• 한국화재소방학회논문지
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• 제33권6호
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• pp.80-86
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• 2019

국내에서는 2012년부터 2018년 까지 총 556건의 화학사고가 발생하였다. 화학사고 중 두 가지 이상의 화학물질 이상반응에 의해 발생하는 사고는 그 원인물질을 파악하는데 많은 시간이 필요하여 효과적인 사고대응과 수습을 위해서 신속한 분석이 필요하다. 본 논문은 이상반응에 의해 발생한 화학사고의 원인물질 파악을 위해 양자전이 비행시간 질량분석기를 사용하였다. 이 분석기는 시료채취와 전처리 없이 빠른 응답시간을 가져 실시간 분석이 가능하며 또한 수소친화도가 높은 대부분의 휘발성유기화합물질의 정량·정성 분석이 가능하여 이상반응에 의해 발생되는 화학사고의 원인 물질을 조사하는데 적합하다. 실제로 201◯년 ◯월에 ◯◯ 지역 화학사고 발생 시 양자전이 비행시간 질량분석기를 이용하여 측정한 결과 메탄올과 톨루엔 등이 검출되는 것을 알았으며 이상반응에 의해 발생된 황 계열 화합물이 사고 주변의 강한 악취의 원인임을 알 수 있었다.

• Nuclear Engineering and Technology
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• 제28권2호
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• pp.175-184
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• 1996

해저에 건설된 방사성폐기물 처분장 방벽에서 핵 종 전달을 평가할 수 있는 한 모델이 제시되었다. 방벽의 출구에서의 물질전달계수와 각 방벽에 대하여 정의된 방벽응답함수를 이용하여 이들 방벽으로부터의 핵종의 전달률을 구할 수 있다. 이러한 접근은 단순하고 즉각적인 계산결과가보수적인 측면에서 요구되어지는 경우 방벽들을 연속된 별개의 매질로 다루어 각각의 응답함수를 적용할 수 있기 때문에 유용하다. 단점으로는 인접한 두 방벽사이에서, 이전의 방벽으로부터의 핵종의 유출율이 연속되는 방벽으로의 유입율로 되어 핵종속은 보존되는 반면 핵종의 농도는 반드시 보존되지는 않는다는 것으로, 이는 두 방벽 매질의 경계에서 핵종전달저항이 없다고 가정할 수 있는 것으로 해결될 수 있다. 물질전달계수는 방벽의 출구 쪽 경계에서의 핵 종의 농도가 일정하다고 보아 구할 수 있고, 매질의 응답함수는 각 방벽에 대하여 핵종의 단위 펄스입력에 대해 경계에서의 농도에 대한 해를 구한 후 물질전달계수를 적용하여 얻을 수 있다. 이리하여 한 방벽매질에 대한 시간 종속적인 핵종의 총전달률은 응답함수에 이전의 방벽에 대해 계산된 핵종의 전달률을 컨볼루트하여 구할 수 있다.

• 대한화학회지
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• 제22권5호
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• pp.340-355
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• 1978

化學反應 수반하는 氣體吸着反應器의 設計에 가장 重要한 氣液界面間의 物質傳達係數와 面積을 測定하는데 자주 모델反應이 利用된다. 本硏究는 그 中에서 wetted wall column 에 sulfite-system을 dldydgkdu 特別히 氣液間의 接觸時間이 氣體吸着速道에 미치는 영향을 硏究 檢討하였다. 反應速道가 매우 빠르거나 늦으면 column의 길이에 따라서, 다시 말하면 接觸時間에 따라서 氣體吸着速道에 差異가 크다는 것을 發見했다. 反應速道恒數 $k_2=5.5{\times}10^6m^3/kmol{\cdot}s$ 近處에서는 이 差異가 없어진다. 換言하면 이런 條件下에서 裝置의 hydrodynamics가 氣體吸着速道에 無關해진다. 金屬 column 代身에 graphite column을 使用할 수 있다는 例證을 題示하였다.

