• 제목/요약/키워드: Material Constants

검색결과 569건 처리시간 0.025초

부식방지를 위한 마그네슘 및 칼슘 이온의 흡착 제거에 관한 연구 (A Study on the Absorptive Removal of Magnesium ion and Calcium ion for Corrosion Prevent)

  • 홍성욱;안형환
    • 한국안전학회지
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    • 제19권3호
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    • pp.40-44
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    • 2004
  • To the removal of hardness materials, we've test the absorptive capacity of main material $Mg^{2+},\;Ca^{2+}$ on the using the activated carbon powder saturated in 0.1M Nitrilotriacetic acid by experimental methods. The absorptive properties of $Ca^{2+}\;and\;Mg^{2+}$ were measured with absorbent quantity and contact time., and investigated the physical properties of overall rate constant and adsorption constant adsorption isotherm, and Langmuir and Freundlich constant. In case of k' adsorption rate constants of $Ca^{2+},\;Mg^{2+}$, was 0.00299, 0.00529 by Bhattahary and Venkobachar equation. $k_{aa}$ was 0.00373, 0.00640 according with adsorption rate constants of Lagergren.

Deposition of PbTio3 thin films by reactive sputtering

  • Ahn, Y.S.;Lee, D.S.;Ahn, E.J.;Yoon, E.
    • Journal of Korean Vacuum Science & Technology
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    • 제3권2호
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    • pp.126-129
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    • 1999
  • PbTio3 is a promising material with perovskite structure for pyroelectric sensor applications with its superior pyroelectric properties, low dielectric constants, and low piezoelectric constants. Growth of pyroelectric thin films in general, needs relatively higher temperatures than those of conventional Si semiconductor processing However, low growth temperature is advantageous for the device integration. We report the low temperature (350$^{\circ}C$) growth of PbTio3 thin films by 3-gun DC magnetron reactive sputtering. The effects of substrate temperature, Pb-flux, and total pressure on crystalinity and preferred orientation of PbTio3 thin films are reported.

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Free-edge effect in cross-ply laminated plates under a uniform extension

  • Sheng, Hongyu;Ye, Jianqiao
    • Structural Engineering and Mechanics
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    • 제18권3호
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    • pp.377-388
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    • 2004
  • Based on the basic equations of elasticity, free-edge effects on stresses in cross-ply laminated plates are found by using the state space method. The laminates are subjected to uniaxial-uniform extension plate, which is a typical example of general plane strain problem. The study takes into account material constants of all individual material layers and the state equation of a laminate is solved analytically in the through thickness direction. By this approach, a composite plate may be composed of an arbitrary number of orthotropic layers, each of which may have different material properties and thickness. The solution provides a continuous displacement and inter-laminar stress fields across all material interfaces and an approxiamte prediction to the singularity of stresses occurring in the boundary layer region of a free-edge. Numerical solutions are obtained and compared with the results obtained from an alternative numerical method.

타이어에서 채취한 고무배합물의 기계적 물성 측정 (Measurement of Mechanical Material Properties of Rubber Compounds Sampled from a Pneumatic Tire)

  • 김용우;김종국
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2002년도 춘계학술대회 논문집
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    • pp.404-409
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    • 2002
  • Pneumatic tires usually contain a variety of rubber compositions, each designed to contribute some particular factor to overall performance. Rubber compounds designed for a specific function will usually be similar but not identical In composition and properties. Since 1970`s finite element analysis of tire has been performed extensively, which requires some energy density functions of rubber components of a tire. The conventional Mooney-Rivlin material model is one of the description that is commonly used in the analysis of tire. In this paper, we report the two material constants of gooney-Rivlin material model for some rubber compounds of a real pneumatic tire, which are obtained through uniaxial tension test.

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승강기용 방진고무부품 특성 및 사용수명 평가 (Useful Lifetime Evaluation of Rubber Component for Elevator Cabin)

  • 우창수;박현성
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.576-580
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    • 2008
  • Rubber material properties and useful life evaluation are very important in design procedure to assure the safety and reliability of the rubber components. In this paper, the evaluation of characteristics and useful life prediction of rubber component for elevator cabin were experimentally investigated. The material test and accelerated heat-aging test were carried. Rubber material constants were obtained by curve fittings of simple tension, pure shear and bi-axial tension test data. Heat aging test results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the rubber material and component test several useful life prediction equations for rubber component were proposed. Predicted useful life of rubber component for elevator cabin agreed fairly with the experimental lives.

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조성비에 따른 3종 페라이트/고무 복합형 전파흡수체의 정합조건 설계 (The Matching Condition Design of Three Kinds of Ferrite/Rubber Composite Microwave Absorber according to the Constitutional Rate)

  • 유영준;양윤석;전홍배;김철한;김한근;사공건
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.247-250
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    • 1999
  • In this study, three kinds of Mn-Zn ferrite/Ni-Zn ferrite/$Ni_2Y$ ferroxplana prepared by the coprecipitation method was compounded with silicon rubber, and thereafter made ring-type specimens with various compositional ratio. The material constant of ferrite/rubber composite absorbers was obtaibed by the 2-port method. The material constants of the ferrite/rubber composite absorber with various compositional ratio of three kinds of ferrite were used to design the matching frequency and thickness with the impedance matching map. We were able to predict the matching condition from the design method.

