• 멤브레인
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• 제25권5호
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• pp.373-384
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• 2015

지난 수십 년 동안, 고분자막은 기체 분리 분야에서 큰 역할을 해왔다. 온실가스의 주범인 이산화탄소를 분리하기 위해서는 더 높은 투과선택도와 장수명 및 대면적 등을 요구한다. 하지만 기존 고분자 분리막들은 투과도와 선택도의 역상관 관계 특징을 지니고 있으며, 무기물질은 투과성능이 우수하지만 가격이 비싸다는 단점이 있다. 최근 많은 연구가 진행되어온 혼합 매질 분리막은 고분자와 무기물질의 이점들을 혼합하여 기체 분리막의 차세대로서 큰 이목을 이끌고 있다. 혼합 매질 분리막은 대칭적인 구조 또는 비대칭적인 구조를 가지고 있으며, 투과량을 증가시키기 위해서는 비대칭적인 구조가 바람직하다. 혼합 매질 분리막에서 가장 중요한 변수로는 무기입자의 균일한 분산과 무기물과 고분자 사이의 좋은 계면을 형성하는 것이다. 최근에 새로운 분류의 다공성 결정성 물질인 금속 유기 구조체(MOF)는 이산화탄소 분리용 소재로써 많은 관심을 끌고 있다. MOF의 한 종류 중, zeolitic imidazolate frameworks (ZIF)는 가장 흔하게 사용되는 무기입자이며 이는 입자의 크기를 작게 만들 수 있으며, $CO_2$를 분리하기에 적절한 기공의 크기를 가지고 있기 때문이다. 이 밖에 혼합 매질 분리막에 사용되는 특정 물질들을 적용하기 위해서는 선택도와 크기, 호환성, 안정성 등을 동시에 최적화시켜야 한다. 이와 같이 본 총설에서는, 혼합 매질 분리막에 관련된 주요 연구내용과 이러한 연구를 수행하는 대표적인 전략들을 소개하였다.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 1997년도 추계학술대회논문집
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• pp.176-181
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• 1997

During a compression molding of continuous fiber reinforced composites, the separation of matrix and fiber is caused by the flow of the molding process. As the characteristics of the products are greatly dependent on the separation, it is very important to clarify the separation in relation to molding condition, degree of needle punching number on the degree of nonhomogeneity are studied.

• 한국세라믹학회지
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• 제23권6호
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• pp.25-32
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• 1986

Phase spearated glass is heterogeneous in microscopic point of view and the heterogeneities affect the structures of glasses. In the present work the phase separation of $BaO-B_2O_3$ glass system was investigated and the effect of $P_2O_5$ on the phase separation and crystallization was also studied in the above system. Experiments such as scanning electron microscopy X-ray diffraction and infrared spectroscopy were performed. Phase separation with $B_2O_3$ rich phase matrix and BaO rich phase droplet was observed for the glasses containing less than 6 mole% of BaO while the opposite morphology of phase separation was found for the glasses containing more than 7 mole% of BaO. Phase separation region was extended up to the glass with 22mole% of BaO when the amount of $P_2O_5$ was increased. The heat-treated glasses crystallized to BaO.$4B_2O_3$$P_2O_5$ hindered the glass from the crystalli-zation.

• 산업기술연구
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• 제15권
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• pp.175-185
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• 1995

Under the new environmental regulations announced by the government, utilities will have to cut their sulfur dioxide emissions by 60% from 1991 levels by the year of 1999. Sulfur dioxide emissions can be reduced prior to combustion by physical, chemical or biological coal cleaning. The new technology of high gradient magnetic separation (HGMS) offers the potential of economic separatoins of a variety of fine, weakly magnetic minerals including inorganic sulfur and many ash-forming minerals from coals. In the present paper, magnetic separation tests have been conducted on Korean anthracite and high-sulfur Chinese coal to investigate the feasibility of these techniques for reducing sulfur content from coals. In wet magnetic separation, the studied operating parameters include particle size, pH, matrix types, feed solids content, feed rate, number of cleaning stages and etc. The results shows that for wet separation, 60~70% of total sulfur was removed from coals with over 80% combustible recovery, on the other hand, for dry separation, 47.6% of total sulfur was removed from coals with 75% recovery.

• 대한전자공학회논문지SP
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• 제44권1호
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• pp.85-93
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• 2007

다채널 암묵 디콘볼루션을 자기상관 값이 큰 신호에 적용할 경우 분리필터행렬의 주대각 성분에 의해서 분리신호의 시간백색화가 발생한다. 이러한 왜곡을 줄이기 위해 분리필터 행렬의 주대각 성분을 강제하거나 선형예측 잔여신호를 이용하여 분리필터 행렬을 구하는 방법들이 제안되었지만 신호자신의 반향성분이나 간섭신호 분리에 있어서 문제점이 발생된다. 본 논문에서는 이러한 문제들을 해결하기 위해서 간섭신호의 분리를 위한 단계와 신호자신의 반향을 감소시키기 위한 단계를 분리하여 처리하는 구조의 다채널 암묵 디콘볼루션 방법을 제안한다. 모의실험 결과 혼합신호에서 간섭신호를 분리해낼 수 있을 뿐만아니라 신호 자신의 반향 또한 감소됨을 확인하였다.

