• Title/Summary/Keyword: Material chemistry

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A Study on School-level Science Elective-centered Curriculum Operation Through Science Teacher Interviews (과학 교사와의 면담을 통해 알아 본 과학 선택 중심 교육과정의 운영 실태)

  • Hong, Mi-Young
    • Journal of The Korean Association For Science Education
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    • v.30 no.5
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    • pp.609-620
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    • 2010
  • The purpose of this study was to examine school-level science elective-centered curriculum operation and teachers' perception of their instruction of elective-centered science courses. Data were collected from 12 science teachers in 12 high schools in the metropolitan Seoul area through semi-constructed interviews. The results showed that students were supposed to select science subjects under insufficient guidance and their choices on subject were also restricted due to school administrative processes such as teacher's instructional time allocation. Participants were well-perceived different group characteristics among humanities course and science course students toward science learning, still, they felt difficulties in valuing students' variety by differentiating contents and teaching methodologies due to school assessment system and workload of extra instructional material preparation. Influenced by the current college entrance examination system, low motivation for humanities course students and students' choice concentrated in chemistry and life science for science course students, were pointed out as main problems. As a way to improve science education for 11th - 12th graders, developing customized science curriculum for humanities course and science course respectively, changing of entrance system into increasing importance of science for students who will major in non-science fields, and designations of essential prerequisite science subject for students who will major in engineering & science fields, were suggested.

Petrogenetic Study on the Foliated Granitoids in the Chonju and the Sunchang Area(I) -In the Light of Petrochemical Properties- (전주 및 순창지역에 분포하는 엽리상화강암류의 성인에 대한 연구(I) - 암석지화학적 특성을 중심으로 -)

  • Na, Choon-Ki;Lee, In-Sung;Chung, Jae-Il
    • Journal of the Korean earth science society
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    • v.18 no.6
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    • pp.480-492
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    • 1997
  • In order to understand the processes involved in the petrogenesis and the differentiation of the primary magma spectrum, a petrological and geochemical properties were investigated for the Chonju and the Sunchang foliated granites, which are located in the southwestern part of the Okchon zone and extends up to the northwestern boundary of the Ryongnam massif as two subparallel batholiths. Major element analyses show that the Chonju and Sunchang foliated granites are classified petrologically into a weakly to strongly peraluminous or calc-alkaline, but do not fit neatly into either of the I/S-type or magnetite/ilmenite-series classification schemes for granites, although the I-type and magnetite-series characteristics seem to be predominant based on the major element chemistry. In normative compositions, the Chonju granite is petrographically evolved from granodiorite to granite, whereas the Sunchang granite is from granodiorite to quartz monzodiorite. It seems to suggest a difference of the magmatic evolution processes such as crustal assimilation and/or fractional crystallization in magma. The REE patterns of both batholiths show high similarity and strongly fractionated REE distributions which show high $(Ce/Yb)_N$ ratios and little or no Eu anomalies. These REE patterns correspond broadly to those seen in the pre-Cretaceous granitoids of Korea. Apparently, the evidences obtained from the bulk compositions strongly suggest that the two foliated granitoids were formed by partial meltings of a relatively restricted and similar, may be common, source material which contains a continental crust component having an igneous composition, and have undergone a similar magmatic differentiation processes.

