• Title/Summary/Keyword: Material Decomposition

Search Result 629, Processing Time 0.021 seconds

Hemicellulose Recovery from Lignocellulosic Material Hydrolyzed by Water (물로 가수분해된 섬유성 기질로부터 hemicellulose 회수)

  • Kim, Sung-Bae;Kim, Chang, Joon
    • KSBB Journal
    • /
    • v.20 no.4
    • /
    • pp.317-322
    • /
    • 2005
  • Various recovery methods were investigated to maximize hemicellulose recovery from lignocellulosic material hydrolyzed by pure water. The pretreatment conditions of water hydrolysis were $170\~180^{\circ}C$ and 1 hour of reaction time. The percentage of hemicellulose solubilized increased as the temperature increased from 170 to $180^{\circ}C$. However, significant decomposition of sugar was observed at temperature of $180^{\circ}C$. From the results of water hydrolysis, the total amount of glucan in solid residue and liquid hydrolyzate was close to the total glucan in the original biomass. For hemicellulose, however, there was a significant difference between both contents. To prove this difference, various recovery methods were proposed. From the total sugar accountability (sugar in liquid + sugar in solid), it was confirmed that hemicellulose recovery in the hydrolyzate was increased if the product including both hydrolyzate and solid residue was physically stimulated by such as heating and ultrasound irradiation. This indicated that, in commercial scale processes that much bigger substrate sizes are used and a sufficient amount of leaching solvent can not be used after pretreatment, a significant amount of oligomers could be trapped in the solid matrix.

Downward particle flux in the eastern Bransfield Strait, Antarctica

  • Kim, Dongseon;Kim, Dong-Yup;Jeonghee Shim;Kang, Young-Chul;Kim, Taerim
    • Journal of the korean society of oceanography
    • /
    • v.38 no.1
    • /
    • pp.1-10
    • /
    • 2003
  • A time-series sediment trap was deployed at a depth of 1034 m in the eastern Bransfield Strait from December 25, 1998 to December 24, 1999. Particle fluxes showed large seasonal variation; about 99% of the annual total mass flux (49 g m/sup -2/) was collected during the austral summer and fall (January-March). Settling particles consisted primarily of biogenic silica, organic carbon, calcium carbonate, and lithogenic material. Biogenic silica and lithogenic material predominated settling particles, comprising 36% and 30% of the total mass flux, respectively, followed by organic carbon, 11% and calcium carbonate, merely 0.6%. The annual organic carbon flux was 5.4 g C m/sup -2/ at 1000 m in the eastern Bransfield Strait, which is greater than the central Strait flux. The relatively lower flux of organic carbon in the central Bransfield Strait may be caused by a stronger surface current in this region. Organic carbon flux estimates in the eastern Bransfield Strait are the highest in the Southern Ocean, perhaps because of the fast sinking of fecal pellets, which leads to less decomposition of organic material in the water column. Approximately 5.8% of the organic carbon produced on the surface in the eastern Bransfield Strait is exported down to 1000 m; this percentage exceeds the maximum EF/sub 1000/ values observed in the Atlantic and Southern Oceans. The eastern Bransfield Strait appears to be the most important site of organic carbon export to the deep sea in the Southern Ocean.

The Evaluation of the thermal degradation and the degree of cure of glass/epoxy composite by ultrasonic technique (복합재료의 열화도 및 경화도에 따른 초음파 특성 연구)

  • 강길호;최원종;박상윤
    • Composites Research
    • /
    • v.16 no.6
    • /
    • pp.33-40
    • /
    • 2003
  • The initial thermal degradation of polymer matrix composite is not observed easily. At the beginning of thermal degradation of polymer matrix composites, phase transformation such as chain scission, oxidation occur, and then micro delamination is produced in matrix and interface between matrix and fiber before blistering. Initial heat damage deteriorate mechanical properties of composites. We presented the detection method of the initial heat damage of composites conveniently using ultrasonic technique. Absorption coefficient and material velocity was measured with thermal degradation and degree of cure. The more thermal degradation was progressed, the more absorption coefficient was increased. When the cure temperature is more high, the absorption coefficient of cured composite is increased and material velocity is decreased. We concluded that cure temperature is more high, the defects such as void is increased and molecular structure cured at high temperature has cross-linking structure which is more absorb the ultrasonic waves.

