• Title/Summary/Keyword: Mass conversion rate

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Effects of ortho-para hydrogen conversion on hydrogen liquefaction performance (Ortho-para 수소변환이 수소액화성능에 미치는 영향)

  • 최항집;강병하;최영돈
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.2
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    • pp.131-139
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    • 2000
  • A direct hydrogen liquefaction equipment has been developed and tested, which consists of a GM refrigerator, a liquefaction vessel, a radiation shield, a cryostat, and an ortho-para converter with catalyst. The effect of ortho-para hydrogen conversion on the performance of hydrogen liquefaction has been investigated. The time needed for the hydrogen liquefaction process with hydrogen pressure charge of 4 atm was delayed to around 75 minutes, and the liquefied mass flow rate of the hydrogen was about 0.0150∼ 0.0205 g/s when the hydrogen was liquefied with the direct hydrogen liquefaction system considering ortho-para conversion. With ortho-para conversion, the liquefied mass flow rate decreased up to 20%. Considering ortho-para conversion, there were up to 30% increase in the work input per unit liquefied mass flow rate. When the ortho-para conversion was considered, FOM decreased to be about 0.031∼0.045.

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Dynamic and Static Characteristics of Sensor Tube for Mass Flow Controller (질량유량제어기용 센서튜브의 정특성과 동특성에 관한 연구)

  • 김영수;이상경
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.3
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    • pp.531-537
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    • 2004
  • In this paper, the static and dynamic characteristics in the sensor tube of a mass flow controller(MFC) were studied by experiments. In the sensor tube of MFC. the difference of temperature between inlet and outlet was necessary for calculating the mass flow rate. Therefore, the relations among flow rate, heat generated by heating wire. and sensor location were investigated to find optimized condition. Finally, the relation between sensor voltage through analog digital conversion(ADC) and flow rate in the sensor tube can be represented. Based on this study, static and dynamic characteristics of sensor tube can be used for design of mass flow controller.

Design and performance evaluation of ortho-para H2 conversion equipment (Ortho-para 수소변화장치의 설계 및 성능평가)

  • Baik, J.H.;Kang, B.H.
    • Transactions of the Korean hydrogen and new energy society
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    • v.9 no.3
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    • pp.93-100
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    • 1998
  • The ortho-para $H_2$ catalytic conversion equipment has been developed to reduce the evaporation loss from stored liquid hydrogen. The ortho-para $H_2$ conversion heat is evaluated at liquid nitrogen temperature. This problem is of particular interest in the design of the ortho-para $H_2$ converter in a hydrogen liquefaction system. The ortho-para $H_2$ conversion equipment consists of a catalytic converter, a precooler, and a liquid nitrogen bath. 30-90 cc of $Fe(OH)_3$ are employed as a catalyst in the present converter. The conversion heat and conversion effectiveness are evaluated when mass flow rate of hydrogen is in the range of 0.05-l.6 g/min. It is found that the ortho-para conversion heat is increased while conversion effectiveness is decreased as the mass flow rate of hydrogen is increased. Both the ortho-para conversion heat and conversion effectiveness are increased with an increase in the amount of the catalyst.

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A Conversion Rate Prediction Study of Exhaust Gas by Catalyst Simulation in Heavy Duty Natural Gas Vehicle (대형천연가스차량에서 촉매시뮬레이션에 의한 배출가스의 변환율 예측 연구)

  • 한영출;오용석;강호인
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.3
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    • pp.257-264
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    • 2000
  • An aftertreatment device which reduce exhaust gas of natural gas vehicle(NGV), NGV catalyst has important meaning as to reduce the exhaust emission. In this study, the characteristics of NGV catalyst were investigated and the effect parameters of NGV catalyst were analyzed and were predicted by changing the various parameters such as temperature, and gas concentration. The conversion efficiency of NGV catalyst converter was also predicted by Pd-loading, mass flow rate and gas composition.

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Effect of Secondary Air Injection on Emission from Sludge Incineration in a Batch-type Internally Cycloned Circulating Fluidized Bed Combustor (배치형 내부 사이클론식 순환유동층 연소로내 2차 공기 주입에 의한 슬러지 소각 유해 배가스 저감효과)

  • Jang, Seuk-Don;Shin, Dong-Hoon;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.7 no.3
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    • pp.16-22
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    • 2002
  • Combustion performance of an internally cycloned circulating fluidized bed for paper sludge was discussed through a series of batch type experiments. Operation parameters such as water content, feeding mass of sludge and secondary air injection rate were varied to find out the effect on the combustion performance, which was examined with carbon conversion rate and pollutant emission such as CO and NOx. A conventional solid fuel reaction was observed in the experiments of varying water content and feeding mass of the sludge, which is characterized with kinetic limited reaction zone, diffusion limited reaction zone and transition zone. Secondary air injection with swirl enhances the mixing of the gas phase as well as the solid phase, and improves combustion efficiency accompanied with higher carbon conversion rate and lower pollutant emission rate.

