• Title/Summary/Keyword: Material Decomposition

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Solid Propellants for Propulsion System Including A Yellow Iron Oxide (황색산화철을 포함하는 혼합형 추진제의 특성에 관한 연구)

  • Park, Sungjun;Choi, Sunghan;Won, Jongung;Park, Jungho;Park, Euiyong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.498-503
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    • 2017
  • There is no unusual difference in the initial viscosity of the propellant applied with yellow iron oxide and red iron oxide. In addition, the thermal decomposition rate of the material added with yellow iron oxide is faster than that of the addition of red iron oxide. Especially, it was confirmed that the pressure exponent was 18% lower at high temperature and high pressure. The initial viscosity was lowest at 71% of large particle/small particle ratio

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Status for the Technology of Hydrogen Production from Natural Gas (천연가스를 이용한 수소 제조 기술 현황)

  • Bak, Young-Cheol;Cho, Kwang-Ju
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.344-351
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    • 2005
  • Hydrogen energy will be considered one of the most important energy carries for the future not only as raw material of petroleum chemical industry but also as the fuel of the fuel cell. The hydrogen production based upon the water electrolysis system combined renewable energy or atomic power energy is being watched as long-term hydrogen sources. Hydrogen from fossil fuel, especially natural gas steam reforming, is the economical mass production method at this time. But the cost of $CO_2$ reduction is added in the economic analysis of hydrogen production processes. Therefore many different results are suggested from these analyses about old processes, and modified schemes are studying for the efficient development. In this review, status for the technology of hydrogen production from natural gas are summarized.

Application of Spray Pyrolysis Process for Production of Ultra Pure and Fine Powder. (고순도 초미립 분체제조를 위한 분무열분해법의 응용)

  • Yu, Jae-Keun;Park, Hee-Beom;Park, Joo-Ill;Han, Jung-Soo;Han, Jin-A;Nam, Yung-Hyeon
    • Proceedings of the KAIS Fall Conference
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    • 2000.10a
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    • pp.39-41
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    • 2000
  • Newly modified spray Pyrolysis system was developed to Produce ultra Pure and fine Powder by spray Pyrolysis Process. In this system, raw material solution was effectively atomized and sprayed into the reaction furnace. Also, thermal decomposition process fully completed in the three zone reaction furnace, and produced powder was effectively collected. A technology to reduce impurities in complex acid solution below 20ppm was also developed. The characteristics of produced powder were studied by changing the reaction conditions such as reaction temperature, the injection velocity of the solution and air, nozzle tip size and concentration of solution. The morphology of powder had spherical shape under the most experimental conditions, and the composition and the particle size distribution were almost uniform. Under the most experimental conditions average particle size of most produced powder was below 100nm.

Extraction of Series Arc Signals Based on Wavelet Transform in an Indoor Wiring System

  • Ji, Hong-Keun;Cho, Young-Jin;Wang, Guoming;Hwang, Seong-Cheol;Kil, Gyung-Suk
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.4
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    • pp.221-224
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    • 2017
  • This paper dealt with the extraction of series arc signals based on wavelet transform in order to improve the accuracy of arc detection in indoor wiring systems. Three types of arc sources including a cord-cord, a terminal-cord, and an outlet-plug were fabricated to simulate typical arc defects. An arc generator fabricated according to UL 1699 was used to generate arcs. The optimal mother wavelet was selected as bior1.5 by calculating the correlation coefficients between the detected single current pulse and the wavelet. The detected arc current signals were then decomposed into eight levels using the discrete wavelet transform that implements the multi-resolution analysis method. By analyzing the decomposed components, the detail components D6, D7, and D8 were associated with arc signals, which were used for signal reconstruction. From the result, it was verified that the proposed method can be used for the extraction of the series arc signal from the AC mains, which is expected to be applied to further analysis of arc signals in indoor wiring systems.