Experimental Study on the Effect of Flow around Solid Combustibles and Thermal Thickness on Heat Release Rate Characteristics (고체 가연물 주위의 유동과 열적 두께의 변화가 열방출률 특성에 미치는 영향에 관한 실험적 연구)

  • Hong, Ter-Ki;Seo, Dong-Pyo;Park, Seul-Hyun
    • Fire Science and Engineering
    • /
    • v.34 no.3
    • /
    • pp.28-34
    • /
    • 2020
  • In this study, an ISO 5660-1 cone calorimeter experiment was conducted to examine the effects of changes in flow and thermal thickness around solid combustibles on heat release rate characteristics. Polymethyl methacrylate (PMMA) is a solid combustible material that does not generate char during the combustion reaction. Hence, it was selected for the experiment, and the thermal penetration depth was calculated to distinguish the thermal thickness of PMMA. Furthermore, the thermal decomposition characteristics were analyzed by measuring the heat release rate measured during the combustion of PMMA. This was performed after generating the forced flow around the combustibles by setting the duct flow of the cone calorimeter to 12, 24, and 40 L/s. The results confirmed that the thermal release rate of the thermally thin combustible material was not significantly affected by the change in the surrounding flow. Hence, the thermally thick combustible material was significantly affected by the change in the flow rate.

Design of Fresnelet Transform based on Wavelet function for Efficient Analysis of Digital Hologram (디지털 홀로그램의 효율적인 분해를 위한 웨이블릿 함수 기반 프레넬릿 변환의 설계)

  • Seo, Young-Ho;Kim, Jin-Kyum;Kim, Dong-Wook
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.23 no.3
    • /
    • pp.291-298
    • /
    • 2019
  • In this paper, we propose a Fresnel transform method using various wavelet functions to efficiently decompose digital holograms. After implementing the proposed wavelet function-based Fresnelet transforms, we apply it to the digital hologram and analyze the energy characteristics of the coefficients. The implemented wavelet transform-based Fresnelet transform is well suited for reconstructing and processing holograms which are optically obtained or generated by computer-generated hologram technique. After analyzing the characteristics of the spline function, we discuss wavelet multiresolution analysis method based on it. Through this process, we proposed a transform tool that can effectively decompose fringe patterns generated by optical interference phenomena. We implement Fresnelet transform based on wavelet function with various decomposition properties and show the results of decomposing fringe pattern using it. The results show that the energy distribution of the coefficients is significantly different depending on whether the random phase is included or not.

A Study on the Activity of Metal Filter Pt Coated on Soot Oxidation (백금 코팅 메탈필터소재의 Soot 산화반응에 대한 활성 연구)

  • Kim, Sung Su;Lee, Sang Moon;Jang, Du Hun;Bae, Se Hyun;Hong, Sung Chang
    • Applied Chemistry for Engineering
    • /
    • v.22 no.4
    • /
    • pp.400-404
    • /
    • 2011
  • The activity and stability of the metal filter material Pt coated on NOx and soot oxidation were examined. The catalytic reaction test for NOx and soot were also performed independently and simultaneously. As a result, it showed the NO to $NO_2$ shift reaction with 20% conversion, NOx decomposition (about 10%) and perfect soot oxidation on the material Pt coated proceeded. Onset temperature of soot oxidation shift to lower temperature (about $30^{\circ}C$) by generated $NO_2$. The material also was less affected by thermal shock than $Pt/Al_2O_3$ or $Pt/TiO_3$ catalysts due to its stability of surface structure.

Evaluation of Heat Resistance of Lyocell-based Carbon/Phenolic for Aerospace (항공우주용 리오셀계 탄소/페놀릭 복합재료의 내열 성능 평가)

  • Seo, Sang-Kyu;Kim, Yun-Chul;Bae, Ji-Yeul;Hahm, Hee-Chul;Hwang, Tae-Kyung
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.49 no.5
    • /
    • pp.355-363
    • /
    • 2021
  • Heat resistance performance evaluation and thermal analysis were performed to confirm the applicability of the lyocell-based carbon/phenolic composite material for heat-resistant parts for aerospace. Heat resistance performance evaluation of carbon/phenolic was conducted by Thermal Protection Evaluation Motor (TPEM). In this paper, boundary layer integration code considering the boundary layer analysis of combustion gas and MSC-Marc 2018 considering ablation and thermal pyrolysis were used for the thermal analysis. The ablation and thermal insulation performance were analyzed by the pressure curve of test motor and the cut carbon/phenolic specimens. The thermal response of the lyocell-based carbon/phenolic material was similar to that of the rayon-based carbon/phenolic material. Based on the results through the combustion test, the applicability of heat-resistant parts for aerospace to which domestic lyocell-based carbon fibers were applied was confirmed.

