• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.9 no.5
• /
• pp.1125-1129
• /
• 2008

Polypropylene (PP)/corn starch master batch(starch-MB) blends with different PP compositions of 90, 80, 70, and 60 wt% were prepared by melt compounding at $200^{\circ}C$, using lab scale Brabender mixer. The chemical structures, thermal properties and non-isothermal crystallization behavior of the PP/starch-MB blends were investigated by FT-infrared spectrometry (FT-IR), differential scanning calorimetry (DSC), and thermogravimetric analyzer (TGA). The fabrication of the PP/starch-MB blend was confirmed by the existence of hydroxy group in FT-IR spectrum. There was no district change in melting temperature and melting enthalpy, and TGA curve indicates a decrease in degradation temperature with starch-MB content. The non-isothermal crystallization process was analyzed using by Avrami equation. The Avrami exponents were in the range of 2.71-3.97 for PP and 1.48-1.99 for PP/starch-MB blonds. The activation energies calculated by Kissinger method were 233 kJ/mol for PP, 484 kJ/mol for PP90, 541 kJ/mol for PP80, 553 kJ/mol for PP70, and 422 kJ/mol for PP60.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.10
• /
• pp.6655-6665
• /
• 2015

Due to tightened environmental regulations on halogen type flame retardants, the portions of those based on phosphorous compounds that are non-halogen type is rising. When producing functional film, the physical and thermal properties become distinctly different depending on the amount of Red-phosphorus(RP) addition which causes flame resistance. The physical properties of resin fall in big scale when too much flame retardants are added, and it is hard to be applied to functional films such as shrink or anticorrosive film. The purpose of this research is to study the effects on mechanical, physical, and other properties of RP-LDPE films by changing the RP-MB contents. The LDPE film used for this study was produced through blow-type injection molding. The flame resistance was VTM-0, and the tear resistance showed inverse trends of MD and TD. Contraction percentage showed no relationship with the amount of RP content, but the anti-corrosive property showed 0.05 % better result than the national anti-corrosion shrink film reliability standard.

• Polymer(Korea)
• /
• v.35 no.1
• /
• pp.17-22
• /
• 2011

Polypropylene/multi-walled carbon nanotube(PP/MWCNT) composites along with various MWCNT contents up to 20 wt% were prepared by a twin screw extruder. Nanocomposites having 20 wt% MWCNT as a master batch(M/B) were diluted with PP by way of melt compounding. The electrical/thermal conductivity, morphology, thermal/viscoelastic/mechanical properties were investigated with the variation of MWCNT contents. Also, we compared some properties between 1-step PP/MWCNT and the diluted PP/MWCNT composites. The percolation threshold of electrical and thermal conductivity was measured at about 3 wt% MWCNT. And conductivity of diluted PP/MWCNT composites were superior to those of PP/MWCNT composites. The non-isothermal crystallization temperature and thermal decomposition temperature appeared at higher temperatures with increasing MWCNT contents. Morphology showed that length of MWCNT in diluted PP/MWCNT composites was shortened by twice melt blending, which contributed to improve the tensile strength of PP/MWCNT composites.

• Journal of Korean Society of Industrial and Systems Engineering
• /
• v.38 no.3
• /
• pp.78-86
• /
• 2015

Up-to-date business environment for manufacturers is very complex and rapidly changing. In other words, companies are facing a variety of changes, such as diversifying customer requirements, shortening product life cycles, and switching to small quantity batch production. In this situation, the companies are introducing the concept of JIT (just-in-time) to solve the problem of on-time production and on-time delivery for survival. Though many companies have introduced ERP (enterprise resource planning) systems and MRP (material requirement planning) systems, the performance of these systems seems to fall short of expectations. In this paper, the case study on introducing an APS (advanced planning and scheduling) system based on dispatching rules to a machining company and on finding a method to establish an efficient production schedule is presented. The case company has trouble creating an effective production plan and schedule, even though it is equipped with an MRP-based ERP system. The APS system is applied to CNC (computer numerical control) machines, which are key machines of the case company. The overall progress of this research is as follows. First, we collect and analyze the master data on individual products and processes of the case company in order to build a production scheduling model. Second, we perform a pre-allocation simulation based on dispatching rules in order to calculate the priority of each order. Third, we perform a set of production simulations applying the priority value in order to evaluate production lead time and tardiness of pre-defined dispatching rules. Finally, we select the optimal dispatching rule suitable for work situation of the case company. As a result, an improved production schedule leads to an increase in production and reduced production lead time.