• 설비공학논문집
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• 제16권2호
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• pp.167-174
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• 2004

A sorption cool pad brings cooling effect without any pre-cooling, nor any external energy supply. It uses evaporative cooling effect stimulated by the desiccative sorption. In this paper, heat and mass transfer in the sorption cool pad are investigated theoretically. The evaporative cooling process caused by the desiccant is modeled and analyzed considering the sorption characteristics of the desiccant. Two nondimensional parameters are found to dominate the cooling process： one is related to the psychrometric characteristics and the other is to the sorption capacity of the desiccant. The former decides the time to reach the lowest temperature and the later controls the time duration of the cooling effect being sustained.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제21권2호
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• pp.89-107
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• 2017

In this paper, we have proposed a modified Marker-And-Cell (MAC) method to investigate the problem of an unsteady 2-D incompressible flow with heat and mass transfer at low, moderate, and high Reynolds numbers with no-slip and slip boundary conditions. We have used this method to solve the governing equations along with the boundary conditions and thereby to compute the flow variables, viz. u-velocity, v-velocity, P, T, and C. We have used the staggered grid approach of this method to discretize the governing equations of the problem. A modified MAC algorithm was proposed and used to compute the numerical solutions of the flow variables for Reynolds numbers Re = 10, 500, and 50000 in consonance with low, moderate, and high Reynolds numbers. We have also used appropriate Prandtl (Pr) and Schmidt (Sc) numbers in consistence with relevancy of the physical problem considered. We have executed this modified MAC algorithm with the aid of a computer program developed and run in C compiler. We have also computed numerical solutions of local Nusselt (Nu) and Sherwood (Sh) numbers along the horizontal line through the geometric center at low, moderate, and high Reynolds numbers for fixed Pr = 6.62 and Sc = 340 for two grid systems at time t = 0.0001s. Our numerical solutions for u and v velocities along the vertical and horizontal line through the geometric center of the square cavity for Re = 100 has been compared with benchmark solutions available in the literature and it has been found that they are in good agreement. The present numerical results indicate that, as we move along the horizontal line through the geometric center of the domain, we observed that, the heat and mass transfer decreases up to the geometric center. It, then, increases symmetrically.

• Earthquakes and Structures
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• 제12권4호
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• pp.425-436
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• 2017

Vibration control using a tuned mass damper (TMD) is an effective technique that has been verified using analytical methods and experiments. It has been applied in mechanical, automotive, and structural applications. However, the damping of a TMD cannot be adjusted in real time. An excessive mass damper stroke may be introduced when the mass damper is subjected to a seismic excitation whose frequency content is within its operation range. The semi-active tuned mass damper (SATMD) has been proposed to solve this problem. The parameters of an SATMD can be adjusted in real time based on the measured structural responses and an appropriate control law. In this study, a stiffness-controllable TMD, called a leverage-type stiffness-controllable mass damper (LSCMD), is proposed and fabricated to verify its feasibility. The LSCMD contains a simple leverage mechanism and its stiffness can be altered by adjusting the pivot position. To determine the pivot position of the LSCMD in real time, a discrete-time direct output-feedback active control law that considers delay time is implemented. Moreover, an identification test for the transfer function of the pivot driving and control systems is proposed. The identification results demonstrate the target displacement can be achieved by the pivot displacement in 0-2 Hz range and the control delay time is about 0.1 s. A shaking-table test has been conducted to verify the theory and feasibility of the LSCMD. The comparisons of experimental and theoretical results of the LSCMD system show good consistency. It is shown that dynamic behavior of the LSCMD can be simulated correctly by the theoretical model and that the stiffness can be properly adjusted by the pivot position. Comparisons of experimental results of the LSCMD and passive TMD show the LSCMD with less demand on the mass damper stroke than that for the passive TMD.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제21권1호
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• pp.39-61
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• 2017

