• 제목/요약/키워드: Material Decomposition

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The dependent of growth temperature of piezoelectric SBN Thin Film by Metal Organic Decomposition Process and their properties (MOD 법에 의한 압전 SBN 박막의 성장 온도 의존성 및 특성)

  • Kim, Kwang-Sik;Jang, Gun-Ik;Ur, Soon-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.382-383
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    • 2006
  • The tungsten bronze type of strontium barium niobate(SBN) thin film was synthesized by metal organic decomposion method for SBN stock solution and the SBN thin film process were deposited by spin-coating process on Pt-deposited si-wafer(100) by magnetron sputtering system. The thickness of SBN thin film was 150~200 nm and were optimized for rpm of spin-coater system. The structural variation of SBN thin film was studied by TG-DTA and XRD. The deposited SBN stock solution on annealing at $400{\sim}800^{\circ}C$ a pure tungsten bronze SBN phase and the corresponding. average grain size about 500~1000 nm influenced by annealing temperature. The piezoelectric properties of prepared SBN thin film, the remanent polarization value(2Pr) and coercive field was $1.2{\mu}C/cm^2$ and 2.15V/cm, respectively.

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Properties of Sol-Gel derived $B_{13}P_2$ Thin Films (졸겔법에 의한 보론 포스파이드의 박막 증착 및 특성에 관한 연구)

  • Kim, Zee-Won;Jung, Ye-Cho;Jeon, Ho-Seung;Im, Jong-Hyun;Kim, Chul-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.165-166
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    • 2006
  • Boron phosphide thin films were prepared on the glass substrate from boron and phosphorous alkoxide precursors by sol-gel processing. Boron phosphide sol with equivalent ratio $(CH_3O_3)B$ : $C_{18}H_{15}P$ = 13 : 2 was selected. Films spin-coated at 4000 rpm for 30 s were coated uniformly. Decomposition and crystallization behavior were examined using DSC/TGA and XRD. The films were sintered at 250, 300 and $400^{\circ}C$. It was determined that crystal structure has a rhombohedral phase. The microstructure of thin film was observed using SEM. Thin films approximately showed a visible ray transmittance of 85 %.

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Effect of after annealing on critical current of Bi-2212 HTS round wires (후열처리 조건에 따른 Bi-2212 고온 초전도선의 임계전류 특성 변화)

  • Ha, Dong-Woo;Kim, Sang-Chul;Oh, Jae-Gn;Oh, Sang-Soo;Ha, Hong-Soo;Song, Gyung-Jung;Goh, Rak-Kil;Kim, Ho-Sup;Kim, Tae-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.91-92
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    • 2006
  • The important merit of Bi-2212/Ag wire is to apply cable as round wire state. Bi-2212 high Tc superconducting wires were fabricated in order to apply Rutherford cable near the future. Various Ag ratio from 0.22 to 0.42 of Ag tubes for PID (powder-In-Tube) process were used to investigate the workability and to prevent breakage of filaments during drawing. In order to find proper heat treatment condition, we investigated micro-structure of Bi-2212/Ag wires by using differential thermal analysis, XRD and SEM. The effect of atmosphere on the peritectic decomposition temperature of precursor was investigated. The shape of grain was observed by SEM to investigate Bi-2212 phase formation in filaments. The higher of Ag ratio of mono filament had the higher critical current density, Jc. The wire with 0.42 of Ag ratio showed 7,886 A/cm2 of Jc at 77K.

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Finite element model updating of in-filled RC frames with low strength concrete using ambient vibration test

  • Arslan, Mehmet Emin;Durmus, Ahmet
    • Earthquakes and Structures
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    • v.5 no.1
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    • pp.111-127
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    • 2013
  • This paper describes effects of infill walls on behavior of RC frame with low strength, including numerical modeling, modal testing and finite-element model updating. For this purpose full scaled, one bay and one story RC frame is produced and tested for plane and brick in-filled conditions. Ambient-vibration testis applied to identify dynamic characteristics under natural excitations. Enhanced Frequency Domain Decomposition and Stochastic Subspace Identification methods are used to obtain experimental dynamic characteristics. A numerical modal analysis is performed on the developed two-dimensional finite element model of the frames using SAP2000 software to provide numerical frequencies and mode shapes. Dynamic characteristics obtained by numerical and experimental are compared with each other and finite element model of the frames are updated by changing some uncertain modeling parameters such as material properties and boundary conditions to reduce the differences between the results. At the end of the study, maximum differences in the natural frequencies are reduced on average from 34% to 9% and a good agreement is found between numerical and experimental dynamic characteristics after finite-element model updating. In addition, it is seen material properties are more effective parameters in the finite element model updating of plane frame. However, for brick in-filled frame changes in boundary conditions determine the model updating process.

