• 제목/요약/키워드: Material Decomposition

검색결과 629건 처리시간 0.028초

열분해에 의한 카펫의 안정성에 관한 연구 (A Study on the Stability of Carpet by Thermal Decomposition)

  • 박근호;이기철
    • 한국응용과학기술학회지
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    • 제23권2호
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    • pp.147-152
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    • 2006
  • The accidents occurred by unstable material which is easily exploded or burnt up were caused by heat and collision under the condition of relatively low temperature without oxygen, have been reported frequently. However, the amount of the unstable material is getting higher by development of fine ceramic research area even though its dangerous characteristic is disregarded. This research studied a heat stability and measured boiling point of various carpet material. Carpet has been used in home as well as general indoor usage. Now a day, carpet material which is hardly burnt has been on commercial, but its detailed unstable conditions is not mentioned. This research reports the measurement of the initial temperature of generation heat and heat-radiation change on differential scanning calorimeter (DSC). The DSC data of nylon bulked continuous filament (N-BCF) yam 100%, nylon (NY), poly propylene (PP), and a new material named polytrimethylene terephthalate (PTT) are studied and researched about the effect of them using TGA, furnace, and direct-burning experiment.

기능성 경사복합재의 적층조형을 위한 분해기반 공정계획 (Decomposition-based Process Planning far Layered Manufacturing of Functionally Gradient Materials)

  • 신기훈;김성환
    • 한국CDE학회논문집
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    • 제11권3호
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    • pp.223-233
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    • 2006
  • Layered manufacturing(LM) is emerging as a new technology that enables the fabrication of three dimensional heterogeneous objects such as Multi-materials and Functionally Gradient Materials (FGMs). Among various types of heterogeneous objects, more attention has recently paid on the fabrication of FGMs because of their potentials in engineering applications. The necessary steps for LM fabrication of FGMs include representation and process planning of material information inside an FGM. This paper introduces a new process planning algorithm that takes into account the processing of material information. The detailed tasks are discretization (i.e., decomposition-based approximation of volume fraction), orientation (build direction selection), and adaptive slicing of heterogeneous objects. In particular, this paper focuses on the discretization process that converts all of the material information inside an FGM into material features like geometric features. It is thus possible to choose an optimal build direction among various pre-selected ones by approximately estimating build time. This is because total build time depends on the complexity of features. This discretization process also allows adaptive slicing of heterogeneous objects to minimize surface finish and material composition error. In addition, tool path planning can be simplified into fill pattern generation. Specific examples are shown to illustrate the overall procedure.

Ca(OH)2촉매를 이용한 플라즈마 반응에 의한 황산화물(유해가스)의 제거에 관한 연구 (A study of decomposition of sulfur oxides(harmful gas) using calcium dihydroxide catalyst by plasma reactions)

  • 김다영;황명환;우인성
    • 대한안전경영과학회지
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    • 제16권2호
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    • pp.237-246
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    • 2014
  • Researches on the elimination of sulfur and nitrogen oxides with catalysts and absorbents reported many problems related with elimination efficiency and complex devices. In this study, decomposition efficiency of harmful gases was investigated. It was found that the efficiency rate can be increased by moving the harmful gases together with SPCP reactor and the catalysis reactor. Calcium hydroxide($Ca(OH)_2$), CaO, and $TiO_2$ were used as catalysts. Harmful air polluting gases such as $SO_2$ were measured for the analysis of decomposition efficiency, power consumption, and voltage according to changes to the process variables including frequency, concentration, electrode material, thickness of electrode, number of electrode winding, and additives to obtain optimal process conditions and the highest decomposition efficiency. The standard sample was sulfur oxide($SO_2$). Harmful gases were eliminated by moving them through the plasma generated in the SPCP reactor and the $Ca(OH)_2$ catalysis reactor. The elimination rate and products were analyzed with the gas analyzer (Ecom-AC,Germany), FT-IR(Nicolet, Magna-IR560), and GC-(Shimazu). The results of the experiment conducted to decompose and eliminate the harmful gas $SO_2$ with the $Ca(OH)_2$ catalysis reactor and SPCP reactor show 96% decomposition efficiency at the frequency of 10 kHz. The conductivity of the standard gas increased at the frequencies higher than 20 kHz. There was a partial flow of current along the surface. As a result, the decomposition efficiency decreased. The decomposition efficiency of harmful gas $SO_2$ by the $Ca(OH)_2$ catalysis reactor and SPCP reactor was 96.0% under 300 ppm concentration, 10 kHz frequency, and decomposition power of 20 W. It was 4% higher than the application of the SPCP reactor alone. The highest decomposition efficiency, 98.0% was achieved at the concentration of 100 ppm.

가스 감응용 3차원 구조체 TiO2 박막 성장기구 (Growth mechanism of three dimensionally structured TiO2 thin film for gas sensors)

  • 문희규;윤석진;박형호;김진상
    • 센서학회지
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    • 제18권2호
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    • pp.110-115
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    • 2009
  • Polystyrene (PS) microspheres were used to good advantage as a template material to prepare macroporous $TiO_2$ thin films. This is enabled to run the thermal decomposition of the PS without the collapsing of the 3-D macroporous framework during the calcination step. $TiO_2$ thin films were deposited onto the colloidal templated substrates at room temperature by RF sputtering, and then samples were thermally treated at $450^{\circ}C$ for 40.min in air to remove the organic colloidal template and induce crystallization of the $TiO_2$ film. The macroporous $TiO_2$ thin film exhibited a quasi-ordered partially hexagonal close-packed structure. Burst holes, estimated to be formed during PS thermal decomposition, are seen as the hemisphere walls. the inner as well as the outer surfaces of the hollow hemispheres formed by the method of thermal decomposition can be easily accessed by the diffusing gas species. As a consequence, the active surface area interacting with the gas species is expected to be enlarged about by a factor of fourth as large as compared to that of a planar films. Also the thickness at neighboring hemisphere could be controlled a few nm thickness. If the acceptor density becomes as large that depletion width reaches those thickness, the device is in the pinch off-situation and a strong resistance change should be observed.

