• Title/Summary/Keyword: Mass transfer rate

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A Study on the Temperature Crack Control for Analysis of Hydration Heat of Mass Concrete Transfer Girder with Design Strength $40N/mm^2$ (설계강도 $40N/mm^2$ 매스콘크리트인 전이층보의 수화열 해석을 통한 온도 균열 제어에 관한 연구)

  • Lee, Jong-Suk;Kim, Ju-Sang;Kang, Youn-Woo;Kim, Jae-Hwan;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.04a
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    • pp.33-36
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    • 2007
  • In order to select the optimum mix for the required fluidity and strength of mass concrete which is applied to transfer girder and to choose the optimum curing method depending on circumstances through hydration heat analysis of mass concrete, this study examined slump flow, air content and elapsed variation (0, 30, 60, 90) in unhardened concrete properties and reviewed compressive strength characteristics in hardening properties. And hydration heat analysis results through simulation are as follows; 1) Fluidity changes of unhardened concrete showed no significant difference, and those of elapsed variation also showed no difference but a bit of tendency to increase in comparison with the initial properties. 2) The higher the water-binder ratio was, the lower the compressive strength properties were, and the higher the fly ash replacement rate was, the lower the compressive strength development was. 3) In case of $Fc=40N/mm^2$, the optimum mix was fly ash replacement rate of 15% from water-binder ratio of 33.0%. 4) Hydration heat analysis results showed that in case of bundle cast, concrete temperature profile characteristics around transfer girder was unfavorable, and in case of separate cast, constant curing for at least seven days guaranteed thermal cracking index of 1.2.

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Study of Pyrolysis Pattern and Transfer Rate of Organochlorine Pesticide in Tobacco

  • Min, Hye-Jeong;Jang, Seok-Su;Kim, Ick-Joong;Kim, Yong-Ha;Min, Young-Keun
    • Journal of the Korean Society of Tobacco Science
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    • v.29 no.2
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    • pp.118-124
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    • 2007
  • GRLs(Guidance Residue Levels) of agricultural chemicals for tobacco are recommended by the CORESTA Agro-Chemical Advisory Committee guide. In the GRLs list, organochlorine group is one of pesticides commonly used on tobacco cultivation. In this model study, the quantitative correlation in the transfer rate of pesticide residue into tobacco smoke by spiking of organochlorine pesticides to cigarette and pyrolysates were investigated. The spiking concentration referred to the range of GRLs list and the organochlorine pesticides in mainstream smoke were analyzed by GC-MS. For the understanding of the composition variation versus temperature, the behavior of pesticides was investigated by pyrolysis-gas chromatography-mass spectrometry(Py-GC-MS). In this study, the transfer rate of pesticide residue into tobacco smoke at four different spiking concentration and the composition of pyrolysates were analyzed differently. At $10\;{\mu}g/cig$ spiking concentrations, the organochlorine pesticides were transferred into tobacco smoke in $0.02\;{\sim}\;10.19\;%$ each of component and the most of pesticides were pyrolyzed during smoking. It was found that the decomposition compounds from organochlorine pesticides were mainly composed of oxygenated and nitrogenous compounds. This study could estimate that the transfer rate of pesticides into tobacco smoke is very small amount.

AC Impedance Study of Hydrogen Oxidation and Reduction at Pd/Nafion Interface

  • Song, Seong-Min;Koo, Il-Gyo;Lee, Woong-Moo
    • Transactions of the Korean hydrogen and new energy society
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    • v.12 no.3
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    • pp.231-238
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    • 2001
  • Electrocatalytic activity of palladium for hydrogen oxidation and reduction was studied using AC impedance method. The system under study was arranged in electrolytic mode consisting of Pd electrode under study, Pt counter electrode and Nafion electrolyte between them. Two types of Pd electrodes were used - carbon-supported Pd (Pd/C) and Pd foil electrode. Pd/C anode contacting pure hydrogen showed a steady decrease of charge transfer resistance with the increase of anodic overpotential, which is an opposite trend to that found with Pd foil anode. But Pd foil cathode also exhibited a decrease of the resistance with the increase of cathodic overpotential. The relationship between imposition of overpotential and subsequent change of the charge transfer resistance is determined by the ratio of the rate of faradaic process to the rate of mass transportation; if mass transfer limitation holds, increase of overpotential accompanies the increase of charge transfer resistance. Regardless of the physical type of Pd electrode, the anode contacting hydrogen/oxygen gas mixture did not reveal any independent arc originated from local anodic oxygen reduction.