A Study on Laser Assisted Machining for Silicon Nitride Ceramics (II) - Surface Characteristics of LAM Machined SSN and HIPSN - (질화규소 세라믹의 레이저 예열선삭에 관한 연구 (II) - 예열선삭된 SSN 및 HIPSN 질화규소 세라믹의 표면특성 -)

  • Kim, Jong-Do;Lee, Su-Jin;Kang, Tae-Young;Suh, Jeong;Lee, Jae-Hoon
    • Journal of Welding and Joining
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    • v.28 no.5
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    • pp.80-85
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    • 2010
  • This study focused on laser assisted machining (LAM) of silicon nitride ceramic that efficiently removes the material through machining of the softened zone by local heating. The effects of laser-assisted machining parameters were studied for cost reduction, and active application in processing of silicon nitride ceramics in this study. Laser assisted machining of silicon nitride allows effective cutting using CBN tool by local heating of the cutting part to the softening temperature of YSiAlON using by the laser beam. When silicon nitride is sufficiently preheated, the surface is oxidized and decomposed and then forms bloating, micro crack and silicate layer, thereby making the cutting process more advantageous. HIPSN and SSN specimens were used to study the machining characteristics. Higher laser power makes severer oxidation and decomposition of both materials. Therefore, HIPSN and SSN specimens were machined more effectively at higher power.

Synthesis and characterization of a new energy material (guanidinium dinitramide) with crystallization solvent

  • Kim, Wooram;Park, Mijung;Park, Yeonsoo;Kwon, Younja;Jo, Youngmin
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.153-160
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    • 2018
  • An environmentally favorable (chlorine-free) solid oxidizer, guanidinium dinitramide [GDN; $NH_2C(NH_2)NH_2N(NO_2)_2$], was newly synthesized from guanidine carbonate [$NH_2C(=NH)NH_2{\cdot}1/2H_2CO_3$]. Two different crystalline forms (${\alpha}-type$ and ${\beta}-type$) appeared according to the applied solvents and synthesis conditions. Moisture, during extraction, might become trapped in a crystal between inner molecules. Therefore, despite having the same chemical composition, Raman-IR and TGA-DSC revealed different physical characteristics of the two forms. Peaks of Raman shift near $1000cm^{-1}$ implied different chemical structures. Thermal analysis revealed an exothermic temperature $155.7^{\circ}C$ for ${\alpha}-type$ but one of $191.6^{\circ}C$ for ${\beta}-type$. The caloric value of ${\alpha}-type$ was 536.4 J/g, which was 2.5 times larger than that of the ${\beta}-type$, which was 1310 J/g. While the synthesized GDN of ${\alpha}-type$ showed a steep exothermic decomposition, the ${\beta}-type$ was slowly decomposed after melting through an endothermic process. This work implied that despite of the same molecular formula some different core thermal properties would appear depending on synthesis conditions.

Review on the heat storage performance and air pollutant adsorption properties of gypsum board according to the additives (석고보드의 첨가제에 따른 오염물질 흡착 및 축열 성능에 대한 고찰)

  • Seo, Hyun Jeong;Jeong, Su-Gwang;Lim, Jae-Han;Kim, Sumin
    • Journal of the Korean Solar Energy Society
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    • v.35 no.1
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    • pp.97-106
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    • 2015
  • Gypsum board is easy to manufacture of a variety of forms and has stable mechanical properties and thermal properties. And gypsum boards are widely used to the walls and ceiling of the building as the interior building materials. The studies about technology of applying the various features in the gypsum board with additives are being actively investigated. Development methods for enhancing performance of the gypsum board using additives are largely divided into two categories. The first case is functional gypsum board that is to improve the moisture absorption and moisture-proof properties. Also studies of adsorption and decomposition of indoor air pollutants of the gypsum board using porous materials as an additive are being actively investigated. Another case is applying thermal storage materials which gives the heat storage performance to gypsum board. In this paper, we would like to introduce the various cases of gypsum board applied various additives.

