• 제목/요약/키워드: Material diffusion

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Coupled diffusion of multi-component chemicals in non-saturated concrete

  • Damrongwiriyanupap, Nattapong;Li, Linyuan;Xi, Yunping
    • Computers and Concrete
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    • v.11 no.3
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    • pp.201-222
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    • 2013
  • A comprehensive simulation model for the transport process of fully coupled moisture and multi-species in non-saturated concrete structures is proposed. The governing equations of moisture and ion diffusion are formulated based on Fick's law and the Nernst-Planck equation, respectively. The governing equations are modified by explicitly including the coupling terms corresponding to the coupled mechanisms. The ionic interaction-induced electrostatic potential is described by electroneutrality condition. The model takes into account the two-way coupled effect of moisture diffusion and ion transport in concrete. The coupling parameters are evaluated based on the available experimental data and incorporated in the governing equations. Differing from previous researches, the material parameters related to moisture diffusion and ion transport in concrete are considered not to be constant numbers and characterized by the material models that account for the concrete mix design parameters and age of concrete. Then, the material models are included in the numerical analysis and the governing equations are solved by using finite element method. The numerical results obtained from the present model agree very well with available test data. Thus, the model can predict satisfactorily the ingress of deicing salts into non-saturated concrete.

Risk Evaluation of Scrubber Deposition By-Products in the Diffusion Process (Diffusion 공정 내 스크러버 퇴적 부산물의 위험성 평가)

  • Minji Kim;Jinback Lee;Seungho Jung;Keunwon Lee
    • Journal of the Korean Institute of Gas
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    • v.28 no.2
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    • pp.76-83
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    • 2024
  • In the semiconductor manufacturing process, the Diffusion process generates various reactive by-products. These by-products are deposited inside the pipes of post-processing and exhaust treatment systems, posing a potential risk of substantial dust explosions. In this study, three methods material verification, selection of analysis samples, and risk analysis were employed to address the substances produced during the Diffusion process. Among the materials handled in the Diffusion process, ZrO2, TEOD, and E-DEOS were identified as raw material capable of generating by-product dust. Test for Minimum Ignition Energy and dust explosion were conducted on the by-products collected from each processing facility. The results indicated that, in the case of MIE, none of the by-products ignited. However, the dust explosion test revealed that ZrO2 exhibited a maximum pressure of 7.6 bar and Kst value of 73.3 bar·m/s, its explosive hazard. Consequently, to mitigate such risks in semiconductor processes, it is excessive buildup.

A Study on Implanted and Annealed Antimony Profiles in Amorphous and Single Crystalline Silicon Using 10~50 keV Energy Bombardment (비정질 및 단결정 실리콘에서 10~50 keV 에너지로 주입된 안티몬 이온의 분포와 열적인 거동에 따른 연구)

  • Jung, Won-Chae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.11
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    • pp.683-689
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    • 2015
  • For the formation of $N^+$ doping, the antimony ions are mainly used for the fabrication of a BJT (bipolar junction transistor), CMOS (complementary metal oxide semiconductor), FET (field effect transistor) and BiCMOS (bipolar and complementary metal oxide semiconductor) process integration. Antimony is a heavy element and has relatively a low diffusion coefficient in silicon. Therefore, antimony is preferred as a candidate of ultra shallow junction for n type doping instead of arsenic implantation. Three-dimensional (3D) profiles of antimony are also compared one another from different tilt angles and incident energies under same dimensional conditions. The diffusion effect of antimony showed ORD (oxygen retarded diffusion) after thermal oxidation process. The interfacial effect of a $SiO_2/Si$ is influenced antimony diffusion and showed segregation effects during the oxidation process. The surface sputtering effect of antimony must be considered due to its heavy mass in the case of low energy and high dose conditions. The range of antimony implanted in amorphous and crystalline silicon are compared each other and its data and profiles also showed and explained after thermal annealing under inert $N_2$ gas and dry oxidation.