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Distribution Model Based on Computer Simulation for Internal Temperature and Moisture Content in Press Drying of Tree Disks (원판(圓板)의 열판건조(熱板乾燥)에서 컴퓨터 시뮬레이션에 의한 내부온도(內部溫度)와 함수율(含水率) 분포모형(分布模型))

  • Yeo, Hwan-Myeong;Jung, Hee-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.2
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    • pp.61-70
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    • 1994
  • This study was executed to find the applicability of press drying of tree disk by investigating the shrinkage and drying defect and to form appropriate model by comparing the actual moisture content(MC) and internal temperature in respect of drying time with calculated values based computer simulation to which was applied finite difference method. In press drying disk, heating period, constant drying rate period maintained plateau temperature at 100$^{\circ}C$ and falling drying rate period were significantly distinguished. Actual MC and internal temperature were analogous to those calculated at comparing points. Heat transfer model formed by Fourier's law using specific heat of moist wood and conduction coefficient considering fractional volume of each element of wood cell wall, bound water, free water and air showed applicability as basic data to developing heat expansion, shrinkage and drying stress during press drying. Also mass transfer model formed by Fick's diffusion law using water vapor diffusion coefficient showed applicability. Longitudinal shrinkage was developed by pressure of hot press and tangential shrinkage was restrained by hygrothermal recovery. The heart check, surface check and ring failure were occurred differently in species, but V-shaped crack didn't develop.

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Performance Evaluation of Double-Tube Condenser using Smooth and Micro-Fin Tubes for Natural Mixture Refrigerant (Propane/Butane)

  • Lee, Sang-Mu;Lee, Joo-Dong;Koyama, Shigeru;Park, Byung-Duck
    • International Journal of Air-Conditioning and Refrigeration
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    • v.15 no.1
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    • pp.25-33
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    • 2007
  • The investigation has been made into the prediction of heat exchange performance of a counter flow type double-tube condenser for natural refrigerant mixtures composed of Propane/n-Butane or Propane/i-Butane in a smooth tube and micro-fin tube. Under various heat transfer conditions, mass flux, pressure drop and heat transfer coefficient of the mixed refrigerants were calculated using a prediction method, when the length of condensing tube, total heat transfer rate, mass flux and outlet temperature of coolant were maintained constant. Also, the predicted results were compared with those of HCFC22. The results showed that the mixed refrigerants of Propane/n-Butane or Propane/i-Butane could be substituted for HCFC22, while the pressure drop and overall heat transfer coefficient of the refrigerants were evaluated together.

A Study on Charateristic of Modern Packing, 25mm NSW-ring, ppm by Absorption of NH3 gas (25mm NSW-ring, pp.를 충진한 충진탑에서 암모니아 흡수에 의한 유해가스 처리시 충진물의 특성연구)

  • 신은재;박진식
    • Journal of Environmental Science International
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    • v.6 no.4
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    • pp.391-397
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    • 1997
  • The study was carried out to demonstrate the superiority of used packing in view of energy saving and efficiency of mass transfer, comparing with conventional packing. The results are as follows : 1. Owing to low Pressure drop under high load. 25mm NSW-ring, pp. can cause energy saving 2. The unique magnitudes of used packing are as follows $C_G$=5.78, m=0.67, n=0.46 3. Used packing can make high efficiency including energy saving because of low pres sure drop per the number of transfer unit. To rate the characteristic of packing, It should be carried out that the measurement of pressure drop per packing height and per the number of transfer unfit. This study demonstrated the superiority of used packing by carring out above experiment and could be used as basic reference for design and predicting efficiency of packing tower which is tilled with same packing.

