• Title/Summary/Keyword: Matrix structure

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Preparation and Characterization of Polysulfone Substrate for Reinforced Composite Membrane Fuel Cell Membrane (연료전지 전해질 복합막 제조를 위한 폴리설폰계 지지체의 제조와 물성)

  • Nam, Sang-Yong;Kim, Deuk-Ju;Hwang, Rae-Young;Kim, Hyoung-Juhn
    • Membrane Journal
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    • v.19 no.1
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    • pp.63-71
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    • 2009
  • In this study, polysulfone which has excellent mechanical and thermal stability with low cost was used for preparing a non-conducting polymer matrix as a reinforced composite membrane for fuel cell application. The membranes were prepared by phase separation method. Polymer concentration and retention time were controlled to investigate the effects on the membrane morphology. The resaltant membranes showed all sponge-like structure independent of polymer concentration. The mechanical and thermal stability were improved with increasing polymer concentration in contrast to the membrane porosity. As a result, the membranes prepared with the retention time for 2 mins using 20 wt% of polymer solution was suitable for a fuel cell compositite membrane providing optimum properties such as approximately 80% of high porosity, 1.3 MPa of tensile strength, and less than 1% of thermal shrinkage both machine and transverse direction.

A Study on the Thermal Behavior and Phase Transformation of Iron-bearing Minerals in Clay of Cheju Island by M ssbauer Effect (M ssbauer 효과에 의한 제주도 찰흙의 함철 광물의 열적 거동과 상변환에 관한 연구)

  • 강동우;김두철;류재연;고정대;홍성락;송관철
    • Journal of the Mineralogical Society of Korea
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    • v.10 no.2
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    • pp.148-161
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    • 1997
  • Based on the X-ray powder diffraction (XRD) and M ssbauer spectroscopy, the thermal behavior and phase transformations of two clays are investigated for raw and fired conditions, which are collected from Kwangryeongli and Ildo district in Cheju Island. M ssbauer spectra at room temperature and 20for two clays show that paramagnetic Fe3- is the structural iron of the layer silicate and ferrihydrite, and superparamagnetic goethite has about 50% of total iron contents. The XRD peaks of hematite for the fired clays appear from 80$0^{\circ}C$ in Kwangryeongli clay and from $600^{\circ}C$ in Ildo district clay, respectively. The structural Fe2+ was completely oxidized into Fe3- at 40$0^{\circ}C$ for Kwangryeongli clay and 50$0^{\circ}C$~$600^{\circ}C$ for Ildo district clay, respectively. The structural Fe2+ was completely oxidized into Fe3- at 40$0^{\circ}C$. For the temperature ranging from 40$0^{\circ}C$ to $700^{\circ}C$~80$0^{\circ}C$, two fired clays exhibit the dehydroxylation of the clay mineral. A disintegration of the clay mineral structure is observed from $700^{\circ}C$~80$0^{\circ}C$ to 110$0^{\circ}C$, followed by the onset and spread of vitrification process. It is also shown that well-crystallized hematite phase is formed at the temperature higher than 110$0^{\circ}C$ and the relative absorption area decreases, which might be related to the recrystallization of alluminosilicate matrix.

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Preparation and Properties of Siloxane Modified EPDM/HDPE/Carbon black Composite (실록산 변성 에틸렌프로필렌 고무/고밀도 폴리에틸렌/카본블랙 복합체의 제조와 물성)

  • Lee, Byoung-Chul;Kang, Doo-Whan
    • Polymer(Korea)
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    • v.31 no.1
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    • pp.80-85
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    • 2007
  • Maleic anhydride (MA) modified ethylene-propylene-diene terpolymer (MEPDM) was pre-pared from solution polymerization. MEPDM-g-PST copolymer was prepared by melt polymerization of male ate d EPDM and quaternary ammonium silyl polydimethylsiloxane -7,7,8,8- tetracyanoquinodimethane (TCNQ) adduct (PST) in internal mixer and MEPDM-g-PST/HDPE/CB (MPEC) was prepared by com-pounding HDPE, MEPDM-g-PST copolymer and carbon black (CB, 5, 10, 15, and 20 phr), and HDPE/ CB (PEC) by compounding HDPE and CB (5, 10, 15, and 20 phr), respectively. The structure of MEPDM-g-PST copolymer was confirmed by measuring the FTIR. The maximum grafting ratio of MA onto EPDM was 2.35%. The thermal and mechanical properties of the composites were measured and dispersion characteristics of CB in matrix show that CB in MPEC was better dispersed than that in PEC composite.