• 멤브레인
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• 제29권1호
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• pp.1-10
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• 2019

Poly(ether block amide) (PEBA)는 이산화탄소 분리에 매우 적합한 상용 블록 공중합체 중 하나이다. 기체분리막의 경우 높은 투과도 뿐 아니라 강한 기계적 강도 또한 필요로 한다. PEBA공중합체의 결정성 폴리아마이드(polyamide) 블록은 기계적 강도를 제공하며 동시에 rubbery한 폴리에테르(polyether) 부분은 이산화탄소와의 친화도를 부여하여 이산화탄소 촉진 수송에 기여한다. PEBA공중합체에서 결정성 상과 rubber한 상의 조성은 기체분리막에 적합하게 조절될 수 있다. PEBA 공중합체를 기반으로 한 분리막은 좋은 투과도를 갖지만 추가적으로 분자체 효과를 이용하여 큰 기체 투과도 손실 없이 분리막의 선택도를 향상시킬 수 있다. 혼합 매질 분리막은 혼합막의 한 종류로서 고분자 매트릭스와 유기 첨가제로 이루어져 있다. 하지만 고분자 매트릭스와 유기 첨가제간의 양립성(compatibility)에 따른 문제점 또한 존재한다. 따라서 본 총설에서는 PEBA 공중합체를 기반으로 한 혼합막의 장점과 한계에 대해 다루고자 한다.

• Steel and Composite Structures
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• 제39권5호
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• pp.543-564
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• 2021

In this study free vibration analysis of a cracked Goland composite wing is investigated. The wing is modelled as a cantilevered beam based on Euler- Bernoulli equations. Also, composite material is modelled based on lamina fiber-reinforced. Edge crack is modelled by additional boundary conditions and local flexibility matrix in crack location, Castigliano's theorem and energy release rate formulation. Governing differential equations are extracted by Hamilton's principle. Using the separation of variables method, general solution in the normalized form for bending and torsion deflection is achieved then expressions for the cross-sectional rotation, the bending moment, the shear force and the torsional moment for the cantilevered beam are obtained. The cracked beam is modelled by separation of beam into two interconnected intact beams. Free vibration analysis of the beam is performed by applying boundary conditions at the fixed end, the free end, continuity conditions in the crack location of the beam and dynamic stiffness matrix determinant. Also, the effects of various parameters such as length and location of crack and fiber angle on natural frequencies and mode shapes are studied. Modal analysis results illustrate that natural frequencies and mode shapes are affected by depth and location of edge crack and coupling parameter.

• 한국전산유체공학회지
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• 제19권2호
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• pp.86-92
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• 2014

In this paper, prediction of separation trajectory for Two-stage-To-Orbit space launch vehicle has been numerically simulated by using an aerodynamic database based on steady state analysis. Aerodynamic database were obtained for matrix of longitudinal and vertical positions. The steady flow simulations around the launch vehicle have been made by using a 3-D RANS flow solver based on unstructured meshes. For this purpose, a vertex-centered finite-volume method was adopted to discretize inviscid and viscous fluxes. Roe's finite difference splitting was utilized to discretize the inviscid fluxes, and the viscous fluxes were computed based on central differencing. To validate this flow solver, calculations were made for the wind-tunnel experiment model of the LGBB TSTO vehicle configuration on steady state conditions. Aerodynamic database was constructed by using flow simulations based on test matrix from the wind-tunnel experiment. ANN(Artificial Neural Network) was applied to construct interpolation function among aerodynamic variables. Separation trajectory for TSTO launch vehicle was predicted from 6-DOF equation of motion based on the interpolated function. The result of present separation trajectory calculation was compared with the trajectory using experimental database. The predicted results for the separation trajectory shows fair agreement with reference[4] solution.

• Membrane and Water Treatment
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• 제7권3호
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• pp.209-221
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• 2016

As a highly hydrophilic fibrillar mineral in nature, attapulgite (ATP) is a promising new additive for preparation of ultrafiltration (UF) hybrid membrane. In this work, ATP particles, which were grafted with a new Gemini surfactant of Ethyl Stearate-di(octadecyl dimethyl ammonium chloride) to detach the crystal bundles to single crystal and enhance the uniform dispersion in an organic polymer matrix, were incorporated into poly(vinylidene fluoride) (PVDF) matrix, and PVDF/Gemini-ATP hybrid membranes for adsorptive removal of Ni(II) ions from aqueous solution were prepared via a phase inversion method. Chemical composition, crystalization and morphology of the modified ATP were characterized by Fourier transform infrared spectroscopy (FTIR), Transmission electron microscope (TEM) and X-ray diffraction (XRD), respectively. The morphology of the hybrid membrane was characterized by Scanning electron microscopy (SEM), the performance of permeability, hydrophilicity and adsorption of Ni(II) ions were studied, and the adsorption kinetics of the PVDF/ATP hybrid membranes were particular concerned. The results showed that the hybrid membrane displayed a good thermal stability and hydrophilicity. Comparing with PVDF membrane, the hybrid membrane possessed good adsorption capacity for Ni(II) ions, and the adsorption kinetics fit well with Lagergren second-order equation.

• 한국해양공학회지
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• 제9권2호
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• pp.123-132
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• 1995

During compression molding of fiber-reinforced polymeric composites, microstructural changes such as the fiber-matrix separation and the fiber orientation are occurred by the flow of composite materials. Since the nonhomogeneity and anisotropy of composites are caused by the separation and orientation of fibers. On the other hand, the separation and the orientation of fibers are inseparably related to each other. In this paper the degree of nonhomogeneity which is a measure of the separation is obtained using one-dimensional rectangular shaped part compression molding. And the orientation function is measured by the image processing using soft X-rayed photograph and image scanner. We study effects of the mold temperature on the degree of nonhomogeneity and the orientation function.