• Title/Summary/Keyword: Major ion

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Hydrochemical Characteristics of Deep Groundwater at Surak-ri, Nonsan-gun, Chungnam Province, Korea (충남 논산군 수락리 일대 심부지하수의 수질특성)

  • Im, HyunChul;Cho, ByongWook
    • Journal of the Korean Geophysical Society
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    • v.7 no.2
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    • pp.113-120
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    • 2004
  • Hydrochemical characteristics of deep groundwater at Surak-ri, Nonsan-gun, Chungnam Province was explained by major ion concentration, water type, and phase stability diagram. The area is composed of meta-sedimentary rock and quartz pophyry. The 5 boreholes where deep groundwater was sampled and analyzed are located on the meta-sedimentary rocks and drilling depth range of the wells is from 554 m to 928 m. pH, TDS, Na, and SiO2 values are high in the groundwater from meta-sedimentary area intruded by quartz pophyry, while Ca is high in the groundwater from meta-sedimentary area. K and Mg concentrations are low but F concentration is high both groundwater. The content of major anions is in the order of CO3(HCO3)>Cl>SO4(F) in both geology, while that of major cations shows the order of Na>Ca>K(Mg) in meta-sedimentary area intruded by quartz porphyry and a>Na>Mg>Na in meta-sedimentary area. Based on the phase equilibrium in the systems Na2O-Al2O3-SiO2-H2O and K2O-Al2O3-SiO2-H2O, the groundwater is saturated with respect to Quartz and more evolved compared with the natural mineral water. It is concluded that chemical evolution in the groundwater from meta-sedimentary area intruded by quartz porphyry, is nearly saturated with respect to feldspar, while the groundwater from meta-sedimentary area continue to proceed with increasing pH by reaction of feldspar.

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Acid/base alterations during major abdominal surgery: 6% hydroxyethyl starch infusion versus 5% albumin

  • Kwak, Hyun Jeong;Lim, Oh Kyung;Baik, Jae Myung;Jo, Youn Yi
    • Korean Journal of Anesthesiology
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    • v.71 no.6
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    • pp.459-466
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    • 2018
  • Background: To compare the effects of intraoperative infusions of balanced electrolyte solution (BES)-based hydroxyethyl starch (HES) and saline-based albumin on metabolic acidosis and acid/base changes during major abdominal surgery conducted using Stewart's approach. Methods: Forty patients, aged 20-65 years, undergoing major abdominal surgery, were randomly assigned to the HES group (n = 20; received 500 ml of BES-based 6% HES 130/0.4) or the albumin group (n = 20; received 500 ml of normal saline-based 5% albumin). Acid-base parameters were measured and calculated using results obtained from arterial blood samples taken after anesthesia induction (T1), 2 hours after surgery commencement (T2), immediately after surgery (T3), and 1 hour after arriving at a postanesthetic care unit (T4). Results: Arterial pH in the HES group was significantly higher than that in the albumin group at T3 ($7.40{\pm}0.04$ vs. $7.38{\pm}0.04$, P = 0.043), and pH values exhibited significant intergroup difference over time (P = 0.002). Arterial pH was significantly lower at T3 and T4 in the HES group and at T2, T3, and T4 in the albumin group than at T1. Apparent strong ion difference (SIDa) was significantly lower at T2, T3, and T4 than at T1 in both groups. Total plasma weak nonvolatile acid ($A_{TOT}$) was significantly lower in the HES group than in the albumin group at T2, T3 and T4 and exhibited a significant intergroup difference over time (P < 0.001). Conclusions: BES-based 6% HES infusion was associated with lower arterial pH values at the end of surgery than saline-based 5% albumin infusion, but neither colloid caused clinically significant metabolic acidosis (defined as an arterial pH < 7.35).

Identification of Antimutagenic Compound from Kale by High Performance liquid Chromatography and Mass Spectrometry

  • Lee, Seon-Mi;Rhee, Sook -Hee;Yoo, Jong-Shin;Park, Kun-Young
    • Preventive Nutrition and Food Science
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    • v.3 no.4
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    • pp.334-338
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    • 1998
  • Kale(Brassica oleracea var. acephala) is one of Cruciferous vegetables that is closely related to the wild ancestral form of cabbabe. The ethanol extract of kale which contains the active compoundsss under Salmonella assay system was fractionated with chloroform to collect the nonpolar solvent soluble compounds, and then further fractionation was carried out by silica gel column chromatography. Among kale extracts separated by silical gel column chromatography, the fractions of 4, 5 and 6 exhibited strong antimutagenic activities. The major active compounds from the fraction were identified as chlorophyll derivatives by the analysis with HPLC-fritp-MS. The molecular weights of each chlorophyll derivatives in the sample were acquired from the peaks of positive ion atomosphere pressure chemical ionization (APCI) mas spectrometry.