Preparation of an Inorganic Scintillator Loaded Film for the Measurement of Surface Contamination and its Performance Test (표면오염 측정용 무기섬광 함침 필름의 제조 및 성능 평가)

  • 서범경;이근우;임난주;박진호;한명진
    • Journal of Energy Engineering
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    • v.13 no.2
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    • pp.93-100
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    • 2004
  • The smear media possible to sampling and radiation detection was prepared and evaluated for the surface contamination using indirect method. The films were made by impregnating Cerium Activated Yttrium Silicate (CAYS) in a polysulfone membrane. The membranes used solution as a dimethylformamide (DMF) and methylene chloride (MC), polysulfone as a polymer matrix and CAYS as a inorganic scintillator. The proximity membranes were prepared with single- and double-layered structure. The solidified methods were immersion to the nonsolvent bath such at water and ethanol and solvent evaporation. The measurement of the photon produced by interaction with radiation and inorganic scintillator used a photomultiflier tube (PMT), amplifier, and counter. In the comparison with the low background alpha/beta counter, the counter rate using inorganic scintillator proximity membrane for the $\^$14/C surface contamination was about 50%. Also. the $^3$H counting results revealed that the prepared membranes were efficient to monitor the surface contaminated with the low energy be-ray emitter nuclides.

Assessment Framework for Multicriteria Comparison Indicators in Various Electricity Supply Systems (다양한 전력생산 시스템에서 다중기준 비교지표의 평가 체계)

  • Kim Seong-Ho;Kim Tae-Woon
    • Journal of Energy Engineering
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    • v.15 no.1 s.45
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    • pp.74-81
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    • 2006
  • In this study, on the basis of an analytic hierarchy process (AHP) method and through a questionnaire on subjective preference and importance, various power supply systems were comprehensively compared with multiple decision criteria such as environmental, social, healthy, and economic viewpoints and then overall priority was assessed. When a decision-making problem is modelled by a hierarchy structure, the AHP method is regarded as a useful tool for extracting subjective opinions via the aforementioned questionnaire. Here, the overall preferences were obtained by linearly aggregating weighting vector and preference matrix. The energy systems such as nuclear, coal, and LNG power plants were selected because they took share over 90% of domestic electricity supply in Korea. Furthermore, wind power and photovoltaic solar systems were included as representative renewable energy systems in Korea. According to the results of this demonstration study, the following comprehensive comparison indicators were yielded: 1) weighting factors for 4 types of main criteria as well as for 11 types of sub-criteria; 2) preference valuation for 7 types of energy systems under consideration; 3) overall score for each energy systems.

Distributed Data Management based on t-(v,k,1) Combinatorial Design (t-(v,k,1) 조합 디자인 기반의 데이터 분산 관리 방식)

  • Song, You-Jin;Park, Kwang-Yong;Kang, Yeon-Jung
    • The KIPS Transactions:PartC
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    • v.17C no.5
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    • pp.399-406
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    • 2010
  • Many problems are arisen due to the weakness in the security and invasion to privacy by malicious attacker or internal users while various data services are available in ubiquitous network environment. The matter of controlling security for various contents and large capacity of data has appeared as an important issue to solve this problem. The allocation methods of Ito, Saito and Nishizeki based on traditional polynomial require all shares to restore the secret information shared. On the contrary, the secret information can be restored if the shares beyond the threshold value is collected. In addition, it has the effect of distributed DBMS operation which distributes and restores the data, especially the flexibility in realization by using parameters t,v,k in combinatorial design which has regularity in DB server and share selection. This paper discuss the construction of new share allocation method and data distribution/storage management with the application of matrix structure of t-(v,k,1) design for allocating share when using secret sharing in management scheme to solve the matter of allocating share.