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Effect of Diameter and Length on the Absorption Performance in a Vertical Absorber Tube (수직형 흡수기 성능에 미치는 흡수기 전열관의 직경과 길이의 영향)

  • 서정훈;조금남
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.12
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    • pp.1214-1222
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    • 2001
  • The present study investigated the effect of diameter and length on the absorption performance of a vertical falling film type absorber using $LiBr-H_2$O solution of 60 wt%. The parameters were diameter of absorber (17.2, 23.4, 31.1 mm), length of absorber (771, 1150, 1528 mm), and film Reynolds numbers (50, 70, 90, 110, 130, 150). As the diameter of the absorber was increased, the absorption mass flux, Sherwood number, heat flux, and heat transfer coefficient were increased, in which Sherwood number and heat transfer coefficient were increased up to 13% and 30% respectively. As the length of the absorber was increased, the total absorption rate and heat transfer coefficient were increased by 37% and 35% respectively, while the absorption mass flux was decreased.

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On increasing the homogeneity of the properties of epitaxial layers grown from the gas phase, taking into account natural convection and changes in the rate of chemical interaction between materials

  • Pankratov, E.L.
    • Advances in materials Research
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    • v.9 no.2
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    • pp.155-170
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    • 2020
  • In this paper, using the recently introduced analytical approach for the analysis of mass and heat transfer during film growth in reactors for epitaxy from the gas phase, these processes are analyzed taking into account natural convection and the possibility of changing the rate of chemical interaction between reagents. As a result of the analysis, the conditions under which the homogeneity of the grown epitaxial layers increases with a change in the values of the parameters of the growth process are formulated.

Numerical Analysis on the Beat and Mass Transport in Horizontal MOCVD Reactor for the Growth of GaN Epitaxy (수평형 MOCVD에 의한 GaN 에피층 성장시 반응로내의 열 및 물질전달에 관한 수치해석 연구)

  • 신창용;윤정모;이철로;백병준
    • Journal of the Korean Vacuum Society
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    • v.10 no.3
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    • pp.341-349
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    • 2001
  • Numerical calculation has been performed to investigate the fluid flow, heat transfer and local mass fraction of chemical species in the MOCVD(metalorganic chemical vapor deposition) manufacturing process. The mixing of reactants (trimethylgallium with hydrogen gas and ammonia) was presented by the concentration of each reactant to predict the uniformity of film growth. Effects of inlet size, location, mass flow rate and susceptor/cold wall tilt angle on the concentration were reported. From the numerical calculation, the concentration of reactants could be qualitatively predicted by the Nusselt number(heat transfer) and the optimum mass flow rate, wall tilt angle and inlet condition were considered.

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Analysis of the Behavior of Tubular-Type Equipment for Nuclear Waste Treatment : Sensitivities of the Parameters Affecting Mass Transfer Yield (방사성폐기물의 화학처리공정에 사용되는 유동관식 장치의 해석 : 물질전달 수율에 미치는 매개변수들의 민감도)

  • Yoo, Jae-Hyung;Lee, Byung-Jik;Shim, Joon-Bo;Kim, Eung-Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.1
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    • pp.91-99
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    • 2007
  • It was intended in this study to investigate the effects of various parameters on the chemical reaction or mass transfer yield in a tubular-type nuclear waste treatment equipment. Since such equipments, as a tubular reactor, multistage solvent extractor, and adsorption column, accompany chemical reaction or mass transfer along the fluid-flowing direction, mathematical modeling for each equipment was carried out first. Then their behaviors of the chemical reaction or mass transfer were predicted through computer simulations. The inherent major parameters for each equipment were chosen and their sensitivities. affecting the reaction or mass transfer yield were analyzed. For the tubular reactor, the effects of axial diffusion coefficient and reaction rate constant on the reaction yield were investigated. As for the multistage solvent extractor, the backmixing of continuous phase and the distribution coefficient between fluid and solvent were considered as the major parameters affecting the extraction yield as well as concentration profiles throughout the axial direction of the extractor. For the adsorption column, the equilibrium constant between fluid and adsorbent surface, and the overall mass transfer coefficient between the two phases were taken as the major factors that affect the adsorption rate.

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