• Korean Chemical Engineering Research
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• 제54권5호
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• pp.648-652
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• 2016

본 연구에서는 구아니딘계 초염기인 1,1,3,3-테트라메틸 구아니딘(TMG)과 에틸렌 글라이콜로 구성된 비수계 흡수제를 충진탑에 적용하여 이산화탄소 흡수특성을 고찰하였다. 흡수탑은 내경이 1 in이고 높이는 0.6 m이며 탑 내부는 $0.16in{\times}0.16in$의 규격을 갖는 다공 충진물로 채웠다. 흡수탑에서의 이산화탄소 제거 효율에 대한 흡수제 농도, 조업온도 등의 영향 뿐 아니라 이들이 물질전달 저항에 미치는 영향을 고찰하였다. 이산화탄소에 대한 TMG의 로딩값은 약 ${\alpha}=1.0mol_{CO2}/mol_{TMG}$에 달하였으며 이산화탄소가 적게 로딩된 흡수제에서는 총괄 물질전달 계수가 TMG의 농도에 비례하였으나 ${\alpha}=0.5$ 이상의 로딩값에서는 총괄 물질전달계수가 오히려 감소하였다. 이는 흡수제의 이산화탄소에 대한 로딩값에 따른 흡수제 점도 증가로 인한 액체상에서의 물질전달 저항 증가로 해석할 수 있다.

• 공업화학
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• 제9권7호
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• pp.1036-1042
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• 1998

소수성실관막을 이용하여 수용액 중의 Cr(VI)을 TDA로 추출하고, 이를 NaOH 수용액으로 회수하였다. 역추출공정에서의 물질전달속도는 추출공정에 비해 작았으며, 이러한 결과는 소수성막의 내부를 유기상이 흐르게 되면 추출과정에서는 무시할 수 있었던 막저항이 작용하기 때문이라 판단된다. 막수량을 달리한 4개의 막모듈(60, 100, 150, 300가닥)을 제작하였으며, 각 모듈에 대해 수용상 및 유기상의 유량이 물질전달속도에 미치는 영향에 대해서도 검토하였다. 이 실험으로부터 소수성막을 이용한 추출공정에서는, 막내부를 흐르는 수용상의 유량이 물질전달속도에 큰 영향을 주었으나 유기상 유량의 영향은 미약하다는 것을 알 수 있었다. 반면, 역추출공정에서의 물질전달속도는 수용상(회수액)유량에도 유기상(Cr-TDA 착화합물)의 유량에도 영향을 받지 않음을 알 수 있었다.

• Journal of Mechanical Science and Technology
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• 제18권3호
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• pp.513-525
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• 2004

This paper reports an experimental study on flow boiling of pure refrigerants R l34a and R l23 and their mixtures in a uniformly heated horizontal tube. The flow pattern was observed through tubular sight glasses with an internal diameter of 10㎜ located at the inlet and outlet of the test section. Tests were run at a pressure of 0.6 MPa in the heat flux ranges of 5-50㎾/㎡, vapor quality 0-100 percent and mass velocity of 150-600㎏/㎡s. Both in the nucleate boiling-dominant region at low quality and in the two-phase convective evaporation region at higher quality where nucleation is supposed to be fully suppressed, the heat transfer coefficient for the mixture was lower than that for an equivalent pure component with the same physical properties as the mixture. The reduction of the heat transfer coefficient in mixture is explained by such mechanisms as mass transfer resistance and non-linear variation in physical properties etc. In this study, the contribution of convective evaporation, which is obtained for pure refrigerants under the suppression of nucleate boiling, is multiplied by the composition factor by Singal et al. (1984). On the basis of Chen's superposition model, a new correlation is presented for heat transfer coefficients of mixture.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제12권1호
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• pp.25-32
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• 2008

A pin fin is optimized based on the increasing rate of heat loss by using a two-dimensional analytic method. The optimum heat loss, corresponding optimum thermal resistance and fin length are presented as a function of the fin base thickness, convection characteristic numbers ratio, fin outer radius and ambient convection characteristic number. One of the results shows that both the optimum heat loss and fin length decrease linearly whereas the optimum thermal resistance increases very slightly with increase of the fin base thickness.

• 동력기계공학회지
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• 제17권2호
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• pp.70-77
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• 2013

An experimental study was carried out to understand the heat transfer performance of a miniature loop heat pipes using water-based copper nanoparticles suspensions as the working fluid. The suspensions consisted of deionized water and copper nanoparticles with an average diameter of 80 nm. Effects of the cupper mass concentration and the operation pressure on the average evaporation and condensation heat transfer coefficients, the critical heat flux and the total heat resistance of the mLHPs were investigated and discussed. The pressure frequency also depends upon the evaporator temperature which has been maintained from $60^{\circ}C$ to $90^{\circ}C$. The Investigation shows 60% filling ratio gives the highest inside pressure magnitude of highest number pressure frequency at any of setting of evaporator temperature and 5wt% results the lowest heat flow resistance.

