• ETRI Journal
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• 제11권4호
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• pp.75-83
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• 1989

The diffusion mechanism of Si in GaAs was investigated using different diffusion sources based on the Si-Ga-As ternary phase equilibria. The Si profiles are measured with secondary ion mass spectrometry and differ significantly for sources taken from the different phase fields in the ternary phase diagram. Neutral As vacancy diffusion is proposed for acceptor Si diffusion anneals using a Ga - Si - GaAs source. Donor Si diffusion using As - rich sources and a Si -GaAs tie line source shows concentration dependent diffusion behavior. Concentration dependent diffusion coefficients of donor Si for As - rich source diffusion were found to be related to net ionized donor concentration and showed three regimes of different behavior: saturation regime, intermediate regime,and intrinsic regime. Ga vacancies are proposed to be responsible for donor Si diffusionin GaAs: $Si_Ga^+V_Ga^-$ (donor Si -acceptor Gavacancy) complex for the extrinsic regime and neutral $V_G$a, for the intrinsic regime.The Si - GaAs tie line source resulted in two branch profiles, intermediate between the As - rich and the Ga - rich source diffusion cases.

• 대한기계학회논문집B
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• 제37권11호
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• pp.977-984
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• 2013

흡착식 제습기에 적용되는 제습 로터는 높은 제습 성능을 달성키 위해, 흡수율이 높은 재질로 구성된 수많은 미세 채널을 포함하고 있다. 본 연구에서는 습공기 흐름에 의해 나타나는 제습 로터 내부의 반복적인 흡착/탈착 과정에 대한 수치해석 결과를 소개한다. 수치해석의 정확도와 효율성을 고려하여 흡습층 내부에서는 표면 확산(surface diffusion)만을 고려하여 해석을 수행하였다. 해석결과는 이전의 연구와 비교하였고, 온도에 대한 비교 오차는 약 2%이하인 점을 감안하여 해석결과가 매우 잘 일치하는 것을 확인하였다. 단일 채널 내부에서 유동층 (flow layer)과 흡습층 (desiccant layer) 간 열/물질전달 연계 해석을 통하여 채널 내부의 수증기 분율, 흡수된 물 분율과 온도 등에 대한 시간 및 공간적 변화를 나타내었다.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2791-2796
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• 2010

In the present study, we constructed a membrane inlet assembly for selective permeation of volatile airborne organic compounds for subsequent analysis by time-of-flight mass spectrometry. The time-dependent diffusion of analytes through a $75\;{\mu}m$ thick polydimethylsiloxane membrane was measured by monitoring the ion signal after a step change in the sample concentration. The results fit well to a non-steady-state permeation equation. The diffusion coefficient, response time, and sensitivity were determined experimentally for a range of polar (halogenated) and nonpolar (aromatic) compounds. We found that the response times for several volatile organic compounds were greatly influenced by the alkyl chain length as well as the size of the substituted halogen atoms. The detection limits for benzene, ethylbenzene, and 2-propanol were 0.2 ppm, 0.1 ppm, and 3.0 ppm by volume, respectively, with a linear dynamic range greater than three orders of magnitude. These results indicate that the membrane inlet/time-of-flight mass spectrometry technique will be useful for a wide range of applications, particularly for in situ environmental monitoring.

• Journal of applied mathematics & informatics
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• 제29권1_2호
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• pp.369-380
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• 2011

This paper studies a boundary value problem for a linear coupled Luikov's system of heat and mass diffusion in one-dimensional case. Using an a priori estimate, we prove the uniqueness of the solution. Also, some traveling wave solutions and explicit solutions are obtained by using the transformation ${\xi}$ = x - ct and separation method respectively.

