• 제목/요약/키워드: Mass transfer rate

검색결과 862건 처리시간 0.023초

수소저장합금 반응용기에서 수소 흡.탈장과정에서의 열 및 물질전달 특성에 관한 실험적인 연구 (An Experimental Study of Heat and Mass Transfer During Absorption and Desorption Processes in a Hydride Material Bed)

  • 박찬우;강병하;이춘식
    • 대한기계학회논문집
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    • 제19권1호
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    • pp.202-211
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    • 1995
  • Heat and hydrogen transfer characteristics have been experimentally investigated for a hydride reaction bed, in which hydride material LaN $i_{4,7}$A $l_{0.3}$ is contained for hydrogen storage. This problem is of particular interest in the design of metal hydride devices such as metal-hydride refrigerators, heat pumps, or metal-hydride storage units. Transient behavior of hydrogen transfer through the hydride materials as well as heat transfer is studied during absorption and desorption processes in detail. The experimental results obtained indicate that the mass flow of the hydrogen is strongly affected by the governing parameters, such as the initial pressure of the reaction bed, absorption or desorption period, and cooling or heating temperature. These mass transfer results are along with the heat transfer rate between hydride materials and heat transfer medium in the reaction bed.d.d.

Mass transfer in cross-flow dialyzer with internal recycle

  • Yeh, Ho-Ming;Chen, Chien-Yu
    • Membrane and Water Treatment
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    • 제4권4호
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    • pp.251-263
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    • 2013
  • The internal reflux effect on dialysis through the retentate phase of a countercurrently cross-flow rectangular module is investigated. Theoretical analysis of mass transfer in cross-flow devices with or without recycling is analogous to heat transfer in cross-flow heat exchangers. In contrast to a device without reflux, considerable mass transfer is achievable if cross-flow dialyzers are operated with reflux, which provides an increase in fluid velocity, resulting in a reduction in mass-transfer resistance. It is concluded that reflux can enhance mass transfer, especially for large flow rate and feed-concentration operated under high reflux ratio.

Dialysis in double-pass cross-flow rectangular membrane modules with external recycle for improved performance

  • Yeh, Ho-Ming
    • Membrane and Water Treatment
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    • 제2권2호
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    • pp.75-89
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    • 2011
  • The predicting equations for mass transfer rate in cross-flow rectangular dialyzers with double flow and recycle, have been derived by mass balances. The recycling operation has two conflicting effects. One is the desirable effect of the increase in fluid velocity, resulting in an increased mass transfer coefficient. The other is the undesirable effect of the reduction in concentration difference due to remixing, resulting in decreased mass-transfer driving force. In contrast a single-pass device without recycling, considerable improvement in mass transfer is achieved if the cross-flow rectangular dialyzer of same size is operated with double pass and external recycling. It is concluded that recycle can enhance mass transfer, especially for larger reflux ratio.

LiBr계 용액을 사용한 수직관 흡수기의 열 및 물질 전달에 관한 연구 (A Study on Heat and Mass Transfer in a Vertical Tube Absorber Using LiBr Family Solutions)

  • 조현철;김종보;정시영;강상우;이춘식
    • 설비공학논문집
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    • 제7권2호
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    • pp.196-206
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    • 1995
  • Experimental investigations on heat and mass transfer characteristics in a vertical tube absorber have been carried out. Three different copper tubes with a length of 1.5m have been tested using LiBr solution and LiBr-$CaCl_2$ solution. The effects of solution flow rate, cooling water temperature, solution inlet temperature and evaporation temperature have been investigated in detail. It is found that heat transfer coefficient increases gradually with the increase of solution flow rate, but decreases rapidly for the flow rates less than 0.02kg/ms. The grooved tube generally shows better heat transfer performances than the smooth tube. LiBr solution shows almost no absorption capability for the cooling water temperatures over $40^{\circ}C$. LiBr-$CaCl_2$ gives less decreasing rate in absorption capability at these temperatures and the heat transfer coefficient becomes less dependent on the types of tubes in use. Considering heat and mass transfer rates, LiBr-$CaCl_2$ solution is found to be more suitable than LiBr solution for air cooled absorber, which operates at higher temperature than water cooled absorber.

