• Korean Journal of Fisheries and Aquatic Sciences
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• v.53 no.5
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• pp.773-783
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• 2020

In order to evaluate the recovery of fishing ground environment after the cessation of aquaculture farming, we examined the variation in sediment quality over time using different geochemical factors and investigated whether these factors are indicators of sediment quality recovery. The study area was an oyster Crassostrea gigas, farm in Tongyeong, Geyongsangnam-do, South Korea, where aquaculture activities had been carried out for 20 years, and the changes in water and sediment environment were monitored for 14 months after the abandonment of the farm. The mean water depth was 14 m, with a tidal range of 3 m, and seawater current velocity ranged from 4.7 to 7.0 cm/s. After the abandonment of the farm, total organic carbon and total nitrogen concentrations in the surface sediments decreased significantly over time compared to those in the control site; in particular, immediately after farm abandonment, acid-volatile sulfide concentrations decreased relatively rapidly. Carbohydrate and protein concentrations in the sediments showed no significant changes; however, lipid concentrations markedly decreased. Further studies on other aquaculture taxa and various aquaculture areas are needed to establish new policies for environmental management of fishing grounds, such as relocation of fishing grounds and determination of optimal fallowing periods.

• Journal of Environmental Science International
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• v.20 no.7
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• pp.845-855
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• 2011

The aim of this paper is to correlate the release characteristics of marine and lake sediment with their vicinal oxic conditions. We performed lab-scale simulation experiments using field sediment and water in order to compare the release concentrations and the release rates one another. To provide a few different kinds of oxic environments we used natural air flow and some oxygen releasing compounds such as $CaO_2$ and $MgO_2$. In case of phosphates, in each oxic condition, removal of phosphorus via biological activity and that via salt precipitation with the metal ions lowered the release rates. The behavior of the nitrogen-origin salts seemed to greatly depend on the typical biological actions - growth of biomass, nitrification, and partial denitrification. Generally speaking, the control of releases of $NH_3$-N, $PO_4$-P, T-N and T-P was successful under the oxic conditions meanwhile COD, nitrates and nitrites were difficult to reduce the releases into the bulk water because of the considerable microbial oxidation. Based on typical diffusive mass transfer kinetics the changes of concentrations of the nutrients were computed for qualitative and quantitative comparisons.

• Ocean and Polar Research
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• v.28 no.4
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• pp.369-383
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• 2006

The Saemangeum project is one of the biggest reclamation efforts in Korea and may cause coastal ecosystem change due to altered environments and habitat loss. Since February 2002, benthic environment and community structure in the Saemangeum studied area were studied to assess the influence of the project on macrofaunal community. The result of seasonal study from February, 2002 to August 2005 is reported here. Overall, changes of species numbers and dominant species of benthic animals in the periods before (1988) and after $(2002{\sim}2005)$ the Saemangeum dike construction were not evident both inside and outside the dike. However, local environmental and community change were noted The partial completion of Saemangeum dike $(4^{th}\;dike)$ in June 2003 altered water circulation and sediment deposition patterns both inside and outside the dike. Fine sediment was accumulated inside and outside the $4^{th}$ dike while coarse sediment dominated near the main channel (Sinsi gate). Benthic community resl)ended to the altered sediment type in these areas. Species number and diversity in both site was low compared to other sites. The dominant species in these areas were composed of the benthos that had not commonly occurred in the Saemangeum subtidal area.

• Journal of Environmental Science International
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• v.19 no.11
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• pp.1355-1362
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• 2010

This study was carried out in order to observe how the bay sediment would be changed with microbial treatments and a chemical oxidant like $CaO_2$. The sediment during the treatments was analyzed in terms of pH, ORP, volatile organics content, COD, AVS, T-N, and T-P. With $CaO_2$ treatment, pH was kept over 9.66 and ORP ranged from +4.70~+46.0, which meant an aerobic state meanwhile with the microbial treatment those were worse. In addition the chemical treatment showed better environmental index values than the microbial one: volatile organics content and COD values in the former were 12.9% and 37.9% while those in the latter were 4.5% and 18.7%, respectively. AVS and T-P were 71.1% and 100% versus 56.5% and 85.8%, respectively. However, the microbial treatment was better for T-N(66% higher). On the other hand, both treatment at a time enhanced all the environmental indices but COD meantime pH and ORP values were lower than with the chemical treatment only. Thus additional input of an oxygen generator like $CaO_2$ could improve the environmental state of a bay sediment where the biological treatment is going on.

• Journal of Navigation and Port Research
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• v.38 no.3
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• pp.269-275
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• 2014

In this study, the adsorption efficiency of mixed heavy metals in aqueous solution was investigated using steel slag. Moreover, heavy-metal stabilization treatment of contaminated marine sediment was achieved using steel slag as stabilizing agents. Heavy metal adsorption was characterized using Freundlich and Langmuir equations. The equilibrium adsorption data were fitted well to the Langmuir model in steel slag. The adsorption uptake of heavy metals were higher in the order of $Pb^{2+}$ > $Cd^{2+}$ > $Cu^{2+}$ > $Zn^{2+}$ > $Ni^{2+}$. The steel slage was applied for a wet-curing duration of 150 days. From the sequential extraction results, the exchangeable, carbonate, and oxides fractions of Ni, Zn, Cu, Pb, and Cd in sediment decreased by 13.0%, 6.0%, 1.3%, 17.0%, and 50.0%, respectively.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.45 no.6
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• pp.704-715
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• 2012