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Theoretical analysis of rotary hyperelastic variable thickness disk made of functionally graded materials

  • Soleimani, Ahmad;Adeli, Mohsen Mahdavi;Zamani, Farshad;Gorgani, Hamid Haghshenas
    • Steel and Composite Structures
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    • 제45권1호
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    • pp.39-49
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    • 2022
  • This research investigates a rotary disk with variable cross-section and incompressible hyperelastic material with functionally graded properties in large hyperelastic deformations. For this purpose, a power relation has been used to express the changes in cross-section and properties of hyperelastic material. So that (m) represents the changes in cross-section and (n) represents the manner of changes in material properties. The constants used for hyperelastic material have been obtained from experimental data. The obtained equations have been solved for different m, n, and (angular velocity) values, and the values of radial stresses, tangential stresses, and elongation have been compared. The results show that m and n have a significant impact on disk behavior, so the expected behavior of the disk can be obtained by an optimal selection of these two parameters.

새로운 N2O계 세 자리 리간드의 합성과 전이금속 착물 안정도상수 (Synthesis of New N2O Tridentate Ligands and Their Stability Constants of Transition Metal Complexes)

  • 김선덕;박영식
    • 대한화학회지
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    • 제47권6호
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    • pp.569-577
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    • 2003
  • 피리딘과 페놀을 포함하는 N2O계 세 자리 리간드 2-[(2-pyridine-2- ethylamino)-methyl]-phenol(H-PEMP)를 합성하였다. 또한 H-PEMP 페놀의 5-위치에 치환기로 브롬, 염소 및 메톡시를 가지는 Br-PEMP, Cl-PEMP 및 $CH_3O-PEMP$를, 그리고 2-hydroxy-1-naphthalene기를 가진 Naph-PEMP을 합성하였다. 합성된 각 리간드들을 수용액에서 전위차 적정 결과 양성자 해리는 3 단계로 일어났으며, 계산된 각 리간드의 총괄 양성자 해리상수(log${\beta}$) 값은 $CH_3O-PEMP$〉Naph-PEMP〉H-PEMP〉Br-PEMP〉Cl-PEMP의 순서로 Hammett식의 치환기 상수(${\sigma}_p$) 값 크기 순서와 일치하였다. 전이금속 이온들의 착물 안정도상수(logML 및 log$ML_2$) 값의 크기는 금속이온에 따라 Co(II)< Ni(II)< Cu(II)>Zn(II)의 순서이었고, 치환기에 따른 각 리간드의 착물 안정도상수 값은 리간드의 총괄 양성자 해리상수 값의 크기순서와 일치하였다.

그물구조 수지 촉매상에서 가솔린 옥탄가 향상제인 ETBE 합성 (Synthesis of ETBE as an Octane Enhancer for Gasoline over Macroreticular Robin Catalysts)

  • 박진화;이진형;김재승
    • 공업화학
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    • 제5권5호
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    • pp.825-835
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    • 1994
  • 가솔린 옥탄가 향상제인 ETBE(Ethyl Tertiary Butyl Ether)의 기상합성을 성질이 다른 그물구조형 이온교환 수지인 Amberlyst-15와 Amberlyst XN-1010촉매상에서 고정층 상압 유통식 미분형 반응기로 수행하였다. 반응물로는 ethanol과 isobutene을 사용하였고, 반응온도 $70-140^{\circ}C$ 범위에서 실험을 행하여 수지촉매들의 활성을 비교한 결과 Amberlyst-15의 활성이 Amberlyst XN-1010보다 우수하였다. 미분형 반응기로부터 얻은 속도론적 자료를 선형회귀분석하여 적합한 속도모델과 매개변수를 구한 결과 ETBE합성반응은 LHHW(Langmuir-Hinshelwood-Hougen-Waston) 반응기구에 의하여 이루어진 것으로 보여진다. 또한, 각 온도에 따른 표면 반응속도 상수와 반응물들의 흡착평형상수와 표면반응 활성화 에너지를 구하였으며, Amberlyst-15 및 Amberlyst XN-1010의 활성화에너지는 각각 18.64 및 24.19 Kcal/mol이었다.

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Transparent Capacitor of the $Bi_2Mg_{2/3}Nb_{4/3}O_7$(BMNO)-Bi Nanostructured Thin Films grown at Room Temperature

  • 송현아;나신혜;정현준;윤순길
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 추계학술발표대회
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    • pp.20.2-20.2
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    • 2011
  • BMNO dielectric materials with a pyrochlore structure have been chosen and they have quite high dielectric constants about 210 for the bulk material. In the case of thin films, 200-nm-thick BMNO films deposited at room temperature showed a low leakage current density of about $10^{-8}\;A/cm^2$ at 3 V and a dielectric constant of about 45 at 100 kHz. Because high dielectric constant BMNO thin films kept an amorphous phase at a high temperature above $900^{\circ}C$. High dielectric constant BMNO thin films grown at room temperature have many applications for flexible electronic devices. However, because the dielectric constant of the BMNO films deposited at room temperature is still low, percolative BMNO films (i.e., those were grown in a pure argon atmosphere) sandwiched between ultra-thin BMNO films grown in an oxygen and argon mixture have greater dielectric constants than standard BMNO films. However, they still showed a leakage problem at a high voltage application. Accordingly, a new nano-structure that uses BMNO was required to construct the films with a dielectric constant higher than that of its bulk material. The fundamental reason that the BMNO-Bi nano-composite films grown by RF-Sputtering deposition had a dielectric constant higher than that of the bulk material was addressed in the present study. Also we used the graphene as bottom electrode instead of the Cu bottom electrode. At first, we got the high leakage current density value relatively. but through this experiment, we could get improved leakage current density value.

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