A Study on Treatment of a Contaminated Soil by Oil using Continuous System of High Temperature Heating Element and Microwave (마이크로웨이브와 고온발열체를 이용한 연속식 공정의 유류오염토양 처리에 관한 연구)

  • Ha, Sang-An;You, Mi-Young
    • Journal of Soil and Groundwater Environment
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    • v.17 no.1
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    • pp.8-12
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    • 2012
  • This study is maintains the condition of high temperature (above $600^{\circ}C$) within a short time using on microwave and high temperature heating elements. And removal characteristics according to changes in soil moisture, microwave power and temperature through the decomposition of the contaminated soil by oil. The difficulty resolvability material was sort of lubricating oil having long carbocyclic (C18-C50) and TPH removal rate reached 85.2% at 6 kW and $700^{\circ}C$ and thus the contaminant was removed 1,788 mg/kg within a process time of 40 minutes. In the case of light oil, gasoline contaminated soil, the removal amount showed 567 mg/kg and the treatment rate reached 98.4% at 6 kW, $500^{\circ}C$ and 20 minute. In the case of non-resolvability reached TPH concentrations on 2,000 mg/kg of worrisome level of soil contamination in the 3 zones at 6 kW, $700^{\circ}C$ and 30 minute. At the time, showed up processing costs 8,173 won per ton.

Effects of Inorganic Fillers on Mechanical Properties of Silicone Rubber

  • Kim, Gyu Tae;Lee, Young Seok;Ha, KiRyong
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.142-148
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    • 2019
  • In this study, the effects of filler particle size and shape on the physical properties of silicone rubber composites were investigated using inorganic fillers (Minusil 5, Celite 219, and Nyad 400) except silica, which was already present as a reinforcing filler of silicone rubber. Fillers with small particle sizes are known to facilitate the formation of the bound rubber by increasing the contact area with the polymer. However, in this experiment, the bound rubber content of Celite 219-added silicone composite was higher than that of Minusil 5-added silicone composite. This was attributed to the porous structure of Celite 219, which led to an increase in the internal surface area of the filler. When the inorganic fillers were added, both thermal decomposition temperature and thermal stability were improved. The bound rubber formed between the silicone rubber and inorganic filler affected the degree of crosslinking of the silicone composite. It is well-known that as the size of the reinforcing filler decreases, the reinforcing effect increases. However, in this experiment, the hardness of the composite material filled with Celite 219 was the highest compared to the other three composites. Furthermore, the highest value of 2.19 MPa was observed for 100% modulus, and the fracture elongation was the lowest at 469%. This was a result of excellent interaction between Celite 219 filler and silicone rubber.

Estimation of Characteristics Treatment for Food Waste using Ultra Thermophilic Aerobic Composting Process (초고온 호기성 퇴비화 공정을 이용한 음식물쓰레기 처리 특성 평가)

  • Park, Seyong;Oh, Dooyoung;Cheong, Cheoljin;Jang, Eunsuk;Song, Hyoungwoon
    • Journal of Korea Society of Waste Management
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    • v.34 no.2
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    • pp.140-147
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    • 2017
  • This study was conducted to evaluate the effects of physical characteristics. Twelve specific odorous compounds and various sources of bacteria were tested via treatment of food waste using an ultra-thermophilic aerobic composting process. Food waste was mixed with seed material and operated for 47 days. During composting, the temperature was maintained at $80-90^{\circ}C$. The variations in $O_2$, $CO_2$ and $NH_3$ production suggested typical microorganism-driven organic decomposition patterns. After composting, the concentrations of 12 specific odorous compounds other than ammonia did not exceed the allowable exhaust limits for odor. After composting, thermophiles represented 50% of all bacteria. After composting, the percentage of thermophile bacterial increased by 15%. Therefore, both stable composting operation and economic benefit can be expected when an ultra-thermophilic composting process is applied to food waste.