• 한국전기전자재료학회논문지
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• 제13권11호
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• pp.954-958
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• 2000

The characterization of zinc diffusion processes applied for high-speed avalanche photodiodes has been examined. The different diffusion process conditions for InP test structures were explored. The zinc diffusion profiles, such as the diffusion depth and the zinc dopant concentration, were examined using secondary ion mass spectrometry with varying the process variables and material parameters. It is observed that the diffusion profiles are severly impacted on the process parameters, such as the amount of Zn$_3$P$_2$ source and the diffusion time, as well as material parameters, such as doping concentration of diffusion layer. These results can be utilized for the high-speed avalanche photodiode fabrication.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.731-734
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• 2000

The characterization of Zinc diffusion processes applied fur high-speed avalanche photodiodes has been examined. The different diffusion process conditions for InP test structures were explored. The Zinc diffusion profiles, such as the diffusion depth and the Zinc dopant concentration, were examined using secondary ion mass spectrometry with varying the process variables and material parameters. It is observed that the diffusion profiles are severely impacted on the process parameters, such as the amount of Zn$_3$P$_2$source and the diffusion time, as well as material parameters, such as doping concentration of diffusion layer. These results can be utilized for the high-speed avalanche photodiode fabrication.

• Steel and Composite Structures
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• 제34권2호
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• pp.309-319
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• 2020

The objective is to study the deformation in a homogeneous isotropic modified couple stress thermoelastic medium with mass diffusion and with two temperatures due to a thermal source and mechanical force. Laplace and Fourier transform techniques are applied to obtain the solutions of the governing equations. The displacements, stress components, conductive temperature, mass concentration and couple stress are obtained in the transformed domain. Numerical inversion technique has been used to obtain the solutions in the physical domain. Isothermal boundary and insulated boundaryconditions are used to investigate the problem. Some special cases of interest are also deduced.

• Korea-Australia Rheology Journal
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• 제18권2호
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• pp.51-65
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• 2006

Of concern in the present theoretical investigation is the study of blood flow and convection-dominated diffusion processes in a model bifurcated artery under stenotic conditions. The geometry of the bifurcated arterial segment having constrictions in both the parent and its daughter arterial lumen frequently appearing in the diseased arteries causing malfunction of the cardiovascular system, is constructed mathematically with the introduction of suitable curvatures at the lateral junction and the flow divider. The streaming blood contained in the bifurcated artery is treated to be Newtonian. The flow dynamical analysis applies the two-dimensional unsteady incompressible nonlinear Wavier-Stokes equations for Newtonian fluid while the mass transport phenomenon is governed by the convection diffusion equation. The motion of the arterial wall and its effect on local fluid mechanics is, however, not ruled out from the present model. The main objective of this study is to demonstrate the effects of constricted flow characteristics and the wall motion on the wall shear stress, the concentration profile and on the mass transfer. The ultimate numerical solutions of the coupled flow and diffusion processes following a radial coordinate transformation are based on an appropriate finite difference technique which attain appreciable stability in both the flow phenomena and the convection-dominated diffusion processes.

• 방사성폐기물학회지
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• 제3권2호
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• pp.85-93
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• 2005

Isotopes of alkali and alkaline earth metals (AM and AEM) are the main contributors to the heat load and the radiotoxicity of spent fuel (SF) . These components are separated from the SF and dissolved in a molten LiCl in an electrolytic reduction process. A mass transfer model is developed to describe the diffusion behavior of Cs, Sr, and Ba in the SF into the molten salt. The model is an analytical solution of Fick's second law of diffusion for a cylinder which is the shape of a cathode in the electrolytic reduction process. And the model is also applied to depict the concentration profile of the oxygen ion which is produced by the electrolysis of Li$_{2}$O. The regressed diffusion coefficients of the model correlating the experimentally measured data are evaluated to be greater in the order of Ba, Cs, and Sr for the metal ions and the diffusion of the oxygen ion is slower than the metal ions which implies that different mechanisms govern the diffusion of the metal ions and the oxygen ions in a molten LiCl.

• 대한기계학회논문집B
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• 제21권9호
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• pp.1126-1138
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• 1997

An axisymmetric laminar jet diffusion flame has been numerically modelled. The present study employs the refined physical submodels to account for the detailed chemical kinetics and the variable transport properties. It is found that preferential diffusion resulting from variable transport properties significantly influences the hydrogen diffusion flame structure in terms of the spatial distribution for temperature, species concentration, thermal and mass diffusivity, Lewis number, and NO concentration. The preferential diffusion effects on the diffusion flame in the high-pressure environment are also discussed in detail.