• Title/Summary/Keyword: Material Constants

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A Study on the Absorptive Removal of Magnesium ion and Calcium ion for Corrosion Prevent (부식방지를 위한 마그네슘 및 칼슘 이온의 흡착 제거에 관한 연구)

  • Hong Sung-Uk;An Hyung-Hwan
    • Journal of the Korean Society of Safety
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    • v.19 no.3 s.67
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    • pp.40-44
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    • 2004
  • To the removal of hardness materials, we've test the absorptive capacity of main material $Mg^{2+},\;Ca^{2+}$ on the using the activated carbon powder saturated in 0.1M Nitrilotriacetic acid by experimental methods. The absorptive properties of $Ca^{2+}\;and\;Mg^{2+}$ were measured with absorbent quantity and contact time., and investigated the physical properties of overall rate constant and adsorption constant adsorption isotherm, and Langmuir and Freundlich constant. In case of k' adsorption rate constants of $Ca^{2+},\;Mg^{2+}$, was 0.00299, 0.00529 by Bhattahary and Venkobachar equation. $k_{aa}$ was 0.00373, 0.00640 according with adsorption rate constants of Lagergren.

Deposition of PbTio3 thin films by reactive sputtering

  • Ahn, Y.S.;Lee, D.S.;Ahn, E.J.;Yoon, E.
    • Journal of Korean Vacuum Science & Technology
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    • v.3 no.2
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    • pp.126-129
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    • 1999
  • PbTio3 is a promising material with perovskite structure for pyroelectric sensor applications with its superior pyroelectric properties, low dielectric constants, and low piezoelectric constants. Growth of pyroelectric thin films in general, needs relatively higher temperatures than those of conventional Si semiconductor processing However, low growth temperature is advantageous for the device integration. We report the low temperature (350$^{\circ}C$) growth of PbTio3 thin films by 3-gun DC magnetron reactive sputtering. The effects of substrate temperature, Pb-flux, and total pressure on crystalinity and preferred orientation of PbTio3 thin films are reported.

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Free-edge effect in cross-ply laminated plates under a uniform extension

  • Sheng, Hongyu;Ye, Jianqiao
    • Structural Engineering and Mechanics
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    • v.18 no.3
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    • pp.377-388
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    • 2004
  • Based on the basic equations of elasticity, free-edge effects on stresses in cross-ply laminated plates are found by using the state space method. The laminates are subjected to uniaxial-uniform extension plate, which is a typical example of general plane strain problem. The study takes into account material constants of all individual material layers and the state equation of a laminate is solved analytically in the through thickness direction. By this approach, a composite plate may be composed of an arbitrary number of orthotropic layers, each of which may have different material properties and thickness. The solution provides a continuous displacement and inter-laminar stress fields across all material interfaces and an approxiamte prediction to the singularity of stresses occurring in the boundary layer region of a free-edge. Numerical solutions are obtained and compared with the results obtained from an alternative numerical method.

Measurement of Mechanical Material Properties of Rubber Compounds Sampled from a Pneumatic Tire (타이어에서 채취한 고무배합물의 기계적 물성 측정)

  • 김용우;김종국
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2002.04a
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    • pp.404-409
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    • 2002
  • Pneumatic tires usually contain a variety of rubber compositions, each designed to contribute some particular factor to overall performance. Rubber compounds designed for a specific function will usually be similar but not identical In composition and properties. Since 1970`s finite element analysis of tire has been performed extensively, which requires some energy density functions of rubber components of a tire. The conventional Mooney-Rivlin material model is one of the description that is commonly used in the analysis of tire. In this paper, we report the two material constants of gooney-Rivlin material model for some rubber compounds of a real pneumatic tire, which are obtained through uniaxial tension test.

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Useful Lifetime Evaluation of Rubber Component for Elevator Cabin (승강기용 방진고무부품 특성 및 사용수명 평가)

  • Woo, Chang-Su;Park, Hyun-Sung
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.576-580
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    • 2008
  • Rubber material properties and useful life evaluation are very important in design procedure to assure the safety and reliability of the rubber components. In this paper, the evaluation of characteristics and useful life prediction of rubber component for elevator cabin were experimentally investigated. The material test and accelerated heat-aging test were carried. Rubber material constants were obtained by curve fittings of simple tension, pure shear and bi-axial tension test data. Heat aging test results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the rubber material and component test several useful life prediction equations for rubber component were proposed. Predicted useful life of rubber component for elevator cabin agreed fairly with the experimental lives.

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The Matching Condition Design of Three Kinds of Ferrite/Rubber Composite Microwave Absorber according to the Constitutional Rate (조성비에 따른 3종 페라이트/고무 복합형 전파흡수체의 정합조건 설계)

  • 유영준;양윤석;전홍배;김철한;김한근;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.247-250
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    • 1999
  • In this study, three kinds of Mn-Zn ferrite/Ni-Zn ferrite/$Ni_2Y$ ferroxplana prepared by the coprecipitation method was compounded with silicon rubber, and thereafter made ring-type specimens with various compositional ratio. The material constant of ferrite/rubber composite absorbers was obtaibed by the 2-port method. The material constants of the ferrite/rubber composite absorber with various compositional ratio of three kinds of ferrite were used to design the matching frequency and thickness with the impedance matching map. We were able to predict the matching condition from the design method.

