• Title/Summary/Keyword: Mass Spectrum

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Synthesis of Phosphates and Phosphoric Amides (Ⅰ) (Phosphates 및 Phosphoric Amides의 합성 (제1보))

  • Kil-Yeong Choi;Sam-Kwon Choi
    • Journal of the Korean Chemical Society
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    • v.24 no.6
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    • pp.457-462
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    • 1980
  • Phosphates and phosphoric amides were synthesized by the reaction of phosphoryl chloride with allyl alcohol, 2,3-dibromopropanol, 2-pyrrolidone and ethylenimine. All of these compounds were thermally very unstable. Allyl phosphorodichoridate and diallyl phosphorochloridate gave significant amount of polymeric products when they were distilled. IR spectra showed characteristic P=O stretching bands between 1300 and $1200 cm^{-1}$ and NMR spectra were very complicated due to the long range coupling effect of phosphorus atom. And mass spectrum of 2,3-dibromopropyl phosphorodichloridate gave no indication of molecular ion peak.

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On Feasibility Study of the Charged Particle Beam Pretreatment Process for Non-conducting Metal Coating (무전도 금속 증착을 위한 하전 입자빔 전처리 공정의 타당성 연구)

  • Na, Myung Hwan;Park, Young Sik;Shim, Ha-Mong;Chun, Young Ho
    • Journal of Korean Society for Quality Management
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    • v.42 no.2
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    • pp.179-187
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    • 2014
  • Purpose: Since several problems were found when present non-conducting metal coating process was applied to mass production, we study and develop to improve those problems. Methods: In this paper, a couple of analysis methods such as surface hardness, XPS spectrum analysis, morphology, and reflection ratio were used. Results: This paper suggest a new possibility of Non-conducting thin metal coating method that has quality of mass production phase without UV coating process. Conclusion: By the result of analysis, we can set optimized process conditions of the electro deposition coating using electron beam.

Analysis of Ultra Pure Sulfuric Acid for Semiconductor Using High Resolution ICP-MS (고분해능 ICP-MS를 이용한 반도체용 고순도 황산 분석)

  • Heo, Y.W.;GiI, J.I.;Lim, H.B.
    • Analytical Science and Technology
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    • v.11 no.4
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    • pp.311-315
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    • 1998
  • Ultra trace metal impurities of high-purity sulfuric acid for semiconductor process have been determined in the concentration of lower than ppb (ng/g) level using high resolution inductively coupled plasma mass spectrometer (HR-ICP-MS).The acid samples were evaporated and concentrated by the factor of 20. No clement in the acids exceeded 1ppb level and most of the clements were determined below 10ppt (pg/g). Elements without spectral interference in mass spectrum, such as In, V, Mn, etc, were determined in the concentration of below 1 ppt level The recoveries in the range of 72% to 127.2% for 0.5 ppb spiked sample were obtained.

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Theoretically-based and practice-oriented formulations for the floor spectra evaluation

  • Abbati, Stefania Degli;Cattari, Serena;Lagomarsino, Sergio
    • Earthquakes and Structures
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    • v.15 no.5
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    • pp.565-581
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    • 2018
  • This paper proposes a new analytical formulation for computing the seismic input at various levels of a structure in terms of floor response spectra. The approach, which neglects the dynamic interaction between primary structure and secondary element, is particularly useful for the seismic assessment of secondary and non-structural elements. The proposed formulation has a robust theoretical basis and it is based on few meaningful dynamic parameters of the main building. The method has been validated in the linear and nonlinear behavior of the main building through results coming from both experimental tests (available in literature) and parametric numerical analyses. The conditions, for which the Floor Spectrum Approach and its simplified assumptions are valid, have been derived in terms of specific interval ratios between the mass of the secondary element and the participant mass of the main structure. Finally, a practice-oriented formulation has been derived, which could be easily implementable also at code level.

Postharvest Biological Control of Colletotrichum acutatum on Apple by Bacillus subtilis HM1 and the Structural Identification of Antagonists

  • Kim, Hae-Min;Lee, Kui-Jae;Chae, Jong-Chan
    • Journal of Microbiology and Biotechnology
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    • v.25 no.11
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    • pp.1954-1959
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    • 2015
  • Bacillus subtilis HM1 was isolated from the rhizosphere region of halophytes for its antifungal activity against Colletotrichum acutatum, the causative agent of anthracnose. Treatment of postharvest apples with the cell culture or with a cell-free culture supernatant reduced disease severity 80.7% and 69.4%, respectively. Both treatments also exhibited antifungal activity against various phytopathogenic fungi in vitro. The antifungal substances were purified and analyzed by acid precipitation, gel filtration, high-performance liquid chromatography, and matrix-assisted laser desorption ionization-time of flight mass spectrometry (MALDI-TOF MS). Three compounds were identified as fengycin, iturin, and surfactin. The MALDI-TOF/TOF mass spectrum revealed the presence of cyclized fengycin homologs A and B, which were distinguishable on the basis of the presence of either alanine or valine, respectively, at position 6 of the peptide sequence. In addition, the cyclized structure of fengycin was shown to play a critical role in antifungal activity.

Development of the evaluation equipment for the prominent discrete tone radiated by acoustic emission products in mass production (대량생산용 음향방출제품의 돌출음 평가장비 개발)

  • Lee, Yong-Kwan;Kim, Sun
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2012.04a
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    • pp.76-81
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    • 2012
  • In-process evaluation equipment for the prominent discrete tone (PDT) emitted by small motors or actuators such as HDD(Hard Disk Driver), ODD(Optical Disk Driver) or linear motors has been developed and estimated on the basis of Prominence Ratio (PR) method in ECMA 74. Correlation of the evaluation equipment was performed in comparison with the method by ECMA 74 in anechoic chamber. Coherent function between two systems was applied in order to compensate traceability of ECMA 74 in anechoic chamber. Usability of the developed system with estimated Gage R&R shall be approved with real samples in the mass production line.