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수평관 내에서 이산화탄소 초임계 가스냉각 과정의 열전달 및 압력강하 특성에 관한 실험적 연구 (An Experimental Study on Heat Transfer and Pressure Drop Characteristics during Supercritical Process of Carbon Dioxide in a Horizontal Tube)

  • 최이철;강병하;김석현
    • 설비공학논문집
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    • 제16권5호
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    • pp.414-420
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    • 2004
  • The heat transfer and pressure drop characteristics associated with the gas cooling of the supercritical carbon dioxide in a horizontal tube have been investigated experimentally. This problem is of particular interest in the design of a gas cooler of cooling systems using $CO_2$refrigerant. The test section is consisted of 6 series of 455 mm in length, 4.15 mm ID copper tube, respectively. The effects of the inlet temperature, pressure and mass flow rate on the heat transfer and pressure drop of $CO_2$in a horizontal tube is studied in detail. The heat transfer coefficient of $CO_2$is varied by temperature, inlet pressure, and mass flow rate of $CO_2$. This has maximum value at near the pseudocritical temperature. The pressure drop is changed by inlet pressure and mass flow rate of $CO_2$. The results have been compared with those of previous work. The heat transfer correlation at the supercritical gas cooling process is also suggested.

경사진 원형관에서의 공냉응축에 관한 실험적 연구 (Experimental Study of Air-cooled Condensation in Slightly Inclined Circular Tube)

  • 김동억;권태순;박현식
    • 한국유체기계학회 논문집
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    • 제19권4호
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    • pp.29-34
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    • 2016
  • In this study, the experimental investigation of air-cooled condensation in slightly inclined circular tubes with and without fins has been conducted. In order to assess the effects of the essential parameters, variable air velocities and steam mass flow rates were given to the test section. The heat transfer performance of air-cooled condensation were dominantly affected by the air velocity, however, the increase of the steam mass flow rate gave relatively weaker effects to total heat transfer capability. And in the experimental cases with the finned tube, the total heat transfer rate of the finned tube was significantly larger than that of the flat tube. From those results, it can be confirmed that the most important parameter for air-cooled condensation heat transfer is the convective heat transfer characteristics of air. Therefore, for the well-designed long-term cooling passive safety system, the consideration of the optimal design of the fin geometry is needed, and the experimental and numerical validations of the heat transfer capability of the finned tube would be required.

폴리(에틸렌 나프탈레이트)의 축중합 반응에서 물질 전달 현상 (Mass Transfer Phenomena in Polycondensation Reaction of Poly(ethylene naphthalate))

  • 이성진;정성일
    • 폴리머
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    • 제28권2호
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    • pp.121-127
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    • 2004
  • 폴리(에틸렌 나프탈레이트)의 축중합 반응은 가역반응이므로 부반응 물질인 에틸렌 글라이콜의 신속한 제거가 높은 분자량의 제품을 얻는데 매우 중요하다. 본 연구에서는 폴리(에틸렌 나프탈레이트)올리고머로 박막을 제조하여 실제 반응기와 동일한 조건 하에서 (28$0^{\circ}C$, <0.1mmHg) 반응시켜 이 때 일어나는 물질 전달 현상을 관찰하고자 하였다. 여러 가치 두께의 박막을 제조하여 반응 실험한 결과 두께가 0.025cm 이하의 영역에서는 박막에서의 물질 전달 저항이 크지 않아 총괄 반응 속도에 영향을 미치지 않음을 관찰하였다. 물질 전달 모델 및 확산 모델을 사용하여 반응 결과를 예측한 결과 두 모델 모두 실험 결과를 잘 예측하였으나 확산 모델의 경우 중합도가 낮은 영역에서 물질 전달 모델에 비해 반응이 더 빨리 진행되는 경향을 보였다. 두 모델을 이용하여 물질 전달 관련 계수를 예측한 결과 폴리(에틸렌 나프탈레이트)에서의 확산 계수는 4.7${\times}$$10^{-6}$$\textrm{cm}^2$/sec, 물질 전달 계수는 1.4${\times}$$10^{-4}$cm/sce로 폴리(에틸렌 테레프탈레이트) 경우보다 작은 값을 보였다.