Coercivity Enhancement in Nd2Fe14B Permanent Magnetic Powders through Rotating Diffusion Process with DyHx Powders

  • Choi, Moon-Hee;Yu, Ji-Hun;Kim, Dong-Hwan;Kim, In-Bae;Kim, Yang-Do
    • Journal of Magnetics
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    • v.16 no.4
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    • pp.342-349
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    • 2011
  • [ $Nd_2Fe_{14}B$ ]permanent magnetic powders ($_iH_c$ = 9.2 kOe, $B_r$ = 12.2 kG) were produced by HDDR process. Their coercivity was enhanced to 12.6 kOe through the grain boundary diffusion process with dysprosium hydride ($DyH_x$). $DyH_x$ diffusion process was optimized through rotating diffusion process, resulting in distinct phases rich in Nd and Dy observable by field emission scanning microscopy and transmission electron microscopy. The mechanism of coercivity enhancement that resulted in restrain the coupling effect between $Nd_2Fe_{14}B$ grains is also discussed.

The Effect of Bonding Condition on Tensile Properties of Diffusion Bonds of Graphite Cast Iron FCD60 to Cr-Mo Steel SCM440 (구상흑연주철 FCD60과 Cr-Mo강 SCM440 확산접합부의 인장성질에 미치는 접합조건의 영향)

  • 송우현;김정길;강정윤
    • Journal of Welding and Joining
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    • v.22 no.1
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    • pp.77-82
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    • 2004
  • The effect of bonding condition on tensile properties of joints diffusion bonded spheroidal graphite cast iron, FCD60 to Cr-Mo steel, SCM 440 was investigated. Diffusion bonding was performed with various temperatures, holding times, pressures and atmospheres. All tensile specimens were fractured at the bonding interface. The tensile strength and elongation was increased with increasing bonding temperature. Especially, tensile strength of joints bonded at 1123K was higher than that of a raw material, FCD60, and tensile strength of joints bonded at 1173K was equal to that of a raw material, SCM440, but elongation of all joints was lower than those of raw materials. There was little the effect of holding time on the tensile properties. In comparison with bonding atmosphere, the difference of tensile strength was not observed, but elongation of joint bonded at vacuum(6.7mPa and 67mPa) was higher than that of Ar gas. Higher the degee of vacuum, elongation increased. Tensile properties of diffusion bonds depended on microstructures of cast iron at the interface and void ratio. Microstructures of cast iron at interface changed with temperature, because decarburizing and interdiffusion at the interface occurs and transformation of austenite-1 ferrite + graphite occurs on the cooling process. The void ratio decreased with increasing temperature, especially, effected on the elongation.

A study on the enhancement of refractive index in Ti:LiTaO$_{3}$ optical waveguides by Zn-vapor diffusion (Zn-Vapor확산에 의한 Ti:LiTaO$_{3}$ 광도파로의 굴절률 증가에 관한 연구)

  • 정홍식;정영식
    • Electrical & Electronic Materials
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    • v.9 no.3
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    • pp.298-303
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    • 1996
  • A double diffusion technique is developed to enhance the effective mode index of optical waveguides in $LiTaO_3$. It consists of Zn diffusion from the vapor phase at relatively low temperatures (750->$800^{\circ}C$), into waveguides initially produced by Ti indiffusion at higher temperature (1150->$1200^{\circ}C$). Both X- and Z-cut substrates are investigated. A model that combines profiles of both diffusion is formulated to calculate the expected effective index values for planar waveguides. Good agreement is found between experimental results and model predictions which assume that the initial Ti profile is not affected by the lower temperature Zn diffusion. Effective index enhancements as high as 0.005 and 0.003 are obtained by this method for the fundamental extraordinary and ordinary modes, respectively.

