• Title/Summary/Keyword: Mass Transport

Search Result 803, Processing Time 0.027 seconds

Internal Mixing of Pollutants for Submicron Particles Observed during Springtime in Japan

  • Matsumoto, Jun;Narukawa, Masahiro;Takahashi, Kenshi;Matsumi, Yutaka;Yabushita, Akihiro;Shimizu, Atsushi;Matsui, Ichiro;Sugimoto, Nobuo
    • Asian Journal of Atmospheric Environment
    • /
    • v.3 no.1
    • /
    • pp.27-41
    • /
    • 2009
  • Internally mixed states of submicron particles during transport from the Asian continent to the Pacific Ocean were analyzed using a single-particle time-offlight mass spectrometer. The observation was conducted at Tsukuba in Japan in the spring of 2005 in order to investigate springtime transport of particles from the continent. The sum of ion intensities of sulfate (${HSO_4}^-$) detected in particles originating from the continental air masses counted for 75% of that in all particles during the observation. By analyzing correlations among compounds, origins and internally mixed states of compounds were estimated. It was found that nitrate was mixed with sulfate-rich particles as the air mass approached Japan. It was confirmed that Asian mineral dust particles played significant roles for transport of continental sulfate to Japan. As a result of analysis on internal mixing of chlorine and nitrate, it was implied that the chlorine loss in fine sea salt particles had already proceeded at Tsukuba. It was characteristic that fluoride ions were significantly detected, coal combustion in the Asian Continent can be an important source of fluorides detected in Japan through the westward transportation of fine particles including fluorides.

Physical, Chemical and Optical Properties of an Asian Dust and Haze Episodes Observed at Seoul in 2010 (2010년 서울에서 관측한 황사와 연무사례의 물리, 화학, 광학적 특성비교)

  • Song, Seungjoo;Kim, Jeong Eun;Lim, Eunha;Cha, Joo-Wan;Kim, Jhoon
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.31 no.2
    • /
    • pp.131-142
    • /
    • 2015
  • This study investigated physicochemical and optical characteristics for three episodes of Asian dust, stagnant haze and long-range transport haze and for one clean day. $PM_{10}$ mass concentration during Asian dust and two haze days was increased by 2~9 times compared to that of clean episode. During Asian dust episode, coarse particle concentration was increased and the mass concentration of calcium in a coarse mode ($1.8{\sim}10{\mu}m$) was $5.4{\mu}g/m^3$ which was 7 times higher than that of clean episode. The calcium was presented as a form of $CaCO_3$ in a coarse mode. During the two haze episodes, fine particle (< $1.8{\mu}m$) concentration was increased and secondary inorganic pollutants such as sulfate, ammonium and nitrate composed of 90% of the total ions. $(NH_4)_2SO_4$ and $NH_4NO_3$ were dominant in a fine mode for stagnant haze episode. But they were the most dominant form in both fine mode and coarse mode for long-range transport haze episode. According to the optical properties for each episode (Asian dust, stagnant haze and long-range transport haze) were classified as dust, black carbon and mixture, respectively.

Numerical Investigation of Mixing Characteristics in a Cavity Flow by Using Hybrid Lattice Boltzmann Method (혼성 격자볼츠만 방법을 이용한 공동 형상 내부에서의 혼합 특성에 관한 수치적 연구)

  • Shin, Myung Seob;Jeon, Seok Yun;Yoon, Joon Yong
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.37 no.7
    • /
    • pp.683-693
    • /
    • 2013
  • In this study, the mixing characteristics in lid-driven cavity flows were studied numerically by using a hybrid lattice Boltzmann method (HLBM). First, we compared the numerical results from single-relaxation-time (LB-SRT) and multi-relaxation-time (LB-MRT) models to examine their reliability. In most of the cavity flow, the results from both the LB-SRT and the LB-MRT models were in good agreement with those using a Navier-Stokes solver for Re=100-5000. However, the LB-MRT model was superior to the LB-SRT model for the simulation of higher Reynolds number flows having a geometrical singularity with much lesser spatial oscillations. For this reason, the LB-MRT model was selected to study the mass transport in lid-driven cavity flows, and it was demonstrated that mass transport in the fluid was activated by a recirculation zone in the cavity, which is connected from the top to the bottom surfaces through two boundary layers. Various mixing characteristics such as the concentration profiles, mean Sherwood (Sh) numbers, and velocity were computed. Finally, the detailed transport mechanism and solutions for the concentration profile in the cavity were presented.

