• Journal of Powder Materials
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• v.29 no.5
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• pp.357-362
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• 2022

The low-temperature sinterability of TiO₂-CuO systems was investigated using a solid solution of SnO₂. Sample powders were prepared through conventional ball milling of mixed raw powders. With the SnO₂ content, the compositions of the samples were Ti_1-xSn_xO₂-CuO(2 wt.%) in the range of x ≤ 0.08. Compared with the samples without SnO₂ addition, the densification was enhanced when the samples were sintered at 900℃. The dominant mass transport mechanism seemed to be grain-boundary diffusion during heat treatment at 900℃, where active grain-boundary diffusion was responsible for the improved densification. The rapid grain growth featured by activated sintering was also obstructed with the addition of SnO₂. This suggested that both CuO as an activator and SnO₂ dopant synergistically reduced the sintering temperature of TiO₂.

• Journal of Powder Materials
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• v.31 no.2
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• pp.146-151
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• 2024

Pure SnO₂ has proven very difficult to densify. This poor densification can be useful for the fabrication of SnO₂ with a porous microstructure, which is used in electronic devices such as gas sensors. Most electronic devices based on SnO₂ have a porous microstructure, with a porosity of > 40%. In pure SnO₂, a high sintering temperature of approximately 1300℃ is required to obtain > 40% porosity. In an attempt to reduce the required sintering temperature, the present study investigated the low-temperature sinterability of a current system. With the addition of TiO₂, the compositions of the samples were Sn_1-xTi_xO₂-CoO(0.3wt%)-CuO(2wt%) in the range of x ≤ 0.04. Compared to the samples without added TiO₂, densification was shown to be improved when the samples were sintered at 950℃. The dominant mass transport mechanism appears to be grain-boundary diffusion during heat treatment at 950℃.

• ALGAE
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• v.27 no.4
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• pp.295-301
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• 2012

Carbon concentrating mechanisms play a vital role in photosynthesis in microalgae and cyanobacteria especially in the proper functioning of Rubisco and assimilation of carbon via the Calvin cycle. This study evaluates the role of carbon dioxide on carbon concentrating mechanism (CCM) in a cynaobacteria, Spirulina platensis and a microalga, Chlorella sp. 786. The study organisms were grown in both atmospheric (control sample, 0.035%) and high (exposed sample, 10%) $CO_2$ concentrations. Second dimension (2D) electrophoresis revealed a huge difference in the protein profiles of both organisms suggesting the induction of CCM related proteins in the sample maintained at atmospheric $CO_2$ concentration and the repression of CCM related proteins in the sample maintained at 10% $CO_2$. Liquid chromatography-mass spectroscopy analysis revealed the presence of two important $C_i$ transporter proteins in the control sample of S. platensis, namely ferredoxin-$NADP^+$ reductase and ATP binding cassette (ABC) transport system protein. These proteins were only expressed in the control sample and were downregulated or not expressed at all in the exposed sample. Consequently, this study conclusively proves that CCMs are only inducted at low $CO_2$ concentrations and are not functional at high $CO_2$ concentration.

• Corrosion Science and Technology
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• v.3 no.5
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• pp.198-208
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• 2004

Although there has been no general agreement on the mechanism of primary water stress corrosion cracking (PWSCC) as one of major degradation modes of Ni-base alloys in pressurized water reactors (PWR's), common postulation derived from previous studies is that the damage to the alloy substrate can be related to mass transport characteristics and/or repair properties of overlaid oxide film. Recently, it was shown that the oxide film structure and PWSCC initiation time as well as crack growth rate were systematically varied as a function of dissolved hydrogen concentration in high temperature water, supporting the postulation. In order to understand how the oxide film composition can vary with water chemistry, this study was conducted to characterize oxide films on Alloy 600 by an in-situ Raman spectroscopy. Based on both experimental and thermodynamic prediction results, Ni/NiO thermodynamic equilibrium condition was defined as a function of electrochemical potential and temperature. The results agree well with Attanasio et al.'s data by contact electrical resistance measurements. The anomalously high PWSCC growth rate consistently observed in the vicinity of Ni/NiO equilibrium is then attributed to weak thermodynamic stability of NiO. Redox-induced phase transition between Ni metal and NiO may undermine the integrity of NiO and enhance presumably the percolation of oxidizing environment through the oxide film, especially along grain boundaries. The redox-induced grain boundary oxide degradation mechanism has been postulated and will be tested by using the in-situ Raman facility.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.7 no.1
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• pp.91-107
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• 1995

In this paper, previously proposed mechanisms of generation and maintenance of rip currents are grouped into three broad categories; (1) prismatic topography models, (2) non-prismatic topography models and (3) structural controls by natural and/or constructed features, such as headlands, piers. groins, jetties. etc. The prismatic models can explain the occurrence of a rip current on a planar beach, while non-prismatic model needs undulatory topography inside the surf zone to generate and maintain a rip current. Yet more detailed and thorough studies need to be conducted to include all relevant variables and to clarify the mechanism(s) governing rip current. Next a simple model is presented to predict mean longshore currents behind a longshore bar (or submerged breakwaters) by considering mass transport over the bar and the bar morphology. This hydrodynamic model could be extended to include the sedimentary feedback mechanism.