• Elastomers and Composites
• /
• v.37 no.1
• /
• pp.14-20
• /
• 2002

Silica-filled rubber compound needs longer mixing time compared to carbon black-filled one since it has poor dispersion or the filler. Influence of the mixing procedure on the properties of natural rubber compound filled with both silica and carbon black was studied. The discharge temperature of the master batch (MB) mixing was $150^{\circ}C$. The mixing time was longer when silica and carbon black were loaded separately than when loaded simultaneously. The mixing time was longer when silica was loaded first than when carbon black is loaded first. The compounds prepared by one MB step (conventional mixing) were compared with the compounds prepared by two MB steps (two-step mixing). Scorch times of the two-step mixing compounds were longer than those by the conventional mixing ones. Bound rubber contents of the formers were lower than those of the tatters. The two-step mixing vulcanizates had longer elongation at break, higher tensile strength, and better fatigue life.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.16 no.11
• /
• pp.7917-7924
• /
• 2015

In this study, based on CMA which is increasingly used for eco-friendly deicing materials, dehumidification MB made of sodium carbonate, $MgCl_2$/MgO (M/M), and SAP is to be produced. And its moisture absorption rate and dehumidification performance of the film are to be analyzed. And the data on the materials used for the dehumidification film are to be acquired. In case of the dehumidification MB, in which CMA and SAP are mixed, had poor film machinability due to foaming and moisture issues, but adding bentonite and calcium carbonate solved the problem. When a foaming agent was added to extend surface area between substances, CMA and M/M showed no remarkable difference, but SC showed large increase to 3.15 g/g. As the result of anti-corrosive test, CMA dehumidification film showed no corrosion while SC showed pitting corrosion and M/M showed corrosion.

• Journal of the Korea Convergence Society
• /
• v.12 no.4
• /
• pp.201-206
• /
• 2021

Damage to the highly pathogenic avian influenza virus(H5N1) continues to increase, but there is a lack of antiviral research. In this study, we analyze antiviral properties on H5N1 by coating Cu/TiO2 photocatalyst on polyethylene films. The specimen was manufactured a photocatalyst master batch and coated both sides of the 3-layer polyethylene fabric at 280℃ from the extrusion coating machine. The results showed a 99.9% decrease in the Staphylococcus aureus and Escherichia coli. In particular, H5N1 type highly pathogenic avian influenza viruses, which is capable of human infection, has been found to decrease 99.9% within five minutes of contact with Cu/TiO2 films. Antibacterial effects of films coated with photocatalyst are known, but this study also confirmed the antiviral effects.

• Applied Chemistry for Engineering
• /
• v.18 no.6
• /
• pp.557-561
• /
• 2007

Polypropylene (PP)/corn starch master batch (starch-MB) blends with different PP compositions of 40, 50, 60, and 80 wt% were prepared by melt compounding at $200^{\circ}C$, using lab scale Brabender mixer. The chemical structures and thermal properties of the PP/starch-MB blends were investigated by FT-IR, differential scanning calorimetry (DSC), and thermogravimetric analyzer (TGA). The chemical structure was confirmed by the existence of hydroxy group. There was no district change in melting temperature and melting enthalpy, and TGA curve indicated a decrease in degradation temperature with starch-MB content. The porosity change of blend was measured by scanning electron microscope (SEM), the degree of porosity on the blend surface increased with the starch-MB content. The rheological properties indicated an increase in complex viscosity, shear thinning tendency and elasticity with the starch-MB concentration. These effects were confirmed by an oscillatory viscometer at $200^{\circ}C$. From these results, it is found that 40 wt% is the optimum starch-MB concentration. The fiber was fabricated from PP60/MB40 with 40 wt% starch-MB and the porosity and tensile properties were investigated.

• Korean Chemical Engineering Research
• /
• v.46 no.1
• /
• pp.106-111
• /
• 2008

Polypropylene (PP)/corn starch master batch (starch-MB)/silicate composites with different corn starch compositions of 10, 20, 30, 40 and 50 were prepared by melt compounding at $200^{\circ}C$, using lab scale Brabender mixer. The content of silicate was fixed at 5 wt%. The composition of starch-MB in composites was confirmed by the existence of hydroxy group and peak intensity in fourier-transform-infrared (FT-IR) spectrum. The thermal properties of the PP/starch-MB/silicate composites were investigated by differential scanning calorimetry (DSC), and thermogravimetric analyzer (TGA). There was no district change in melting temperature, and TGA curve indicates a decrease in degradation temperature with the increase of starch-MB content. The silicate dispersion of the composites was measured by X-ray diffraction (XRD) and transmission electron microscope (TEM). The degree of silicate dispersion in PP/starch-MB/silicate composites depended on the content of starch-MB. There was detectable change in d-spacing and peak intensity of the composite when the content of starch-MB was higher than 20 wt%. The rheological behavior of the composites was explained by both shear thinning effect and elastic property with the starch-MB amount. These effects were remarkable when the content of starch-MB was higher than 20 wt%. These were confirmed by an oscillatory viscometer at $200^{\circ}C$.