Oil Price Forecasting Based on Machine Learning Techniques (기계학습기법에 기반한 국제 유가 예측 모델)

  • Park, Kang-Hee;Hou, Tianya;Shin, Hyun-Jung
    • Journal of Korean Institute of Industrial Engineers
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    • v.37 no.1
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    • pp.64-73
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    • 2011
  • Oil price prediction is an important issue for the regulators of the government and the related industries. When employing the time series techniques for prediction, however, it becomes difficult and challenging since the behavior of the series of oil prices is dominated by quantitatively unexplained irregular external factors, e.g., supply- or demand-side shocks, political conflicts specific to events in the Middle East, and direct or indirect influences from other global economical indices, etc. Identifying and quantifying the relationship between oil price and those external factors may provide more relevant prediction than attempting to unclose the underlying structure of the series itself. Technically, this implies the prediction is to be based on the vectoral data on the degrees of the relationship rather than the series data. This paper proposes a novel method for time series prediction of using Semi-Supervised Learning that was originally designed only for the vector types of data. First, several time series of oil prices and other economical indices are transformed into the multiple dimensional vectors by the various types of technical indicators and the diverse combination of the indicator-specific hyper-parameters. Then, to avoid the curse of dimensionality and redundancy among the dimensions, the wellknown feature extraction techniques, PCA and NLPCA, are employed. With the extracted features, a timepointspecific similarity matrix of oil prices and other economical indices is built and finally, Semi-Supervised Learning generates one-timepoint-ahead prediction. The series of crude oil prices of West Texas Intermediate (WTI) was used to verify the proposed method, and the experiments showed promising results : 0.86 of the average AUC.

A Logit Model for Repeated Binary Response Data (반복측정의 이가반응 자료에 대한 로짓 모형)

  • Choi, Jae-Sung
    • The Korean Journal of Applied Statistics
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    • v.21 no.2
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    • pp.291-299
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    • 2008
  • This paper discusses model building for repeated binary response data with different time-dependent covariates each occasion. Since repeated measurements data are having correlated structure, weighed least squares(WLS) methodology is applied. Repeated measures designs are usually having different sizes of experimental units like split-plot designs. However repeated measures designs differ from split-plot designs in that the levels of one or more factors cannot be randomly assigned to one or more of the sizes of experimental units in the experiment. In this case, the levels of time cannot be assigned at random to the time intervals. Because of this nonrandom assignment, the errors corresponding to the respective experimental units may have a covariance matrix. So, the estimates of effects included in a suggested logit model are obtained by using covariance structures.

THE SELECTION OF GROUND STATIONS FOR IGS PRODUCTS (IGS 산출물 생성을 위한 지상국 선정에 관한 연구)

  • Jung, Sung-Wook;Baek, Jeong-Ho;Bae, Tae-Suk;Jo, Jung-Hyun;Cho, Sung-Ki;Park, Jong-Uk
    • Journal of Astronomy and Space Sciences
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    • v.24 no.4
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    • pp.417-430
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    • 2007
  • The selection of ground stations is one of the essential process of IGS (International GNSS Service) products. High quality GPS data should be collected from the globally distributed ground stations. In this study, we investigated an effect of ground station network selection on GPS satellite ephemeris. The GPS satellite ephemeris obtained from the twelve ground station networks were analyzed to investigate the effect of selection of ground stations. For data quality check, the observations, the number of cycle slips, and multipath of pseudoranges for L1 and L2 were considered. The ideal network defined by Taylor-Karman structure and SOD (Second Order Design) were used to obtain the optimal ground station network.

The Control of Flexible Robot Arm using Adaptive Control Theory (적응제어 이론을 이용한 유연한 로봇팔의 제어)

  • Han, Jong-Kil
    • The Journal of the Korea institute of electronic communication sciences
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    • v.7 no.5
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    • pp.1139-1144
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    • 2012
  • The ration of payload to weight of industrial robot amounts form 1:10 to 1:30. Compared with man who have a ration of 3:1, it is very low. One of the goals for the next generation of robots will be a ration. This might be possible only by developing lightweight robots. When two-link flexible arm is rotated about an joint axis, transverse vibration may occur. In this paper, vibration dynamics of flexible arm is modeled by using Bernoulli-Euler beam theory and Lagrange equation. Using the fact that matrix $\dot{D}-2C$ is skew symmetric, new controllers which have a simplified structure with less computational burden is proposed by using Lyapunov stability theory. We propose deterministic and adaptive control laws for two link flexible arm, and the validity of the proposed control scheme is shown in computer simulation for two-link flexible arm.