금속유기분해법을 사용한 Zr0.7Sn0.3TiO4 박막 제조 및 유전특성 (Preparation of Zr0.7Sn0.3TiO4 Thin Films by Metal Organic Decomposition and Their Dielectric Properties)

  • 선호정
    • 한국전기전자재료학회논문지
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    • 제23권4호
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    • pp.311-316
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    • 2010
  • $Zr_{0.7}Sn_{0.3}TiO_4$ (ZST) thin films were fabricated by metal-organic decomposition, and their dielectric properties were investigated in order to evaluate their potential use in passive capacitors for rf and analog/mixed signal integrated circuits. The ZST thin film annealed at the temperature of $800^{\circ}C$ showed a dielectric constant of 27.3 and a dielectric loss of 0.011. The capacitor using the ZST film had quadratic and linear voltage coefficient of capacitance (VCC) of -65 ppm/$V^2$ and -35 ppm/V at 100 kHz, respectively. It also exhibited a good temperature coefficient of capacitance (TCC) value of -32 ppm/$^{\circ}C$ at 100 kHz.

난연성 폴리 올레핀 케이블 절연재료의 내화특성 (Fire Resistance Characteristics of Polyolefin cable Insulating Materials for Flame Retardant)

  • 윤헌주;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.251-254
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    • 2001
  • In this paper, we analyzed the properties change of electric wire when the thermal stress was applied to NFR-8 and FR-PVC 600[V] wire. Messurement is made of the attenuation of a light beam by smoke accumulating with in a closed chamber due to nonflaming pyrolytic decomposition and flaming combustion. Results are expressed in terms of specific optical density which is derived from a geometrical factor and the measured optical density a measurement characteristic of the concentration of smoke. Referenced documents were ASTM E662 standard test method for specific Ds genalated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of $2.5{\pm}0.04[w/cm^{2}]$ for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 25.2 to 37.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. The amount of carbon monoxide generated was found to be much higher in FR-PVC decomposition than in NFR-8 due to incomplete combustion of FR-PVC which has high content of carbon in compound.

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MOD 방법을 이용한 Bi2Sr2CaCu2O8+d 박막제작 (Bi2Sr2CaCu2O8+d Thin Films Grown on (100) MgO Substrate by Metallorganic Decomposition Method)

  • 김선미;박미화;이기진;차덕준
    • 한국전기전자재료학회논문지
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    • 제16권11호
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    • pp.1035-1040
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    • 2003
  • High $T_{c}$ superconducting B $i_2$S $r_2$CaC $u_2$ $O_{8+d}$ (BSCCO2212) films were prepared by a metallorganic decomposition (MOD) method. The metal organic solution of BSCCO2212 was spin-coated on MgO (100) substrates at 3000 rpm for 1 min. To achieve a high critical current density, we controlled heat-treatment conditions and atmosphere. The films were annealed at temperature 75$0^{\circ}C$ ∼ 80$0^{\circ}C$ in $O_2$ or air. We obtained c-axis orientated BSCCO thin films on MgO substrates. The annealed sample at 77$0^{\circ}C$ with $O_2$ showed the critical temperature about 77 K and critical current denstity of 1.19 ${\times}$ 10$^{5}$ A/$\textrm{cm}^2$ about 13 K.

난연성 폴리 올레핀 케이블 절연재료의 내화특성 (Fire Resistance Characteristics of Polyolefin cable Insulating Materials for Flame Retardant)

  • 윤헌주;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.251-254
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    • 2001
  • In this paper, we analysed the properties change of electric wire when the thermal stress was applied to NFR-8 and FR-PVC [600] wire. Measurement is made of the attenuation of a light beam by smoke accumulating with in a closed chamber due to nonflamining pyrolytic decomposition and flaming combustion. Results are expressed in terms of specific optical density which is derived from a geometrical factor and the measured optical density a measurement characteristic of the concentration of smoke. Referenced documents were ASTM E662 standard test method for specific Ds generated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of 2.5${\pm}$0.04[w/$\textrm{cm}^2$] for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 7.2 to 77.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. The amount of carbon monoxide generated was found to be much higher in FR-PVC decomposition than in NFR-8 due to incomp1ete combustion of FR-PVC which has high content of carbon in compound.

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고체추진기관 연소관단열재의 열파괴 예측기법 (Prediction Method for Thermal Destruction of Internal Insulator in Solid Rocket Motor)

  • 배지열;황인식;강윤구
    • 한국추진공학회지
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    • 제27권1호
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    • pp.9-16
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    • 2023
  • 본 연구에서는 고체추진기관 내 연소관단열재의 열분해와 삭마를 고려하여 단열재의 열응답을 예측할 수 있는 일차원 해석기법을 개발하였다. 모델링에는 연소관단열재 내부에서 발생하는 열분해로 인한 물성변화, 숯층의 팽창 및 분해가스 이동을 고려하였다. 또한 연소가스로부터의 복사/대류 열유속을 경계조건으로 적용하였으며 단열재 표면에서 발생하는 화학적 삭마속도를 대수식으로 모델링하였다. 해석기법 검증을 위해 열전대가 설치된 시험모터에 대한 해석을 수행하였다. 해석으로 도출된 온도분포는 시험과 유사한 값을 나타냈으며 시험과 예측 열파괴두께의 오차는 0.1 mm 내외였다.