To examine temporal and spatial variation in salinity and nutrients in the shallow pore water of intertidal sandflats, we measured salinity and nutrient concentrations (dissolved inorganic nitrogen [DIN], phosphorus [DIP], and silicate [DSi]) in pore water of the intertidal zone along the coastline of Jeju Island at two and/or three month intervals from May 2009 to December 2010. Geochemical parameters (grain size, ignition loss [IL], chemical oxygen demand [COD], and acid volatile sulfur [AVS]) in sediment were also investigated. The surface sediments in intertidal sandflats of Jeju Island were mainly composed of sand, slightly gravelly sand and gravelly sand, with a range of mean grain size from 0.5 to 2.5 ${\O}$. Concentrations of IL and COD in sediment were higher along the eastern coast, as compared to the western coast, due to differences in biogenic sediment composition. Salinity and nutrient concentrations in pore water were markedly different across time and space during rainy seasons, whereas concentrations were temporally and spatially more stable during dry seasons. These results suggest that salinity and nutrient concentrations in pore water depend on the advective flow of fresh groundwater. We also observed an imbalance of the DIN/DIP ratio in pore water due to the influence of contaminated sources of DIN. In particular, nutrient concentrations during rainy and dry seasons were characterized by high DIN/DIP ratios (mean-127) and low DIN/DIP ratios (mean-10), respectively, relative to the Redfield ratio (16) in offshore seawater. Such an imbalance of DIN/DIP ratios in pore water can affect the coastal ecosystem and appears to cause outbreaks of benthic seaweed along the coastline of Jeju Island.

• Ocean and Polar Research
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• v.32 no.3
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• pp.299-307
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• 2010

In conjunction with geochemical characteristics, rate of sulfate reduction was investigated at two sediment sites in the continental slope and rise (basin) of the Ulleung Basin in the East Sea. Geochemical sediment analysis revealed that the surface sediments of the basin site (D2) were enriched with manganese oxides (348 ${\mu}mol$ $cm^{-3}$) and iron oxides (133 ${\mu}mol$ $cm^{-3}$), whereas total reduced sulfur (TRS) in the solid phase was nearly depleted. Sulfate reduction rates (SRRs) ranged from 20.96 to 92.87 nmol $cm^{-3}$ $d^{-1}$ at the slope site (M1) and from 0.65 to 22.32 nmol $cm^{-3}$ $d^{-1}$ at the basin site (D2). Depth integrated SRR within the top 10 cm depth of the slope site (M1; 5.25 mmol $m^{-2}$ $d^{-1}$) was approximately 6 times higher than that at the basin site (D2; 0.94 mmol $m^{-2}$ $d^{-1}$) despite high organic content (>2.0% dry wt.) in the sediment of both sites. The results indicate that the spatial variations of sulfate reduction are affected by the distribution of manganese oxide and iron oxide-enriched surface sediment of the Ulleung Basin.

• Journal of the Korean Society of Marine Environment & Safety
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• v.20 no.6
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• pp.640-645
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• 2014

This study aimed to determine the swimming suitability of sea and to suggest methods to address the problems on sea water color and green plants growing on sediment in the artificial created swimming in the beach of southwestern Korea. Sea water samples were collected from January to December of 2010 and analysis for SS, COD, $NH_4{^+}-N$, TP, MPN, sediment IL, ORP and plants on sediment. The results showed that the sea water under the swimming suitability "level of management" based on the relating high levels of SS and TP, but still suitable for swimming on the basis of MPN. Improving exchange seawater flow, dredging, coating and chemical treatment of polluted sediments in addition to removal of point sources and restriction of non point sources in the study area could improve the sea water quality and swimming suitability of the sea.

• Journal of Environmental Science International
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• v.28 no.5
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• pp.511-520
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• 2019

This study was investigated to improve the phosphorus release and water quality by transformation of sedimentary P fraction for application of $CaO_2$. For the experiment, 0.5% (w/w) of $CaO_2$ was homogenized in the sediment and incubated with the control for 20 days. The analytical results showed that pH increased with $CaO_2$ and redox potential (ORP) was improved in the sediment of the reactor. The growth rate of chlorophyll-a was lower in the $CaO_2$ reactor and Dissolved Oxygen (DO) of overlying water maintained higher than that of the control. Total phosphorus (T-P) concentration in the overlying water increased from the initial concentration to 0.304mg/L in the control at 20 days. The reactor of $CaO_2$ was lowered by 29.3%. Ex-P, Fe-P and Ca-P in sediment P fraction were increased with the $CaO_2$. The formation of bound Fe-P and Ca-P in the sediments seemed to control the release of P by removing the Soluble Reactive Phosphorus (SRP) presented in the pore water. From the result, this indicated that the reduction of P release from the sediments seems to be effective in suppressing the eutrophication of P and improving the oxygen condition in the water quality with the application of $CaO_2$.

• Journal of the korean society of oceanography
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• v.33 no.3
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• pp.64-70
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• 1998

Forty sediment samples from Kyeonggi Bay, Korea were analyzed for butyltins, including tributyltin (TBT), dibutyltin (DBT), and monobutyltin (MBT) to determine their distribution and source in this area. Total butyltin concentrations in Kyeonggi Bay sediments ranged from 0.8 to 297 ng/g dry wt. with a mean value of 38 ng/g. The highest butyltin concentration was found in the innermost site in Incheon Harbor basin. The mouth of Han River had higher butyltin levels in sediments compared to open ocean. Butyltin levels correlated well with organic carbon content of sediment, but the major factor was the distance from the source area where antifouling paints were used for vessels and marine structures. Butyltin concentrations in the study area were lower than those reported for bays in other parts of the world. Considering the high toxic potential and sediment/water partition coefficient of TBT, further studies are needed to assess its biological effect in the marine ecosystem of Kyeonggi Bay.