균일 전단류내에 있는 원봉주위의 국소 대류 물질 전달에 관한 실험적 연구 (Experimental Study on Local Convective Mass Transfer From a Circular Cylinder in Uniform Shear Flow)

  • 류명석;성형진;정명균
    • 대한기계학회논문집
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    • 제13권4호
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    • pp.789-798
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    • 1989
  • 본 연구에서는 평균속도구배를 용이하게 변화시킬 수 있는 전단유동 발생기를 제작하였다. 최고속도구배는 38se $c^{-1}$까지 얻을 수 있으며 최대중심선 속도는 15m/sec까지이다. 10개의 채널(두께 2mm인 알루미늄판)로 유동단면을 등분하 였으며, 각 채널의 내부저항조절 방법으로 마름모형태의 막대인 knob을 설치하였다.

연료전지용 판형 막 가습기의 유동방향에 따른 열 및 물질전달 특성에 관한 해석적 연구 (Numerical Study of Characteristic of Heat and Mass Transfer in Planar Membrane Humidifier According to Flow Direction)

  • 윤성호;변재기;최영돈
    • 대한기계학회논문집B
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    • 제37권5호
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    • pp.503-511
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    • 2013
  • 연료전지 시스템에서 공급기체 가습은 연료전지 성능효율과 전해질막 수명 향상 측면에서 중요하다. 판형 막 가습기는 일반적으로 유동 방향에 따라 직교류와 대향류로 구분되고 판과 막 사이에서 고온 다습한 공기와 저온 건조한 공기의 열 및 물질전달이 이루어진다. 본 연구에서는 현열 및 잠열 ${\varepsilon}$-NTU 법을 이용하여 입구 온도와 유량 변화에 따른 열 및 물질전달 성능 변화를 유동 방향에 따라 비교하였다. 이를 통하여 저유량 일 때 대향류는 직교류 보다 열 및 물질전달 성능이 높은 것을 알 수 있었고 유량이 증가함에 따라 성능 차이가 감소되는 것을 확인할 수 있었다. 그리고 입구온도가 증가함에 따라 열전달 성능 변화는 작은 반면 물질전달 성능 변화는 비선형으로 크게 감소되는 결과를 얻었다.

Non-absorbable Gas Effects on Heat and Mass Transfer in Falling Film Absorption

  • Kim, Byongjoo;Lee, Chunkyu
    • Journal of Mechanical Science and Technology
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    • 제17권4호
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    • pp.581-589
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    • 2003
  • Film absorption involves simultaneous heat and mass transfer in the gas-liquid system. While the non-absorbable gas does not participate directly In the absorption process. its pretence does affect the overall heat and mass transfer. An experimental study was performed to investigate the heat and mass transfer characteristics of LiBr-H$_2$O solution flow ing over 6-row horizontal tubes with the water vapor absorption in the pretence of non-absorbable gases. The volumetric concentration of non-absorbable gas, air, was varied from 0.17 to 10.0%. The combined effects of the solution flow rate and its concentration on the heat and mass transfer coefficients were also examined. The presence of 2% volumetric concentration of air resulted in a 25% reduction in the Nusselt number and 41% reduction in the Sherwood number Optimum film Reynolds number was found to exist at which the heat and mass transfer reach their maximum value independent of air contents. Reduced Nusselt and Sherwood numbers. defined as the ratio of Nusselt and Sherwood numbers at given non-absorbable gas content to that with pure water vapor, were correlated to account for the reduction in the heat and mass transfer due to non-absorbable gases in a falling film absorption process.