• Bulletin of the Korean Chemical Society
• /
• 제18권7호
• /
• pp.706-710
• /
• 1997

Isotope ratios of K, Ca, Cr and Fe are measured at cool plasma condition generated using high carrier flow rate and relatively low RF power of 900 W. Background molecular ions are suppressed to below 100 counts which give isobaric interference to the analytes. The background ions show different attenuation characteristics at increased carrier flow rate and hence for each element different carrier flow rate should be used to measure isotope ratios without isobaric interference. Isotope ratios are measured at both scan and peak-hopping modes and compared with certified or accepted ratios. The measured isotope ratios show some mass discrimination against low mass due to low ion energy induced from a copper shield to eliminate capacitive coupling of plasma with load coil.

• 설비공학논문집
• /
• 제21권6호
• /
• pp.367-372
• /
• 2009

The performance of a $CO_2$ heat pump water heater was measured with a variation of operating conditions such as refrigerant charge amount, outdoor temperature, compressor frequency, EEV opening, and water mass flow rate. The optimum refrigerant charge amount of the $CO_2$ system was 1800 g. At water mass flow rates of 75, 85, and 95 kg/h, the water heating temperatures were 74, 67, and $62^{\circ}C$ and COPs were 2.6, 2.8, and 3.0, respectively. Besides, the compressor frequency and water mass flow rate were adjusted to maintain the water heating temperature at $60^{\circ}C$ with the decrease of outdoor temperature. As the outdoor temperature decreased by $5^{\circ}C$, the compressor frequency increased beyond 60 Hz and the water mass flow rate decreased by 16.7%.

• 대한설비공학회:학술대회논문집
• /
• 대한설비공학회 2008년도 동계학술발표대회 논문집
• /
• pp.310-315
• /
• 2008

In this study, experimental study on the heating performance of a $CO_2$ heat pump water heater with a variation of operating conditions such as refrigerant charge amount, outdoor temperature, compressor frequency, EEV opening and water mass flow rate. Based on the test results, the optimum charge amount was 1800 g. At the water mass flow rates of 75, 85, 95 kg/hr, the water heating temperature was 62, 67, $74^{\circ}C$ and COP was 2.6, 2.8, 3.0, respectively. Besides, the water mass flow rate and compressor frequency were varied to maintain above the water heating temperature of $60^{\circ}C$ with the decrease of outdoor temperature. So, The compressor frequency increased beyond 65 Hz and the water mass flow rate was 45 kg/hr at the outdoor temperature of $-13^{\circ}C$, 65 kg/hr at $-8^{\circ}C$, 75 kg/hr at $-3^{\circ}C$ and 85 kg/hr at 2, $7^{\circ}C$. As the outdoor temperature decreased, the heating COP decreased by 2.5-39.8%.

• 설비공학논문집
• /
• 제18권11호
• /
• pp.881-887
• /
• 2006

The objective of this study are to analyze the flow characteristics of R22 flowing through EEVs and to develop an empirical correlation to predict the refrigerant flow rate. The mass flow rates of EEVs with different geometries were measured at various condensing temperatures, subcoolings, and EEV openings. Based on the experimental data, an empirical correlation for mass flow predictions in EEVs was developed by modifying the orifice equation. The correlation showed good agreement with the measured data for R22 with average and standard deviations of 1.4% and 6.1%, respectively. Approximately 90% of the measured data were within ${\pm}10%$ of the predictions.

• 한국연소학회지
• /
• 제19권4호
• /
• pp.49-55
• /
• 2014

Design criterion for the size of micro Pt-catalytic combustor is investigated in terms of heat release rate. One-dimensional plug flow model is applied to determine the surface reaction constants using the experimental data at stoichiometric butane-air mixture. With these reaction constants, the mass fraction of butane and heat release rate predicted by the plug flow model are in good agreement with the experimental data at the combustor exit. The relationship between the size of micro catalytic combustor and mixture flowrate is introduced in the form of product of two terms-the effect of fuel conversion efficiency, and the effect of chemical reaction rate and mass transfer rate.