Case Studies of Mass Concentration Variation in the Central-Southern Korean Peninsula Caused by Synoptic Scale Transport of Dust Storms

  • Kim, Hak-Sung;Cho, Jae-Hee
    • Journal of the Korean earth science society
    • /
    • v.40 no.4
    • /
    • pp.414-427
    • /
    • 2019
  • In East Asia, the long-range transport of dust storms originating from Mongolia and northern China affects airborne dust loadings over downwind areas in the southern Korean Peninsula. Since 1997, dust loading cases caused by dust storms have been observed using the thresholds of total suspended particles (TSP, ${\geq}250{\mu}g\;m^{-3}\;hr^{-1}$) and particulate matter less than $10{\mu}g$ ($PM_{10}$, ${\geq}190{\mu}g\;m^{-3}\;hr^{-1}$) in the central-southern Korean Peninsula. There were two dust loading cases that exceeded these thresholds in 2016 and three in 2017, which reflects the downward trend of the last twenty-one years in the central-southern Korean Peninsula. Furthermore, five other dust loading cases with mass concentrations lower than the thresholds were observed from 2016 to 2017. In the moderate dust loading cases exceeding the thresholds, a descending motion of cut-off lows below $45^{\circ}N$ and a southward trough at 500 hPa gpm isopleths intensified at the western ridge, and largely extended the surface high-pressure system over southeast China. Airborne dust loadings following pronounced north-westerlies in the forward side of the high-pressure system were transported to the surface of the central-southern Korean Peninsula. However, in slight dust loading cases lower than the thresholds, the restricted descending motion of cut-off lows over $45^{\circ}N$ and the southwestward trough at 500 hPa gpm isopleths intensified the zonal flow over the Korean Peninsula. Surface high- and low-pressure systems moved eastward from the source compared to moderate dust loading cases. Due to the zonal movement of dust storms traversing eastern China, slight dust loading cases were observed with relatively higher ratios of $PM_{2.5}/TSP$ and carbon monoxide (CO) in the central-southern Korean Peninsula.

Dynamics Transition of Electroconvective Instability Depending on Confinement Effect (공간 제약 효과에 따른 전기와류 불안정성의 동역학 전이)

  • Lee, Seungha;Hyun, Cheol Heon;Lee, Hyomin
    • Korean Chemical Engineering Research
    • /
    • v.59 no.4
    • /
    • pp.626-631
    • /
    • 2021
  • One of the nonlinear electrokinetic phenomena around ion exchange membrane is electroconvective instability which can be found in various electrokinetic applications such as electrodialysis, electrochemical battery, microfluidic analysis platform, etc. Such instability acts as a positive transport mechanism for the electrodialysis via amplifying mass transport rate. On the other hands, in the electrochemical battery and the microfluidic applications, the instability provokes unwanted mass transport. In this research, to control the electroconvective instability, the onset of the instability was analyzed as a function of confinement effect as well as applied voltage. As a result, we figured out that the dynamic behavior of electroconvective instability transited as a sequence of stable regime - static regime - chaotic regime depending on the applied voltage and confinement effect. Furthermore, stability curves about the dynamic transition were numerically determined as well. Conclusively, the confinement effect on electroconvective instability can be applied for effective means to control the electrokinetic chaos.

Flow, Heat and Mass Transfer Analysis for Vertical Grooved Tube Evaporator (흠진 수직 증발관에서 유동 및 열/물질 전달 해석)

  • Park Il-Seouk;Choi Do Hyung
    • 한국전산유체공학회:학술대회논문집
    • /
    • 1998.11a
    • /
    • pp.108-113
    • /
    • 1998
  • A numerical investigation for the flow, heat and mass transfer characteristics of the grooved evaporating tube with the films flowing down on both the inside and outside tube walls has been carried out. The condensation occurs along the outside wall while the evaporation takes place at the free surface of the inside film. The 3-D transport equations for momentum and energy are solved by using the FVM(Finite Volume Method). The free surface shape is tracked by the moving grid technique satisfying the SCL(Space Conservation Rule). Due to the secondary motion of the fluid, the film thins at the crest, while thickens at the valley. The velocity and temperature fields as well as the amounts of the condensed and evaporated mass have been successfully predicted for various operating conditions and groove shapes.