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A Study on Diffusion Constant Measurement Using Light Reflectance within Biological Tissue (생체조직내에서 반사광을 이용한 확산 상수의 측정에 관한 연구)

  • 임현수
    • Journal of Biomedical Engineering Research
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    • v.17 no.2
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    • pp.227-234
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    • 1996
  • This paper is the study of the diffusion constant in order to calculate the percent oxygenation and percent blood volume using reflectance light within biological tissue. The diffusion constant play major role in percent oxygenation and percent blood volume and varies with the biological material such as hemolyzed blood, whole blood, dermis and epidermis in vivo tissue. The diffusion constant can be modeled to consist of a contribution from bloodless tissue and blood present in tissue. The reflectance light for experimental are red light of 660nm, infrared light of 880nm, green light of 569nm. The correlation between the diffusion constant and biological tissue was analyzed by the intensity of reflectance light at different depth within human limb. The reflectance light was changed in response to physiological changes within biological tissue. The data for diffusion constant were obtained at different depth beneath the surface of the skin and will be utilized to amen the percent oxygenation and percent blood volume.

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Preparation and Properties of Poly($\varepsilon$-caprolactone) Nanocapsules Containing Phytoncide Oil by Emulsion-diffusion Method(1) (유화확산법을 이용한 피톤치드오일 함유 폴리입실론카프로락톤 나노캡슐의 제조와 성질(1))

  • Jeong, Cheon-Hee;Kim, Hea-In;Park, Soo-Min
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.114-116
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    • 2008
  • Poly(${\varepsilon}$-caprolactone) nanocapsules(nanoPCL) containing phytoncide oil were synthesized by emulsion diffusion method using ethyl acetate as organic solvent. The influence of the degree of hydrolyzation of poly(vinyl acohol) used as an emulsion stabilizer, and the different weight ratio of core material to wall material on the particle size, morphology, and emulsion stability was investigated to design nanocapsules. The encapsulated nanoPCL were characterized by FT-IR spetrometry, Scanning electron microscope, Differential scanning calorimetry, and Thermogravimetry analysis, respectively.

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Evaluation of Chloride Resistance with Application Method of Coating Materials Using Electric Acceleration Test (코팅재료의 도포 특성에 따른 전기적 촉진을 통한 염해 저항성 평가)

  • Kim Myung Yu;Yang Eun Ik;Yeon Kyu Seok;Joo Myung Ki
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.551-554
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    • 2005
  • The durability of concrete is decreased by various deterioration factors such as a crack, spalling, corrosion. Many repair and rehabilitation methods have been introduced to extend service life of RC structure. An application of coating material is one of repair and rehabilitation methods. However, there is a problem due to reduction of bonding strength and damage of coating material in the case of existed coating material. Thus, this paper is aim to investigate the chloride resistance according to application method of coating material which improve the existed problem. According to the results, it is showed that application of coating material reduces diffusion of chloride into concrete. In special, application of MMA polymer showed the best resistance for chloride attack. However, variation of application method and number of times has a minor effect on chloride diffusion.

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Specific Heat Measurement of Insulating Material using Heat Diffusion Method

  • Choi, Yeon-Suk;Kim, Dong-Lak
    • Progress in Superconductivity and Cryogenics
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    • v.14 no.2
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    • pp.32-35
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    • 2012
  • The objective of the present work is to develop a precise instrument for measuring the thermal property of insulating material over a temperature range from 30 K to near room temperature by utilizing a cryocooler. The instrument consists of two thermal links, a test sample, heat sink, heat source and vacuum vessel. The cold head of the cryocooler as a heat sink is thermally anchored to the thermal link and used to bring the apparatus to a desired temperature in a vacuum chamber. An electric heater as a heat source is placed in the middle of test sample for generating uniform heat flux. The entire apparatus is covered by thermal shields and wrapped in multi-layer insulation to minimize thermal radiation in a vacuum chamber. For a supplied heat flux the temperature distribution in the insulating material is measured in steady and transient state. The thermal conductivity of insulating material is measured from temperature difference for a given heat flux. In addition, the specific heat of insulating material is obtained by solving one-dimensional heat diffusion equation.