In this present article, we analyzed the heat and mass transfer characteristics of the nonlinear unsteady radiative MHD flow of a viscous, incompressible and electrically conducting fluid past an infinite vertical porous plate under the influence of Soret and chemical reaction effects. The effect of physical parameters are accounted for two distinct types of thermal boundary conditions namely prescribed uniform wall temperature thermal boundary condition and prescribed heat flux thermal boundary condition. Based on the flow nature, the dimensionless flow governing equations are resolved to harmonic and non harmonic parts. In particular skin friction coefficient, Nusselt number and Sherwood number are found to evolve into their steady state case in the large time limit. Parametric study of the solutions are conducted and discussed.

• Geomechanics and Engineering
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• 제6권6호
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• pp.517-530
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• 2014

Seismic ground response analysis is one of the most important issues in geotechnical earthquake engineering. Conventional seismic site response and free field analysis of layered soils does not consider the effect of surcharge mass which may be present on the top layer. Surcharge mass may develop extra inertial force to the soil and, hence, significantly affect on the results of seismic ground response analysis. Methods of analysis of ground response may also be categorized into time domain and frequency domain concepts. Simplicity in developing analytical relations and accuracy in considering soil dynamic properties dependency to loading frequency are benefits of frequency domain analysis. In this part of the paper, seismic ground response is analyzed using transfer function method for soil layers considering surcharge mass on the top layer. Equation of motion, wave equation, is solved using amended boundary conditions which effectively take the impact of surcharge mass into account. A computer program is developed by MATLAB software based on the solution method developed for wave equation. Layered soils subjected to earthquake loading were numerically studied and solved especially by the computer program developed in this research. Results obtained were compared with those given by DEEP SOIL computer program. Such comparison showed the accuracy of the program developed in this study. Also in this part, the effects of geometrical and mechanical properties of soil layers and especially the impact of surcharge mass on transfer function are investigated using the current approach and the program developed. The efficiency and accuracy of the method developed here is shown through some worked examples and through comparison of the results obtained here with those given by other approaches. Discussions on the results obtained are presented throughout in this part.

• 한국화재소방학회논문지
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• 제6권1호
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• pp.17-22
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• 1992

We have derived the general transfer equation for governing the continuity, energy transfer, mass and momentum transfer, and turbulent energy dissipation rate within the fire compartment which has the 800t fire source at the center of the floor. The governing transfer equations have been descretized using the finite volume approach and numerically experimented under the SIMPLE algorithm. In order for the SIMPLE algorithm approach to be physically reliable, the test results are compared with those of Morita's SOR Method using Conjugate Residual Method and found to be close to physical values though the computational convergence time still remains to be upgraded. The treatment of source terms in the system of finite difference equations has been critical in order to converge the governing equations within the appropriate time steps. The criteria of convergence allowance for the whole domain have been checked and the sudden change of the non-linear effects from the source term have been avoided. The criteria has been allowed to be for 5$\times$10$^{-5}$ .

• 한국수소및신에너지학회논문집
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• 제34권3호
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• pp.283-291
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• 2023

The physical properties were analyzed for four gas diffusion layers, and gas diffusion electrodes (GDEs) for the cathode of high-temperature polymer electrolyte membrane fuel cell were fabricated through bar coating with three binder to carbon (B/C) ratios. Among them, The GDE from JNT30-A6P showed a significant change in secondary pore volume at a B/C ratio of 0.31, which had the largest pore volume among all GDEs. In the polarization curve, JNT30-A6P GDE showed the best membrane electrode assembly (MEA) performance with a peak power density of 384 mW/cm² at a a B/C ratio of 0.31. From the distribution of relaxation time analysis, the peak 1 corresponding to mass transfer resistance of oxygen reduction reaction (ORR) was significantly reduced in the JNT30-A6P GDE. This is the result that when the binder content decreased, the volume of the secondary pore increased, and the mass transfer resistance of ORR decreased, which played an essential role in the MEA performance.