  • PDF

A Conceptual Two-Layer Model of Thermohaline Circulation in a Pie-Shaped $\beta$-Plane Basin

  • Park, Young-Gyu
    • Journal of the korean society of oceanography
    • /
    • v.38 no.1
    • /
    • pp.11-16
    • /
    • 2003
  • The three dimensional structure of thermohaline circulation in a D-plane is investigated using a conceptual two layer model and a scaling argument. In this simple model, the water mass formation region is excluded. The upper layer represents the oceans above the main thermocline. The lower layer represents the deep ocean below the thermocline and is much thicker than the upper layer. In each layer, geostrophy and the linear vorticity balance are assumed. The cross interfacial velocity that compensates for the deep water mass formation balances downward heat diffusion from the top. From the above relations, we can determine the thickness of the upper layer, which is the same as thermocline depth. The results we get is basically the same as that we get for an f-plane ocean or the classical thermocline theory. Mass budget using the velocity scales from the scaling argument shows that western boundary and interior transports are much larger than the net meridional transport. Therefore in the thermohaline circulation, horizontal circulation is much stronger than the vertical circulation occuring on a meridional plane.

Study on the Mass Transfer Behavior of AQ and Its Effectiveness during AQ-Kraft Pulping Process

  • Huang, Xiannan;Song, Hainong;Qin, Chengrong;Yoon, Sung-Hoon;Chai, Xin-Sheng
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2006.06b
    • /
    • pp.291-294
    • /
    • 2006
  • Studies of the effectiveness of anthraquinone (AQ) in kraft-AQ pulping in terms of its mechanism of mass transfer have been conducted. Experiments performed have demonstrated an 'apparent solubility' of AQ in caustic solutions of wood lignin. The adsorption behavior of AQ species was also analyzed. Anthraquinone-2-sulfonic acid (AQ-S), a water-soluble derivative of AQ, showed selective adsorption on wood. A mechanism for the transport of AQ into wood chips during kraft pulping are proposed, and some explanations for previously unexplained observations are addressed.

  • PDF

Mass Spectrometry-based Hair Metabolomics for Biomarker Discovery

  • Lee, Yu Ra;Hong, Jongki;Chung, Bong Chul
    • Mass Spectrometry Letters
    • /
    • v.13 no.1
    • /
    • pp.2-10
    • /
    • 2022
  • Metabolomics makes it possible to analyze the interrelationships between various signaling molecules based on the metabolic pathways involved by using high-resolution devices. This approach can also be used to obtain large-scale metabolic information to identify the relevant pathways for disease diagnosis and prognosis and search for potential biomarkers. In the fields of medicine and forensics, hair analysis is used to detect various metabolites in the body. Hair can be harvested readily in a noninvasive manner and is easier to transport and store than blood and urine. Another advantage from a forensic viewpoint is that hair reflects all the components of body fluids. In addition, because of the unique coating structure of hair, it can be used for measurements without changing or destroying its adsorbed components. In this review, the pretreatments for hair analysis, instrumental conditions and clinical applications are discussed. Especially, the clinical use of hair metabolomics in the diagnosis of various diseases and the limitations of the technique are described.

A Study on Particle Diffusion to Develop Faraday Cup Array of Particle Beam Mass Spectrometer System (Faraday cup array 개발을 위한 Particle Beam Mass Spectrometer 시스템 내에서의 입자 확산 연구)

  • Mun, Ji-Hun;Shin, Yong-Hyun;Kim, Tae-Sung;Kang, Sang-Woo
    • Particle and aerosol research
    • /
    • v.8 no.1
    • /
    • pp.29-35
    • /
    • 2012
  • The Faraday cup electrode of different size has been developed and evaluated to investigate the diffusion effect of particles by Brownian motion in a particle beam mass spectrometer(PBMS). Particles which focused and accelerated by aerodynamic lens are charged to saturation in an electron beam, and then deflected electrostatically into a Faraday cup detector for measurement of the particle current. The concentration of particles is converted from currents detected by Faraday cup. Measurements of particle current as a function of deflection voltage are combined with measured relationships between particle velocity and diameter, charge and diameter, and mass and diameter, to determine the particle size distribution. The particle currents were measured using 5, 10, 20, 40 mm sized Faraday cup that can be move to one direction by motion shaft. The current difference for each sizes as a function of position was compared to figure out diffusion effect during transport. Polystyrene latex(PSL) 100, 200 nm sized standard particles were used for evaluation. The measurement using 5 mm sized Faraday cup has the highest resolution in a diffusion distance and the smaller particles had widely diffused.