• Resources Recycling
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• v.31 no.5
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• pp.59-66
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• 2022

To investigate the rate-determining step of nickel, cobalt and copper electrowinning, experiments were conducted by varying the electrolyte temperature and agitation speed using a rotating disc electrode. Analyzing the rate-determining step by calculating the activation energy in the electrowinning process, it was found that nickel electrowinning is controlled by a mixed mechanism (partly by chemical reaction and partly by mass transport), cobalt is controlled by chemical reaction, and copper is controlled by mass transfer. Electrowinning of nickel, cobalt and copper was performed by varying the electrolyte temperature and agitation speed, and the comparison of the current efficiencies was used the determine the rate-determining step.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.1
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• pp.355-365
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• 1991

New definition for the interaction of flames is introduced and interacting turbulent diffusion flames issuing from two rectangular nozzles are investigated on the basis of the definition. Theoretical study through numerical model is carried out and experiment for validation is conducted. The characteristics of interaction due to the variation of major parameters such as nozzle spacing, Reynolds number and nozzle aspect ratio are studied. Results show that strong interaction occurs for small nozzle spacing, small Reynolds number and large aspect ratio. In order of their magnitude, the intensity of interactions on the individual transport mechanism is momentum, heat and mass. It is also found that interaction makes flames longer, tilted and finally merged. Increase of velocities and temperature, decrease of oxygen concentration and depression of turbulence are occurred in the region between flames.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2004.06a
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• pp.268-277
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• 2004

process (ACP), electrochemical properties of high heat-generating alkali and alkali earth oxides in molten salt were measured and the behavior of those elements were analyzed. The reduction potentials of Cs, Sr, and Ba in a molten LiCl-$Li_2O$ system were more cathodic than that of Li and closely located one another. Thus, it is expected that the alkali and alkali earth would not hinder the reaction mechanism which is via lithium reduction. Alkali and alkali earth metals are likely to recycle into molten salt when the process is operated beyond metal reduction potentials and the effect of electric current on the mass transport is also determined by measuring the metal concentrations in the molten salt phase at different current conditions.

• The KIPS Transactions:PartC
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• v.16C no.4
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• pp.511-520
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• 2009

Grid technology enables high performance computation and mass data processing by connecting geographically distributed computing resources to high-speed network. To carry on grid tasks requiring guaranteed quality of service, we need to build converged infrastructure which controls and manages network resources as well as computing resources. In this paper, we defined grid network service interface and information model to support grid network path, resource creation and reservation. In addition to resource creation and reservation messages of the existing GLIF, grid network path and notification messages were defined in the grid network service interface. We also defined related statuses and messages for two-phase resource reservation mechanism. We designed and implemented network resource management system based on the grid network information model and service interface. We experimented in resource reservation, allocation and release of network resources in grid environment with GMPLS control and transport network.

• 한국해양학회지
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• v.25 no.4
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• pp.182-188
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• 1990

The sedimentation processes and heavy metal distributions at the Nakdong estuary were investigated during October 1987 and September 1988. The depositional sedimentary environment of the studied area was estuarine environments and was divided into three provinces depending on its textural parameters such as barrier, tidal falt, and water passes. The relationship between the textural parameters showed that the barrier was under strong wave action, that the tidal flat was under relatively weak wind-driven currents, and that the water passes were under strong and continuous tidal currents. Each environments was resulted from different transport mechanism. the sand barrier sediments were transported by all three populations including suspension, saltation, and bed load, and water pass-deposited sediments were by the bad load with some suspension population. In water mass over the studied area, the concentrations of heavy metals including Cu, Cd, $Cr^{+6}$, Pb and Zn were recorded to be 27.8, 6.7, 20.4, 16.3, and 37.3 ppb in their highest concentrations, respectively. and those in sediments were 20.0, 1.65, 25.4, 15.4, and 132.0 ppm, respectively. The total up take factored of Cu, Cd, $Cr^{+6}$, Pb, and Zn by V. Muller (corbicula fluminea) were 1600, 310, 310, 490 and 7900, respectively.