• Korean Chemical Engineering Research
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• 제46권3호
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• pp.521-528
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• 2008

중공사막 접촉기에 적절한 PVDF 중공사막을 상전이 공정에 의하여 제조하였으며, SEM 과 기체투과도에 의하여 그 특성을 분석하였다. 벤치규모 중공사막 접촉기에서 $SO_2$ 제거를 위한 흡수제는 수산화나트륨 수용액을 사용하였다. 기체는 shell side, 액체는 lumen side로 흐르는 counter-current로 실험하였으며, 흡수제의 농도, 기체의 유속, 액가스비, 유입 $SO_2$ 농도에 따른 영향을 알아보았으며, 수학적 모델링에 의해 막 물질전달계수($k_m$)를 측정하였다. 흡수제의 농도와 액기비가 증가함에 따라 기-액 계면에서 충분한 알칼리도가 제공되므로, 액체막 저항이 감소하며, 총괄물질전달 용량계수는 증가하였다. 기체유속이 증가함에 따라 기체막저항은 감소하게 되므로 총괄물질전달 용량계수는 증가하였다.

• 설비공학논문집
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• 제17권1호
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• pp.25-32
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• 2005

Falling film heat transfer has been widely used in many applications in which heat and mass transfer occur simultaneously, such as evaporative coolers, cooling towers, absorption chillers, etc. In such cases, it is desirable that the falling film spreads widely on the surface forming thin liquid film to enlarge contact surface and to reduce the thermal resistance across the film and/or the flow resistance to the vapor stream over the film. In this work, the surface is treated to have thin porous layer on the surface. With this treatment, the liquid can be spread widely on the surface by the capillary force resulting from the porous structure. In addition to this, the liquid can be held within the porous structure to improve surface wettedness regardless of the surface inclination. The experiment on the evaporative cooling of an inclined surface has been conducted to verify the effectiveness of the surface treatment. It is measured that the evaporative heat transfer increases about $50\%$ by the porous layer treatment as compared with that from orignal bare surfaces.

• 국제초고층학회논문집
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• 제13권1호
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• pp.85-95
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• 2024

A composite member made of concrete-filled steel tubes (CFT columns) has been recognized for its fire resistance due to the thermal mass effect of concrete inside the steel tube, as shown in various studies. In this study, the fire resistance performance of reinforced CFT columns under constant axial load was evaluated using finite element analysis with ABAQUS. For this purpose, the variables including cross-section size, steel tube thickness, and concrete cover thickness were set, and the temperature distribution in the column cross-section exposed to a standard fire was investigated using heat transfer analysis. Ultimately, a P-M interaction curve was obtained by evaluating the overall residual strength of columns, and the fire resistance time was determined by evaluating axial displacement-time responses due to the reduction in load capacity during fire through stress analysis.

• 한국미생물·생명공학회지
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• 제16권6호
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• pp.510-516
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• 1988

본 연구는 균주로 Rhodospirillum rubrum KS-301, 증식 제한 기질로 글루코오스, 고정화 담체로 Ca alginate를 사용한 고정화 생물 반응기를 조작할 때 담체에 의해 형성되는 물질전달 저항에 대한 도입 기질의 농도, 희석속도의 영향을 고찰하였다. 또한 효율인자를 평가하기 위해 속도식 변수를 구하였다. 충전층 반응기의 경우 외부 액막 물질전달 저항보다는 내부 물질전달 저항이 우세함을 알 수 있었고 총괄 효율인자는 희석속도의 증가에 따라 감소하였다. 연속 교반 탱크 반응기의 경우 외부 액막 물질전달 저항은 무시할 수 있으며 총괄 효율인자는 희석속도에 영향을 받지 않았다. 희석속도 0.2/h, 비드 반경 0.15cm, 초기 글루코오스 농도 1.0g/L의 실험조건에서 총괄 효율인자는 충전층 반응기와 연속 교반 반응기에서 각각 0.70과 0.77이었다.

• 한국환경과학회지
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• 제30권6호
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• pp.429-439
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• 2021

Food waste is both an industrial and residential source of pollution, and there has been a great need for food waste reduction. As a preliminary step in this study, waste reduction is quantitatively modeled. This study presents two models based on kinetics: a simple kinetic model and a mass transport-shrinking model. In the simple kinetic model, the smaller is the reaction rate constant ratio k₁, the lower the rate of conversion from the raw material to intermediate products. Accordingly, the total elapsed reaction time becomes shorter. In the mass transport-shrinking model, the smaller is the microbial decomposition resistance versus the liquid mass transfer resistance, the greater is the reduction rate of the radius of spherical waste particles. Results showed that the computed reduction of waste mass in the second model agreed reasonably with that obtained from a few experimantal trials of biodegradation, in which the microbial effect appeared to dominate. All calculations were performed using MATLAB 2020 on PC.