($R_w$), which is a gradient of straight line of wear loss versus testing time, was influenced by the type and the particle size of the abrasives. The $R_w$ value against SiC was found to be larger than that against A1$_2$O$_3$under the similar abrasive particle size. In the case of SiC, the $R_w$ value increased with an increase in the particle size. The $R_w$ value also increased as the eutectic colony size decreased, and that of the 17%Cr iron was larger than that of the 26%Cr iron at the same $E_w$ value. Both of the $S_B$ and $D_c$ values were closely related to the $R_w$ value regardless of chromium content of the specimens. The $R_w$ values of the annealed specimens were greater than those of the as-cast specimens because of softened matrix structures. As for the relationship between wear rate and macro-hardness of the specimens, the hardness resulting in the minimum wear rate was found to be at 550 HV30.

Computational Algorithm for Nonlinear Large-scale/Multibody Structural Analysis Based on Co-rotational Formulation with FETI-local Method (Co-rotational 비선형 정식화 및 FETI-local 기법을 결합한 비선형 대용량/다물체 구조 해석 알고리듬 개발)

  • Cho, Haeseong;Joo, HyunShig;Lee, Younghun;Gwak, Min-cheol;Shin, SangJoon;Yoh, Jack J.
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.9
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    • pp.775-780
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    • 2016
  • In this paper, a computational algorithm of an improved and versatile structural analysis applicable for large-size flexible nonlinear structures is developed. In more detail, nonlinear finite element based on the co-rotational (CR) framework is developed. Then, a finite element tearing and interconnecting method using local Lagrange multipliers (FETI-local) is combined with the nonlinear CR finite element. The resulting computational algorithm is presented and applied for nonlinear static analyses, i.e., cantilevered beam and multibody structure. Finally, the proposed analysis is evaluated with regard to its parallel computation performance, and it is compared with those obtained by serial computation using the sparse matrix linear solver, PARDISO.

Strain-Hardening Cementitious Composites with Low Viscosity Suitable for Grouting Application (그라우팅에 적합한 점성을 갖는 변형률 경화 시멘트 복합재료)

  • Lee, Bang Yeon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.1
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    • pp.55-63
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    • 2012
  • This paper presents materials and processing technique to manufacture low viscous strain-hardening cementitious composite which is suitable for structures requiring low viscosity of materials. The micromechanics and fracture mechanics tools coupled with processing techniques were adopted to achieve low viscosity of composites as well as high tensile strain capacity. Optimal volume and length of fibers and interfacial properties between fibers and matrix for composites with tensile strength of 2~3MPa were determined on the basis of the micromechanical analysis and the steady-state cracking theory. Then six mixtures were determined and the experiment was carried out to evaluate the viscosity and uniaxial tensile performance of those. From the test results, it is verified that the strain-hardening cementitious composite with low viscosity suitable for grouting applications in fresh state as well as high ductility over 1.5% in hardened state can be feasible.

Improvement of Flexural Structural Performance and Applied Section Shape for Sound Proof Wall Structures Using Glass Fiber Reinforced Polymer(GFRP) (GFRP를 활용한 도로 방음벽 구조물의 구조성능 및 단면형상 개선에 관한 연구)

  • Jung, Woo-Young;Choi, Hyun-Kyu
    • International Journal of Highway Engineering
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    • v.11 no.4
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    • pp.9-15
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    • 2009
  • This research presents the structural performance and an improving technique for flexural capacity of road safety facilities based on the damage cases by wind pressure. Among road safety facilities, a support frame of soundproofing walls is considered as a prototype structure and its corresponding structural behaviors and section design are performed mainly by analytical and experimental studies. On the basis of analytical results, glass fiber reinforced polymer(GFRP) with an epoxy matrix which is high stiffness-to-weight ratio was used for applied one of strengthening techniques and their results shows that support frame strengthened by GFRP is the most effective compared to other cases proposed in this research for advancing its flexural improvement, Finally, optimum section design was performed analytically to evaluate wind-resistance capacity and its result would be very useful for developing a practical design guideline for Road safety facilities under strong wind.

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Improved Stability Design of Plane Frame Members (평면프레임 구조의 개선된 좌굴설계)

  • Kim, Moon Young;Song, Ju Young;Kyung, Yong Soo
    • Journal of Korean Society of Steel Construction
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    • v.18 no.2
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    • pp.225-237
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    • 2006
  • Based on the study conducted by Kim et al. (205a, b), an improved stability design method for evaluating the effective buckling lengths of beam-column members is proposed herein, using system elastic/inelastic buckling analysis and second-order elastic analysis. For this purpose, the stress-strain relationship of a column is inversely formulated from the reference load-carrying capacity proposed in design codes, so as to derive the tangent modulus of a column as a function of the slenderness ratio. The tangent stiffness matrix of a beam-column element is formulated using the so-called "stability functions," and elastic/inelastic buckling analysis Effective buckling lengths are then evaluated by extending the basic concept of a single simply-supported column to the individual members as one component of a whole frame structure. Through numerical examples of several structural systems and loading conditions, the possibilities of enhancement in stability design for frame structures are addressed by comparing their numerical results obtained when the present design method is used with those obtained when conventional stability design methods are used.