Mechanical and Thermal Properties of Industrial Protective Fabric with Recycled m-Aramid and Natural Fiber

  • Sung, Eun Ji;Baek, Young Mee;An, Seung Kook
    • Textile Coloration and Finishing
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    • v.30 no.4
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    • pp.227-236
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    • 2018
  • As consciousness of safety becomes an important social issue, the demand for protective clothing is increasing. Conventional flame-retardant cotton working wear has low durability, and working wear with m-aramid fibers are stiff, heavy, less permeable, and expensive. In this study, recycled m-aramid and cotton have been blended to produce woven fabric of different compositions to enhance high performance and comfort to solve aforementioned problems. The fabrics were analyzed according to constituents and various structural factors. Mechanical properties were measured using KES-FB system. The measured thermal properties are TGA, $Q_{max}$, TPP and RPP. Fabric with polyurethane yarn covered by m-aramid/cotton spun yarn is observed to have good wearability. The fabric of open end spun yarn showed more stiffness than that of ring spun yarn. The sample with the high count of yarn has more smooth surface. In addition, high m-aramid content fabric is considered to have relatively high stiffness when using as clothing. In TGA the fabric with higher m-aramid content showed more stable decomposition behavior. The fabric having rough surface showed lower heat transfer properties in $Q_{max}$. The influence of the fabric thickness was important in convection and radiant heat test.

Triallyl Borate as an Effective Separator/Cathode Interphase Modifier for Lithium-ion Batteries

  • Ha Neul Kim;Hye Rim Lee;Taeeun Yim
    • Journal of Electrochemical Science and Technology
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    • v.14 no.3
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    • pp.272-282
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    • 2023
  • Ni-rich layered oxides cathode has recently gained attention as an advanced cathode material due to their applicable energy density. However, as the Ni component in the layered site is increased, the high reactivity of Ni4+ results in parasitic reaction associated with decomposing electrolyte, which leads to a rapid decreasing the lifespan of the cell. The electrolyte additive triallyl borate (TAB) improves interfacial stability, leading to a stable cathode-electrolyte interphase (CEI) layer on the LNCM83 cathode. A multi-functionalized TAB additive can produce a uniformly distributed CEI layer via electrochemical oxidation, which implies an increase in long-term cycling performance. After 100 cycles at elevated temperature, the cell tested by 0.75 TAB retained 88.3% of its retention ratio, whereas the cell performed by TAB-free electrolyte retained 64.1% of its retention. Once the TAB additive formed CEI layers on the LNCM83 cathode, it inhibited the decomposition of carbonate-based solvents species in addition to the dissolution of transition metal components from the cathode. The addition of TAB to LNCM83 cathode material is believed to be a promising way to increase the electrochemical performance.

The Prediction of Water Quality in Ulsan Area Using Material Cycle Model (물질순환모델을 이용한 울산해역의 수질예측)

  • SHIN BUM-SHICK;KIM KYU-HAN;PYUN CHONG-KUN
    • Journal of Ocean Engineering and Technology
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    • v.20 no.1 s.68
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    • pp.55-62
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    • 2006
  • Recently, pollution by development in coastal areas is going from bad to worse. The Korean government is attempting to make policies that prevent water pollution, but it is still difficult to say whether such measures are lowering pollution to an acceptable level. More specifically, the general investigation that has been done in KOREA does not accurately reflect the actual conditions of pollution in coastal areas. An investigation that quantitatively assesses water quality management using rational prediction technology must be attempted, and the ecosystem model, which incorporates both the 3-dimensional hydrodynamic and material cycle models, is the only one with a broad enough scope to obtain accurate results. The hydrodynamic model, which includes advection and diffusion, accounts for the ever-changing flow and (quality) of water in coastal areas, while the material cycle model accounts for pollutants and components of decomposition as sources of the carbon, phosphorus, and nitrogen cycles. In this paper, we simulated the rates of dissolved oxygen (DO), chemical oxygen demand (COD), total nitrogen(T-N) and total-phosphorous(T-P) in Korea's Ulsan Area. Using the ecosystem model, we did simulations using a specific set of parameters and did comparative analysis to determine those most appropriate for the actual environmental characteristics of Ulsan Area. The simulation was successful, making it now possible to predict the likelihood of coastal construction projects causing ecological damage, such as eutrophication and red tide. Our model can also be used in the environmental impact assessment (EIA) of future development projects in the ocean.