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THE PATIENTS' SATISFACTION FOLLOWING IMPLANT TREATMENT

  • Heo, Yoon-Young;Heo, Seong-Joo;Chang, Myung-Woo;Park, Ji-Man
    • The Journal of Korean Academy of Prosthodontics
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    • v.46 no.6
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    • pp.569-576
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    • 2008
  • STATEMENT OF PROBLEM: While patient-centered outcomes are usually not reported, these may represent major aspects of the implant success for the patient. Use of a well-designed patient survey form can be an invaluable asset to the implant practitioners. PURPOSE: The objective of this study was to investigate patient satisfaction after implant therapy by means of a questionnaire. MATERIAL AND METHODS: South Korean patients (n = 100), who visited the dental examination center of Soon Chun Hyang university hospital, were asked to fill out the satisfaction questionnaire regarding aspects of cost, comfort, esthetics, chewing, gingival health, food impaction, phonetic aspect, screw loosening, and general satisfaction. Responses to statements were given on the Likert response scale. Four experimental groups of patients were distinguished with various location ($A_1,\;A_2,\;A_3$), year ($B_1,\;B_2,\;B_3$), number of implant replacements ($C_1,\;C_2,\;C_3$), and treatment cost ($D_1,\;D_2,\;D_3$). The reliability of the response scales was measured by calculation of its internal consistency, expressed as Cronbach's ${\alpha}$. The scales were distinguished by means of factor analysis method. Possible differences in scale scores among the groups were assessed by One-way ANOVA (${\alpha}$= 0.05). RESULTS: Patients responded to most of the statements with high satisfaction. But the mean scale score of statement about cost was low. After the verification of internal consistency and factor analysis, five components, e.g. general satisfaction, comfort, chewing efficiency, esthetics, and phonetic aspect were grouped together. These components could be explained with common meaning and the first factor was named as 'general satisfaction'. Differences in patient satisfaction on the scale with esthetics were present between patients who have been wearing the implant prosthesis less than three years and those more than seven years ($B_1<B_3$). CONCLUSION: The patients were generally satisfied with the outcome of implant treatment. But the patients' major complaint was high cost and while the statistically significant difference was not shown, the satisfaction scale about food impaction and esthetics was low. So the continuing efforts to make improvements about these problems are needed for the implant practitioners.

Role of Sulfone Additive in Improving 4.6V High-Voltage Cycling Performance of Layered Oxide Battery Cathode (층상계 산화물 양극의 4.6V 고전압 특성 향상에서의 Sulfone 첨가제의 역할)

  • Kang, Joonsup;Nam, Kyung-Mo;Hwang, Eui-Hyeong;Kwon, Young-Gil;Song, Seung-Wan
    • Journal of the Korean Electrochemical Society
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    • v.19 no.1
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    • pp.1-8
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    • 2016
  • Capacity of layered lithium nickel-cobalt-manganese oxide ($LiNi_{1-x-y}Co_xMn_yO_2$) cathode material can increase by raising the charge cut-off voltage above 4.3 V vs. $Li/Li^+$, but it is limited due to anodic instability of conventional electrolyte. We have been screening and evaluating various sulfone-based compounds of dimethyl sulfone (DMS), diethyl sulfone (DES), ethyl methyl sulfone (EMS) as electrolyte additives for high-voltage applications. Here we report improved cycling performance of $LiNi_{0.5}Co_{0.2}Mn_{0.3}O_2$ cathode by the use of dimethyl sulfone (DMS) additive under an aggressive charge condition of 4.6 V, compared to that in conventional electrolyte, and cathode-electrolyte interfacial reaction behavior. The cathode with DMS delivered discharge capacities of $198-173mAhg^{-1}$ over 50 cycles and capacity retention of 84%. Surface analysis results indicate that DMS induces to form a surface protective film at the cathode and inhibit metal-dissolution, which is correlated to improved high-voltage cycling performance.

Development of Hyaluronic Acid-Functionalized Hydrogel Lens and Characterization of Physical Properties and Lysozyme Adsorption (Hyaluronic acid의 첨가방법에 따른 하이드로겔 콘택트렌즈의 물리적 특성과 lysozyme 흡착량 비교)

  • Lim, Hwa-lim;Kim, Ho-joong;Jun, Jin
    • Journal of Korean Ophthalmic Optics Society
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    • v.20 no.3
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    • pp.285-291
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    • 2015
  • Purpose: The hydrogel lenses have been functionalized with HA(Hyaluronic Acid) using two different methods: construction of an IPN(Interpenetrating Polymer Networks) and formation of CCB(Chemical Covalent Bonding). The lysozyme adsorption and physical properties such as optical transmittance and water content of the hydrogel lenses have been investigated in order to determine whether method is suitable for the application potentials in contact lens industry. Methods: HA have been added to the hydrogel lenses prepared in the Lab using the two different method, e.g. IPN and CCB. The optical transmittance was measured in the wavelength range of 300~800 nm. The water content was measured by the gravimetric method using 0.9% NaCl saline solution. The amounts of adsorbed lysozyme on the contact lenses was analyzed by HPLC after incubation for 12h in artificial tears. Results: The water content of the HA added hydrogel contact lenses was increased, and the lens made by IPN method showed higher water content than the lens made by CCB method. The optical transmittance was over 90% both before and after addition of HA. Comparing the lysozyme adsorption reduction ratio, contact lens manufactured by IPN method was 60.0%, and the lens made by CCB method was 40.4%. Conclusions: CCB method is appropriate to distribute the functional material evenly throughout the lens, whereas IPN method is effective for the case of giving the functionality on the lens surface without phase separation.