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Dynamical Structure of NGC 4486

  • Park, Kyung-Suk;Chum, Mun-Suk
    • Journal of Astronomy and Space Sciences
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    • v.4 no.1
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    • pp.35-45
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    • 1987
  • The peculiar elliptical (EOp) galaxy NGC 4486 and two KOII comparison stars HR5450, HR6935 were observed spectroscopically using the 74-inch telescope and Image Tube at Mt. Stomlo Observatory. From the Gaussian Broadening Function, broadened spectrum of two comparison stars were computed for the range between wavelength 4800$\AA$ and 5400$\AA$. Velocity dispersions in the line of sight of M87 were obtained by visual fitting. The fitted velocity dispersion is 450 km/sec at the nucleus, 350km/sec at r=12", and 300km/sec at r=24". Using the photometric data and the central value of velocity dispersion, we determined the mass of M87. From <$r^{2/4}$ law and the Virial theorem the calculated total mass in $2.1\times10^{12}M_\odot$ and from the King Model $M=1.2\times10^{12}M_\odot$. And M/L ratio of M87 is about 30.

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Neurilemoma Localized in the Palmaris Longus Tendon with no Connection to the Major Nerve Trunk (주요 신경과의 연결이 없이 발생한 긴손바닥근의 신경초종)

  • Park, Jeong-Young;Jung, Sung-No;Sohn, Won-Il;Kwon, Ho
    • Archives of Plastic Surgery
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    • v.38 no.4
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    • pp.498-500
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    • 2011
  • Purpose: Neurilemoma is benign tumor of the nerve sheath which arises from Schwann cells. It is usually formed along the path of a peripheral nerve but is rarely separate from normal nerve fascicles. We experienced a patient with an isolated neurilemoma localized in the palmaris longus tendon with no connection to the major nerve trunk, which was in an unusual location and has never been reported. We report our case with the review of the literature. Methods: A 23-year-old female visited our clinic with mild pain on the mass at the flexor area of the right wrist which had been present for about one year. The physical examination revealed a $1{\times}1cm$ sized subcutaneous mass at the flexor area of the right wrist. Sonography and computed tomography showed an ovoid, superficial solid mass on the palmaris longus tendon. Upon surgical excision, a $1{\times}0.5cm$ sized mass attached to the palmaris longus tendon was found. The tumor had no connection with the median nerve and was detached easily from the palmaris longus tendon. Results: Histological examination demonstrated the mass to be a neurilemoma, which consists of spindle shaped cells with oval elongated nuclei arranged fascicles. No sensory dysfunction or evidence of recurrence was found during the 12 months of postoperative follow-up. Conclusion: We experienced a rare case of neurilemoma attached to the palmaris longus tendon with no connection to the major nerve trunk. We wish to emphasize its unusual location through our case and hope to expand our spectrum in exploring the upper extremity mass.

High-resolution optical and near-infrared spectroscopic study of 2MASS J06593158-0405277

  • Park, Sunkyung;Lee, Jeong-Eun;Pyo, Tae-Soo;Sung, Hyun-Il;Lee, Sang-Gak;Kang, Wonseok;Oh, Hyung-Il;Yoon, Tae Seog;Mace, Gregory N.;Jaffe, Daniel T.;Yoon, Sung-Yong;Green, Joel D.
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.50.2-50.2
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    • 2019
  • We present the results of high-resolution (R ≥ 30,000) optical and near-infrared spectroscopic monitoring observations of a FU Orionis-type object, 2MASS J06593158-0405277. We have monitored 2MASS J06593158-0405277 with the Bohyunsan Optical Echelle Spectrograph (BOES) and the Immersion GRating INfrared Spectrograph (IGRINS) since December 2014. Various features produced by wind, disk, and outflow/jet were detected. The wind features varied over time and disappeared about a year after the outburst occurred. The double-peaked line profiles were detected in the optical and near-infrared, and the line widths decrease with increasing wavelength. The disk features in the optical spectra are fit well with G2-type or G5-type stellar spectra convolved with a disk rotational profile of about 45 km s-1, which corresponds to a disk radius of about 71 Rfor a central mass of 0.75 M. Disk features in near-infrared spectra are fit well with a K1-type stellar spectrum convolved with a disk rotational profile of about 35 km s-1, which corresponds to a disk radius of about 117 R for a central mass of 0.75 M. We also detected [S II] and H2 emission lines, which are rarely found in FUors but are usually found in the earlier stage of young stellar objects. Therefore, we suggest that 2MASS J06593158-0405277 is in the relatively earlier part of Class II stage.

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Feature Selection for Classification of Mass Spectrometric Proteomic Data Using Random Forest (단백체 스펙트럼 데이터의 분류를 위한 랜덤 포리스트 기반 특성 선택 알고리즘)

  • Ohn, Syng-Yup;Chi, Seung-Do;Han, Mi-Young
    • Journal of the Korea Society for Simulation
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    • v.22 no.4
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    • pp.139-147
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    • 2013
  • This paper proposes a novel method for feature selection for mass spectrometric proteomic data based on Random Forest. The method includes an effective preprocessing step to filter a large amount of redundant features with high correlation and applies a tournament strategy to get an optimal feature subset. Experiments on three public datasets, Ovarian 4-3-02, Ovarian 7-8-02 and Prostate shows that the new method achieves high performance comparing with widely used methods and balanced rate of specificity and sensitivity.