Advances in Ultrasonic Testing of Austenitic Stainless Steel Welds

  • Moysan, J.;Ploix, M.A.;Corneloup, G.;Guy, P.;Guerjouma, R. El;Chassignole, B.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.28 no.3
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    • pp.245-253
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    • 2008
  • A precise description of the material is a key point to obtain reliable results when using wave propagation codes. In the case of multipass welds, the material is very difficult to describe due to its anisotropic and heterogeneous properties. Two main advances are presented in the following. The first advance is a model which describes the anisotropy resulting from the metal solidification and thus the model reproduces an anisotropy that is correlated with the grain orientation. The model is called MINA for modelling anisotropy from Notebook of Arc welding. With this kind of material model1ing a good description of the behaviour of the wave propagation is obtained, such as beam deviation or even beam division. But another advance is also necessary to have a good amplitude prediction: a good quantification of the attenuation, particularly due to grain scattering, is also required as far as attenuation exhibits a strong anisotropic behaviour too. Measurement of attenuation is difficult to achieve in anisotropic materials. An experimental approach has been based both on the decomposition of experimental beams into plane waves angular spectra and on the propagation modelling through the anisotropic material via transmission coefficients computed in generally triclinic case. Various examples of results are showed and also some prospects to continue refining numerical simulation of wave propagation.

The Study on Material Characteristics of the By-Products of the Production of Bronze during the Goryeo Dynasty Excavated from the Sinpung Site, Wanju, Jeollabuk-do, South Korea (완주 신풍유적 출토 고려시대 청동생산 부산물의 재료학적 특성)

  • Choi, Nam Young;Cho, Nam Chul;Kang, Beoung Sun
    • Journal of Conservation Science
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    • v.35 no.5
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    • pp.392-402
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    • 2019
  • This study interpreted the characteristics of the site and provenance of raw material by performing material characteristics analysis of the slags and tuyeres excavated from the Sinpung site in Wanju, Jeollabuk-do. The major chemical compositions suggested that the slags and tuyeres were created when Cu-Sn-Pb was alloyed. Metal microscope and scanning electron microscopy-energy dispersive spectrometer analyses revealed that the slags and tuyeres were by-products formed in the alloying process. This alloy, created by adding galena to copper and tin ingots, was an intermediary material used in making the finished products. According to the lead isotope ratio analysis result, slags could be made using galena of the southern Zone III region of Korea. Based on the decomposition of mica group minerals and the formation of mullite detected through X-ray diffraction analysis, it is possible to conclude that the tuyeres operated at approximately 1,000℃ as, the mullite was detected on the outside of the tuyeres.

Preparation and Properties of Modified Silicon-containing Arylacetylene Resin with Bispropargyl Ether

  • Zhang, Jian;Huang, Jianxiang;Yu, Xiaojiao;Wang, Canfeng;Huang, Farong;Du, Lei
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3706-3710
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    • 2012
  • A novel silicon-containing arylacetylene resin (MSAR) modified by dipropargyl ether of bisphenol A (DPBPA) and dipropargyl ether of perfluorobisphenol A (DPPFBPA) was prepared separately. The curing behaviors of modified resins, DPBPA/MSAR and DPPFBPA/MSAR, were characterized with differential scanning calorimeter (DSC). The kinetic parameters of modified resins were obtained by the Kissinger and Ozawa methods. The results of dynamic mechanical analysis (DMA) revealed that the glass transition temperature ($T_g$) of the cured DPBPA/MSAR reached $486^{\circ}C$. According to the thermogravimetric analysis (TGA), the decomposition temperature ($T_{d5}$) of the cured resins and char yield ($Y_c$, $800^{\circ}C$) decreased as the dipropargyl ether loadings increased, especially in air. With the same weight loading, thermal stability of DPBPA/MSAR was better than that of DPPFBPA/MSAR. The carbon fiber (T300) reinforced composites exhibited excellent flexural properties at room temperature with a high property retention at $300^{\circ}C$.