The Status of Contact Lens Wearing, Management and Eye Health Awareness Among Female University Students in Jeju Area (제주지역 여대생들의 콘택트렌즈 착용 및 관리 실태와 눈건강 인식)

  • Choi, Ji Young;Song, Yun Young;Byun, Jong Chul
    • Journal of Korean Ophthalmic Optics Society
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    • v.21 no.3
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    • pp.203-214
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    • 2016
  • Purpose: The purpose of this study is to analyze the status of contact lens wearing, management and awareness of eye health knowledge among female university students in Jeju area and to utilize the basic data for education and management of contact lens. Methods: Data for this study were collected from the 236 female university students in Jeju area who have a contact lens experience from May 1, 2016 to June 11, 2016. Results: We found the status of contact lens wearing and management of subjects and there were different correlations between discomfort and awareness of eye health knowledge among the subjects who have different characteristics. There were also correlations in discomfort, the average days of contact lens wear per week, initial wearing day and action when they have any discomfort in some contact lens wearers. Conclusions: We realized the status of contact lens wearing and management of female university students and it suggests appropriate contact care education and sustainable management system are need to be established for considering daily average wearing time, the type and material of contact lens wear and main discomfort and so on.

Organic Thin Film Transistors with Cross-Linked PVP Gates (Cross-Linked PVP 게이트 유기 박막트랜지스터)

  • Jang Ji-Geun;Oh Myung-Hwan;Chang Ho-Jung;Kim Young-Seop;Lee Jun-Young;Gong Myoung-Seon;Lee Young-Kwan
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.1 s.38
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    • pp.37-42
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    • 2006
  • The preparation and processing of PVP-gate insulators on the device performance have been studied in the fabrication of organic thin film transistors (OTFTs). One of polyvinyl series, poly-4-vinyl phenol(PVP) was used as a solute and propyleneglycol monomethyl etheracetate(PGMEA) as a solvent in the formation of organic gate solutions. The cross-linking of organic insulators was also attempted by adding the thermosetting material, poly (melamine-co-formaldehyde) as a hardener in the compounds. From the measurements of electrical insulating characteristics of metal-insulator-metal (MIM) samples, PVP-based insulating layers showed lower leakage current according to the increase of concentration of PVP and poly (melamine-co-formaldehyde) to PGMEA in the formation of organic solutions. The PVP(20 wt%) copolymer with composition of 20 wt% PVP to PGMEA and cross-linked PVPs in which 5 wt% and 10 wt% poly (melamine-co-formaldehyde) hardeners had been additional]y mixed into PVP(20 wt%) copolymers were used as gate dielectrics in the fabrication of OTFTs, respectively. In our experiments, the maximum field effect mobility of $0.31cm^2/Vs$ could be obtained in the 5 wt% cross-linked PVP(20 wt%) device and the highest on/off current ratio of $1.92{\times}10^5$ in the 10 wt% cross-linked PVP(20 wt%) device.