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Theoretical analysis of rotary hyperelastic variable thickness disk made of functionally graded materials

  • Soleimani, Ahmad;Adeli, Mohsen Mahdavi;Zamani, Farshad;Gorgani, Hamid Haghshenas
    • Steel and Composite Structures
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    • v.45 no.1
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    • pp.39-49
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    • 2022
  • This research investigates a rotary disk with variable cross-section and incompressible hyperelastic material with functionally graded properties in large hyperelastic deformations. For this purpose, a power relation has been used to express the changes in cross-section and properties of hyperelastic material. So that (m) represents the changes in cross-section and (n) represents the manner of changes in material properties. The constants used for hyperelastic material have been obtained from experimental data. The obtained equations have been solved for different m, n, and (angular velocity) values, and the values of radial stresses, tangential stresses, and elongation have been compared. The results show that m and n have a significant impact on disk behavior, so the expected behavior of the disk can be obtained by an optimal selection of these two parameters.

Synthesis of New N2O Tridentate Ligands and Their Stability Constants of Transition Metal Complexes (새로운 N2O계 세 자리 리간드의 합성과 전이금속 착물 안정도상수)

  • Kim, Sun-Deuk;Park, Young-Sik
    • Journal of the Korean Chemical Society
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    • v.47 no.6
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    • pp.569-577
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    • 2003
  • Ligands, Br-PEMP, Cl-PEMP and $CH_3O-PEMP$ having Br, Cl and $CH_3O$ substituents at 5-position of the $N_2O$ tridentate ligand, 2-[(2-pyridine-2-ethylamio)-methyl]-phenol (H-PEMP) containing pyridine and phenol were synthesized. Another ligand, Naph-PEMP having pyridine and 2-hydroxy-1-naphthalene was also synthesized. The ligands were characterized using elemental analysis, UV-visible, IR, $^1H\;NMR\;and\;^{13}C$ NMR spectroscopy and mass analysis. The potentiometric titration study in aqueous solution revealed that the proton dissociation of the ligands occurred in three steps and the order of overall proton dissociation constants (log${\beta}$) was $CH_3O-PEMP$ > Naph-PEMP > H-PEMP > Cl-PEMP > Br-PEMP. The order of stability constants (logML and log$ML_2$) of their transition metal complexes was Co(II) < Ni(II) < Cu(II) > Zn(II). The order in their stability constants values of each transition metal complex agreed well with that in overall proton dissociation constant value of the ligands.

Synthesis of ETBE as an Octane Enhancer for Gasoline over Macroreticular Robin Catalysts (그물구조 수지 촉매상에서 가솔린 옥탄가 향상제인 ETBE 합성)

  • Park, Jin-Hwa;Lee, Jin-Hyung;Kim, Jae-Seung
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.825-835
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    • 1994
  • Synthesis of ETBE as an octane number enhancer from ethanol and isobutene in a flow reactor under atmospheric pressure was studied. Amberlyst-15 and Amberlyst XN-1010 were used as catalysts within the temperature range of $70-140^{\circ}C$. The activity of Amberlyst 15 was higher than that of Amberlyst XN-1010. The reaction rate data obtained under differential reactor condition were tested by a linear regression method to determine the reaction mechanism and kinetic parameters. The ETBE synthesis reaction seems to be proceeded via the LHHW(Langmuir-Hinshelwood-Hougen-Watson) machanism. The activation energy of the surface reaction was estimated by the reaction rate constants as well as the adsorption equilibrium constants. Apparent activation energies are 18.64 and 24.19kcal/mol for Amberlyst-15 and Amberlyst XN-1010, respectively.

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Transparent Capacitor of the $Bi_2Mg_{2/3}Nb_{4/3}O_7$(BMNO)-Bi Nanostructured Thin Films grown at Room Temperature

  • Song, Hyeon-A;Na, Sin-Hye;Jeong, Hyeon-Jun;Yun, Sun-Gil
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.20.2-20.2
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    • 2011
  • BMNO dielectric materials with a pyrochlore structure have been chosen and they have quite high dielectric constants about 210 for the bulk material. In the case of thin films, 200-nm-thick BMNO films deposited at room temperature showed a low leakage current density of about $10^{-8}\;A/cm^2$ at 3 V and a dielectric constant of about 45 at 100 kHz. Because high dielectric constant BMNO thin films kept an amorphous phase at a high temperature above $900^{\circ}C$. High dielectric constant BMNO thin films grown at room temperature have many applications for flexible electronic devices. However, because the dielectric constant of the BMNO films deposited at room temperature is still low, percolative BMNO films (i.e., those were grown in a pure argon atmosphere) sandwiched between ultra-thin BMNO films grown in an oxygen and argon mixture have greater dielectric constants than standard BMNO films. However, they still showed a leakage problem at a high voltage application. Accordingly, a new nano-structure that uses BMNO was required to construct the films with a dielectric constant higher than that of its bulk material. The fundamental reason that the BMNO-Bi nano-composite films grown by RF-Sputtering deposition had a dielectric constant higher than that of the bulk material was addressed in the present study. Also we used the graphene as bottom electrode instead of the Cu bottom electrode. At first, we got the high leakage current density value relatively. but through this experiment, we could get improved leakage current density value.

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