Status and Trends of Emission Reduction Technologies and CDM Projects of Greenhouse Gas Nitrous Oxide (온실가스 아산화질소(N2O) 저감기술 및 CDM 사업의 현황과 전망)

  • Chang, Kil Sang
    • Applied Chemistry for Engineering
    • /
    • v.19 no.1
    • /
    • pp.17-26
    • /
    • 2008
  • With the effectuation of Kyoto Protocol on the United Nations Framework Convention on the Climate Change, the emission reduction of greenhouse gases became an urgent issue and has been competitively secured among countries as the form of certificates through clean development mechanism (CDM) or joint implementation (JI). Nitrous oxide ($N_2O$) is one of the major greenhouse gases along with carbon dioxide ($CO_2$) and methane ($CH_4$) having warming potential 310 times that of carbon dioxide and chemically very stable in the atmosphere to give a life time of more than 120 years so that it reaches to the stratosphere to act as an ozone depleting substance. $N_2O$ hardly decomposes and thus, besides to the adoption of thermal decomposition at high temperature, selective catalytic reduction methods are usually used at temperatures over $400^{\circ}C$ in which the presence of NOx acts as a major impeding material in the decomposition process. In this article, the sources of various $N_2O$ generation, catalytic reduction processes and the status and trends of emission trade with CDM projects for greenhouse gas reduction are summarized and discussed on a condensed basis.

Ammonia Conversion in the Presence of Precious Metal Catalysts (귀금속촉매하에서 암모니아의 전환반응)

  • Jang, Hyun Tae;Park, YoonKook;Ko, Yong Sig
    • Korean Chemical Engineering Research
    • /
    • v.46 no.4
    • /
    • pp.806-812
    • /
    • 2008
  • The ammonia decomposition reaction has been of increasing interest as a means of treating ammonia in flue gas in the presence of precious metal catalyst. Various catalysts, $Pt-Rh/Al_2O_3$, $Pt-Rh/TiO_2$, $Pt-Rh/ZrO_2$, $Pt-Pd/Al_2O_3$, $Pd-Rh/Al_2O_3$, $Pd-Rh/TiO_2$, $Pd-Rh/ZrO_2$, $Pt-Pd-Rh/Al_2O_3$, $Pd/Ga-Al_2O_3$, $Rh/Ga-Al_2O_3$, and Ru/Ga-$Al_2O_3$, were synthesized by using excess wet impregnation method. Using a homemade 1/4" reactor at $10,000{\sim}50,000hr^{-1}$ of space velocity in the presence of precious metal catalyst ammonia decomposition reactions were carried out to investigate the catalyst activity. The inlet ammonia concentration was maintained at 2,000 ppm, with an air balance. Both $T_{50}$ and $T_{90}$, defined as the temperatures where 50% and 90% of ammonia, respectively, are converted, decreased significantly when alumina-supported catalysts were applied. In terms of catalytic performance on the ammonia conversion in the presence of hydrogen sulfide, $Pt-Rh/Al_2O_3$ catalyst showed no effect on the poisoning caused by hydrogen sulfide. These results indicate that platinum-rhodium bimetallic catalyst is a useful catalyst for ammonia decomposition.

Analyzing Characteristic of Deterioration Status for Stone Properties in the Tae-Jo Geonwolleung of the Royal Tombs of the Joseon Dynasty (조선왕릉 태조 건원릉 내 석물의 훼손 특성 분석)

  • Lee, Mi Hye;Lee, Myeong Seong;Chun, Yu Gun;Lee, Tae Jong
    • Korean Journal of Heritage: History & Science
    • /
    • v.48 no.4
    • /
    • pp.62-73
    • /
    • 2015
  • The Tae-Jo Geonwolleung is the tomb of the first king Tae-Jo of the Joseon Dynasty in the complex of the Royal Tombs of the Joseon Dynasty which is listed in World Heritage, and it contains various types of stone properties. The material of the stone properties consist of a single type of medium-grained biotite granite, however, each properties have different intensity and types in deterioration phenomena according to their locations and purposes. The major deterioration types of the stones are analyzed as physical decomposition and biodeterioration. The exfoliation, breaking-out and granular decomposition are widespread types of the deterioration throughout the entire burial mound stone properties and surrounding stone properties. On the other hands, the colonization of mosses and plants, and contamination by foreign materials are found more frequent in the burial mound stone properties as these stones are in contact with the soil of the tomb mound and moisture in the soil helped biodeterioration. It is suggested that anti-biology treatment and physical reinforcement are applied to the deteriorated stones to prevent further damage on the stone components of the tomb.