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Preparation of Oligosaccharides from Microcrystalline Cellulose by Acetolysis (미소결정성(微少結晶性) 섬유소(纖維素)의 가(加)아세트산분해(酸分解)에 의한 과당류(寡糖類)의 조제(調製))

  • Choi, Woo Young
    • Korean Journal of Agricultural Science
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    • v.10 no.2
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    • pp.365-370
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    • 1983
  • Cellooligosaccharides were prepared from microcrystalline cellulose by acetolysis, deacetylation, and chromatographic fractionation, to determine the optimum time of treatment with acetolysis mixture. The fractionation was accomplished by ethanol-water gradient elution on chromatographic column composed of stearic acid-treated mixture of charcoal and Celite. The amount of initial acetolysis product was increased with the reaction period, however, the acetylated mixture of longer reaction period appeared to contain the greater bulk of methanol-insoluble material. Better yields of most of oligosaccharides were obtained with 3-hr acetolysis. When the reaction time was extended to 4-hr, yields of shorter chain oligosaccharides increased at the expense of the The yields obtained with 3-hr acetclys is from 68.2g of Sigmacell Type 19 were : cellotriose, 1.36g(2.0%) ; -tetraose, 1.64g(2.4%) ; -pentaose, 1.16g(1.7%) ; -hexaose, 0.82g(1.2%) ; and -heptaose, 0.21g(0.3%).

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Geochemical Application for Clarifying the Source Material of the Earthenware: A Preliminary Study for Archaeological Application of Geochemical Tool (도토기의 태토(기원물질)산지를 추적하기 위한 지구화학적 응용연구: 지구화학연구기법의 고고학적 응용을 위한 기초연구)

  • Lee, Seung-Gu;Lee, Kil-Yong;Yoon, Yoon-Yeol;Yang, Myeong-Kwon;Kim, Kyu-Ho;Lee, Sung-Joo;Ahn, Sang-Doo
    • The Journal of the Petrological Society of Korea
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    • v.19 no.3
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    • pp.181-197
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    • 2010
  • This study is for finding a geoscientific factor for clarifying the source soil of the ancient earthenware finding. The used samples were the earthenware, soil and rocks, which were collected at the Gyeongju, Gyeongsan and Haman area. The chemical and mineralogical study for the samples were carried out for understanding the change of mineralogical and chemical composition among them. The mineralogical compositions of the earthenware are different from those of the soils from the surrounding area, which suggests that the mineralogical approach for clarifying the source soil of the earthenware should be difficult. Major element compositions of the earthenware also are different from those of the surrounding soils, which suggests that the comparison of the chemical composition using the major elements might be difficult for deducing the source soil of the earthenware. However, PAAS-normalized rare earth element (REE) patterns and Nd model ages among the rock, soils and earthenware from the same sampling sites show similar characteristics one another compared to those of the major element compositions. Nd-Sr isotopic systematics among the earthenware, soils and rocks also show a close relationship. Our results suggest that REE and Nd-Sr isotope geochemistry might be more useful than the other geochemical technique in clarifying the source soils of the ancient earthenware.

A Study on Characteristics of HI Decomposition Using Pt Catalysts on ZrO2-SiO2 Mixed Oxide (ZrO2-SiO2 복합산화물에 담지된 백금 촉매의 요오드화수소 분해 특성 연구)

  • Ko, Yunki;Park, Eunjung;Bae, Kikwang;Park, Chusik;Kang, Kyoungsoo;Cho, Wonchul;Jeong, Seonguk;Kim, Changhee;Kim, Young Ho
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.5
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    • pp.359-366
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    • 2013
  • This work is investigated for the catalytic decomposition of hydrogen iodide (HI). Platinum was used as active material by loading on $ZrO_2-SiO_2$ mixed oxide in HI decomposition reaction. To obtain high and stable conversion of hydrogen iodide in severe condition, it was required to improve catalytic activity. For this reason, a method increasing dispersion of platinum was proposed in this study. In order to get high dispersion of platinum, zirconia was incorporated in silica by sol-gel synthesis. Incorporating zirconia influence increasing platinum dispersion and BET surface area as well as decreasing deactivation of catalysts. It should be able to stably product hydrogen for a long time because of inhibitive deactivation. HI decomposition reaction was carried out under the condition of $450^{\circ}C$ and 1 atm in a fixed bed reactor. Catalysts analysis methods such as $N_2$ adsorption/desorption analysis, X-ray diffraction, X-ray fluorescence, ICP-AES and CO gas chemisorption were used to measurement of their physico-chemical properties.