• 한국산학기술학회논문지
• /
• 제19권2호
• /
• pp.15-20
• /
• 2018

본 논문은 자동차 열전발전용 열교환기에서 배기가스의 유량과 온도 변화에 따른 발열량 특성을 수치적으로 연구하였다. 자동차 열전발전용 열교환기는 내부에 핀을 설치하여 자동차 배기가스에서 나오는 열에너지를 열전소자로 최대 값을 전달할 수 있도록 하였으며, 상용 프로그램인 CAD를 이용하여 설계하였다. 그리고 배기가스의 유량과 온도 변화에 따른 열교환기 발열량 특성을 분석하기 위하여 상용 프로그램인 ANSYS CFX v17.0을 이용하여 배기가스 유량은 0.01, 0.02, 0.03 kg/s로 변화시키고, 배기가스 온도는 400, 450, 500, 550, $600^{\circ}C$로 변화시켜 수치해석 하였다. 결론적으로 열교환기의 입구 측과 출구 측 배기가스 압력 차는 배기가스의 유량에 따라 결정된다. 배기가스 유량이 증가하면 열교환기 입구 측과 출구 측 압력차는 증가하지만, 열교환기 입구 측과 출구 측 배기가스 압력차는 배기가스 온도에 따라 변하지 않는다. 따라서 열교환기 표면 온도를 최대 값으로 얻기 위해서는 배기가스 유량은 낮추고, 배기가스 온도는 높여야 한다는 결론을 도출하였다.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2001년도 춘계학술대회논문집E
• /
• pp.738-741
• /
• 2001

The purpose of the present study is to measure the viscosity of liquid in the capillary tube viscometer using the unsteady flow concept. The capillary tube viscometer is consisted of a small cylindrical reservoir, capillary tubes, and the mass flow rate measuring system interfaced with computer. Two capillary tubes with 1.152 and 3.002 mm I.D. are used to determine the diameter effects on the viscosity measurements. The instantaneous shear rate and gravitational driving force in the capillary tube are determined by measuring the mass flow rate through the capillary tube instantaneously. The measured viscosities of water and aqueous Separan solution are in good agreement with the reported experimental data.

• 공업화학
• /
• 제9권7호
• /
• pp.1036-1042
• /
• 1998

소수성실관막을 이용하여 수용액 중의 Cr(VI)을 TDA로 추출하고, 이를 NaOH 수용액으로 회수하였다. 역추출공정에서의 물질전달속도는 추출공정에 비해 작았으며, 이러한 결과는 소수성막의 내부를 유기상이 흐르게 되면 추출과정에서는 무시할 수 있었던 막저항이 작용하기 때문이라 판단된다. 막수량을 달리한 4개의 막모듈(60, 100, 150, 300가닥)을 제작하였으며, 각 모듈에 대해 수용상 및 유기상의 유량이 물질전달속도에 미치는 영향에 대해서도 검토하였다. 이 실험으로부터 소수성막을 이용한 추출공정에서는, 막내부를 흐르는 수용상의 유량이 물질전달속도에 큰 영향을 주었으나 유기상 유량의 영향은 미약하다는 것을 알 수 있었다. 반면, 역추출공정에서의 물질전달속도는 수용상(회수액)유량에도 유기상(Cr-TDA 착화합물)의 유량에도 영향을 받지 않음을 알 수 있었다.

• 한국전산구조공학회논문집
• /
• 제23권6호
• /
• pp.651-657
• /
• 2010

Solute transport through a groove is affected by its vortices. Our laboratory and numerical experiments of dye transport through a single axisymmetric groove reveal evidence of enhanced spreading and mixing by the vortex, i.e., a new kind of dispersion called here the vortex dispersion. The uptake and release of contaminants by vortices in porous media is affected by the flow Reynolds number. The larger the flow Reynolds number, the larger is the vortex dispersion, and the larger is the mass-transfer rate between the mobile zone and the vortex. The long known dependence of the mass-transfer rate between the mobile and "immobile" zones in porous media on flow velocity can be explained by the presence of vortices in the "immobile" zone and their uptake and release of contaminants.

• 한국식품영양과학회지
• /
• 제20권5호
• /
• pp.494-502
• /
• 1991

Diazotized chitin(CHITN) as supports of immobilized enzyme, which was obtained by alkaline hydrolysed chitin with NaN3 and HCI was employed to produce CHITN-Gase with glutaraldehyde as bifunctional reagent. Activities of CHITN-Gase were determined with reaction of p-nitro-pheol-$\beta$-D-glucopyranoside(PNG) in plug flow reactor as a reference of CHITA-Gase. Their optimum temperature, pH, Km and Vmax, mass transfer coefficient (h), effctiveness factor(η)were plotted with variation of flow rate and H/D. Mass transfer coefficient(h) of those enzymes increased because of their flux, as flow rates were increased and controlled by reaction rate. Effectiveness factor(η) of both enzymes were nearly 1.0.