Properties of Polymer-Modified Mortar with Styrene-Butyl Acrylate and Styrene Butadiene Rubber (S/BA와 SBR을 혼입한 폴리머 시멘트 모르타르의 특성)

  • Mun, Kyung-Ju;Song, Hae-Ryong;Hyung, Won-Gil
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.555-560
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    • 2008
  • Polymer-modified mortars have been largely used as paving materials, flooring, waterproofing material, adhesives, anticorrosive linings, deck coverings, and other various materials. The various types and properties of the mixed polymer largely affect the characteristics of polymer-modified mortar that has been mixed with polymer latexes. Consequently, its application purposes are varied according to these properties. This paper investigates the typical properties of polymer-modified mortars that contain styrene and butyl acrylate latexes and styrene butadiene rubber. They are then tested to obtain air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the superior flexural strength of polymer-modified mortars is obtained at a S/BA-2 and a polymer-cement ratio of 20%. And, the water absorption and chloride ion penetration depth are greatly affected by the polymer-cement ratio rather than the types of polymer. In the polymer-modified mortar and concrete structures, aggregates are bound by such a co-matrix phase, resulting in the superior properties of polymer-modified mortar and concrete compared to conventional mortar and concrete.

Tungsten oxide interlayer for hole injection in inverted organic light-emitting devices

  • Kim, Yun-Hak;Park, Sun-Mi;Gwon, Sun-Nam;Kim, Jeong-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.380-380
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    • 2010
  • Currently, organic light-emitting diodes (OLEDs) have been proven of their readiness for commercialization in terms of lifetime and efficiency. In accordance with emerging new technologies, enhancement of light efficiency and extension of application fields are required. Particularly inverted structures, in which electron injection occurs at bottom and hole injection on top, show crucial advantages due to their easy integration with Si-based driving circuits for active matrix OLED as well as large open area for brighter illumination. In order to get better performance and process reliability, usually a proper buffer layer for carrier injection is needed. In inverted top emission OLED, the buffer layer should protect underlying organic materials against destructive particles during the electrode deposition, in addition to increasing their efficiency by reducing carrier injection barrier. For hole injection layers, there are several requirements for the buffer layer, such as high transparency, high work function, and reasonable electrical conductivity. As a buffer material, a few kinds of transition metal oxides for inverted OLED applications have been successfully utilized aiming at efficient hole injection properties. Among them, we chose 2 nm of $WO_3$ between NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] and Au (or Al) films. The interfacial energy-level alignment and chemical reaction as a function of film coverage have been measured by using in-situ ultraviolet and X-ray photoelectron spectroscopy. It turned out that the $WO_3$ interlayer substantially reduces the hole injection barrier irrespective of the kind of electrode metals. It also avoids direct chemical interaction between NPB and metal atoms. This observation clearly validates the use of $WO_3$ interlayer as hole injection for inverted OLED applications.

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Fluorescence Properties of Size Fractions of Dissolved Organic Matter Originated From Different Sources (생성 기원에 따른 용존 자연유기물질 분자량별 형광특성 비교)

  • Hur, Jin;Park, Min-Hye
    • Journal of Korean Society on Water Environment
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    • v.23 no.4
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    • pp.482-489
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    • 2007
  • Fluorescence properties and carbohydrate content were investigated using ultrafiltrated size fractions of dissolved organic matters (DOM) originated from different sources. The materials included a treated sewage, an algal organic matter, and a soil leachate, all of which are major constituents of dissolved organic matter in a typical urban river. Four different size fractions were separated from the three sources of each DOM. The size distribution demonstrated that a higher molecular weight fraction was more present in soil leachate compared to two other source DOMs. A higher content of carbohydrates was observed in the following order - algal DOM > treated sewage > soil leachate. A wide range of specific UV absorbance was observed from size fractions of a single source DOM, indicating that aromatic carbon structures are heterogeneously distributed within one source of DOM. The structural heterogeneity was the most pronounced for the soil leachate. The fluorescence index ($F_{450}/F_{500}$) of the treated sewage was similar to that (2.0) typically obtained from autochthonous DOM, suggesting that the treated sewage exhibited autochthonous organic matter-like properties. No protein-like fluorescence intensities were observed for all of the soil leachate size fractions whereas they were observed with two other source DOMs. Based upon the fluorescence peak ratios from fluorescence excitation-emission matrix (EEM), two discrimination indices could be suggested to distinguish three different source DOMs. It is expected that the suggested discrimination indices will be useful to predict the sources of DOM in a typical urban river affected by treated sewage.