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Transport Phenomena in a Steam Methanol Microreformer for Fuel Cell (마이크로 연료전지용 수소개질기내 전달현상 특성 연구)

  • Suh, Jeong-Se
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.3-8
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    • 2008
  • Effect of external heating rate on the conversion efficiency for the steam reforming of methanol is investigated numerically considering both heat and mass transfer of the species in a packed bed microreactor. In a results from the numerical simulation, the conversion efficiency of methanol has been obtained for the external heating rate. The axial variation of mole fraction of methanol has been additionally presented for several cases of external heating rates. The results show that for the constant inlet temperature condition the conversion efficiency of methanol increases with external heating rate over the range of operating conditions.

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Reduction Characteristics of Mass Produced Particle for Chemical-Looping Combustor with Different Fuels (매체순환식 가스연소기용 대량생산입자의 연료별 환원반응특성)

  • Ryu, Ho-Jung;Kim, Kyung-Su;Lee, Seung-Yong;Park, Yeong-Seong;Park, Moon-Hee
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.4
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    • pp.348-358
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    • 2008
  • Reduction reactivity and carbon deposition characteristics of mass produced oxygen carrier particle(OCN-650) have been investigated by using hydrogen, methane, syngas, and natural gas as fuels. For all fuels, the maximum conversion and oxygen transfer capacity increased as the temperature increase. The reduction rate and the oxygen transfer rate increased as the temperature increase for methane. However, those values showed maximum at 900$^{\circ}C$ for hydrogen, syngas, and natural gas. To explain consistently the change of maximum conversion, reduction rate, oxygen transfer capacity, oxygen transfer rate and degree of carbon deposition for different fuels, new parameters such as reactive carbon contents and require oxygen per input gas were adopted.

A Study on the Modeling of Pt-Catalyzed Reaction and the Characteristics of Mass Transfer in a Micro-Scale Combustor (마이크로 스케일 연소기의 백금 촉매 반응 모델링과 물질 전달 특성에 대한 연구)

  • Lee, Gwang-Goo;Suzuki, Yuji
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.11
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    • pp.870-877
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    • 2008
  • Numerical analysis is applied to model Pt-catalyzed reaction in a micro-scale combustor fueled by butane. The reaction constants of catalytic oxidation are determined from plug flow model with the experimental data. Orders of magnitude between the chemical reaction rate and the mass transfer rate are carefully compared to reveal which mechanism plays a dominant role in the total fuel conversion rate. For various conditions of fuel flow rate and surface temperature, the profiles of Sherwood number are investigated to study the characteristics of the mass transport phenomena in the micro-tube combustor.

Mass Production of Pullulan with Optimized Concentrations of Carbon and Nitrogen Sources by Aureobasidium pullulans HP-2001 in a 100-L Bioreactor with the Inner Pressure

  • Seo, Hyung-Pil;Chung, Chung-Han;Kim, Sung-Koo;Richard A. Gross;David L. Kaplan;Lee, Jin-Woo
    • Journal of Microbiology and Biotechnology
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    • v.14 no.2
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    • pp.237-242
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    • 2004
  • Cell growth and the production of pullulan by Aureobasidium pullulan HP-2001, the UV-induced mutant of A pullulans ATCC 42023, increased with increased concentration of glucose up to 15.0% (w/v). Maximal production of pullulan in the flask scale was 27.65 g/l, when concentrations of glucose and yeast extract were 15.0 and 0.25% (w/v), respectively. Maximal conversion rate of pullulan from glucose as the carbon source was 0.37, when those of glucose and yeast extract were 5.0 and 0.15% (w/v), respectively. On the basis of total amount of pullulan, the conversion rate of pullulan from glucose, and utilization rate of glucose to cell mass and pullulan by A. pullulans HP-2001, the optimal concentrations of glucose and yeast extract for the mass production of pullulan were determined to be 10.0 and 0.25% (w/v), respectively, at which concentrations the production of pullulan and its conversion rate were 27.14 g/l and 0.27, respectively. Maximal production of pullulan with optimized concentrations of carbon and nitrogen sources by A. pullulans HP-200l in a 7-1 bioreactor was 32.12 g/l for 72 h culture, and that in a 100-1 bioreactor with the inner pressure of $0.4 kgf/cm^2$ was 36.87 g/l. Increased inner pressure of a 100-1 bioreactor resulted in a higher concentration of dissolved oxygen in the medium, which might enhance the production of pullulan by A. pullulans HP-2001.

Study on Methanol Conversion Efficiency and Mass Transfer of Steam-Methanol Reforming on Flow Rate Variation in Curved Channel (곡유로 채널을 가지는 수증기-메탄올 개질기에서 유량 변화에 따른 메탄올 전환율 및 물질 전달에 관한 연구)

  • Jang, Hyun;Park, In Sung;Suh, Jeong Se
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.3
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    • pp.261-269
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    • 2015
  • In this study, numerical analysis of curved channel steam-methanol reformer was conducted using the computational fluid dynamics (CFD) commercial code STAR-CCM. A pre-numerical analysis of reference model with a cylindrical channel reactor was performed to validate the combustion model of the CFD commercial code. The result of advance validation was in agreement with reference model over 95%. After completing the validation, a curved channel reactor was designed to determine the effects of shape and length of flow path on methanol conversion efficiency and generation of hydrogen. Numerical analysis of the curved-channel reformer was conducted under various flow rate ($10/15/20{\mu}l/min$). As a result, the characteristics of flow and mass transfer were confirmed in the cylindrical channel and curved channel reactor, and useful information about methanol conversion efficiency and hydrogen generation was obtained for various flow rate.