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A study on the visual sensibility of brassiere design(Part II) (브래지어 디자인에 대한 시각적 감성연구(제2보))

  • 하수진;이경희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.23 no.6
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    • pp.767-775
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    • 1999
  • The purpose of this study is to investigate the visual sensibilities of brassiere design. Brassieres were divided into three types according to connection of a cup and a strp. In each type Lace was used where the part of the cup divided by Lines which were constructed such as a mold a horizontal a vertical a mixed and an oblique design. As a result 39 brassieres were obtained. The experiment has been done for seven groups which were divided by the type line and lace with 5 semantic differential bi-polar scales and 10 specialists. The data was analyzed using the statistical SPSS package. The major findings of this research were as follows. An oblique design line in the brassiere were effective in making the breast look bigger more buxom and more voluminous. To make the breast look small and unvoluminous the use of a mold in the 1/2 cup brassiere was effective. Also a mold using lace ion the 1/2 cup brassiere had an effect in making the breast look flatter and broader.

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Comparison of Sesquiterpenes in Korean and American Ginsengs (한국인삼과 북미산 서양상의 Sesquiterpene 성분 비교)

  • 위재준;신지영
    • Journal of Ginseng Research
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    • v.21 no.3
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    • pp.209-213
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    • 1997
  • Sesquiterpenes of Korean ginseng (Panax ginseng C.A. Meyer, KG) and American ginseng (Panax quinquefolium, AG) were Isolated by simultaneous distillation and extraction (SDE) with 30% methanol and n-hexane or adsorption using C18 Sep-Pak . The sesquiterpenes in KG and AG were compared each other by using TLC and GC/MS. Thin layer chromatogram of KG gave 4~5 spots of terpenes colored by vanillin-sulfuric acid, while AG did one major spot. Total ion chromatogram of KG showed about 30 peaks of sesquiterpene having molecular weight 204. Among these, 9 components such as alloaromadendrene, germacrene B, isocaryophyllene, $\alpha$-neoclovene, ${\gamma}$-muurolene and $\beta$-panasinsene together occupied 81.5% of total sesquiterpenes identified. In AG, however, only 3 components, i.e., isocaryophyllene, $\beta$-bisabolene, $\beta$-sesquiphellandrene occupied 79.3% of total sesquiterpenes identified. Especially isocaryophyllene was a dominant component of AG occupying 56.6%. Eight sesquiterpenes, including alloaromadendrene, germacrene B and $\alpha$-humulene, were not detected in AG. These results indicate that sesquiterpenes could be used as indices for the chemical difference between KG and AG.

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Uptake of Lead by the Lead-tolerant Bacteria (Pb ion내성균(耐性菌)에 의한 Pb의 균체내(菌體內) 축적(蓄積)에 관(關)하여)

  • Hong, Soon Duck;Kim, In Seok
    • Current Research on Agriculture and Life Sciences
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    • v.1
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    • pp.47-53
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    • 1983
  • A strain of Alcaligenes sp. Isolated from the sludge of industrial area was found to uptake 24.1 mg lead/g dried cell during incubation in medium containing 100g/ml of lead. Analyses of cellular subfractions reveal that fractions of cell wall contain 88.6 percent of lead found associated with the cells and the remainder is found associated with the cytoplasmic fraction. Ultrastructural examination of the cells cultured in media containing 500 and 1000g/ml of lead showed no major irregularities between cells of the treated and untreated cultures.

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Micromechanics-based evaluation of diffusivity and permeability of concrete containing silica fume (실리카퓸 혼입 콘크리트의 확산계수 및 투수계수의 미시학적 추정)

  • 장종철;송하원;변근주
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.531-536
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    • 2002
  • Silica fume influences concrete diffusivity and permeability as well as strength by densifying the microstructure of the interfacial transition zone (ITZ) of high strength concrete, by reducing the capillary porosity of cement paste and by producing less diffusible and permeable pozzolanic CSH gel than CSH gel of conventional cement hydration. This paper presents a procedure to predict the chloride ion diffusivity and water permeability of the high strength concrete containing silica fume. Water binder ratio, silica fume addition, degree of hydration and volume fraction of aggregates are considered as the major factors influencing concrete diffusivity and permeability in the procedure. Analytical results using the procedure are shown and verified with other data.

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High Selective Oxidation of Alcohols Based on Trivalent Ion (Cr3+ and Co3+) Complexes Anchored on MCM-41 as Heterogeneous Catalysts

  • Shojaei, Abdollah Fallah;Rafie, Mahboubeh Delavar;Loghmani, Mohammad Hassan
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2748-2752
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    • 2012
  • Cr(III) and Co(III) complexes with acetylacetonate were anchored onto a mesoporous MCM-41 through Schiff condensation. The materials were characterized by XRD, FT-IR, BET, CHN and ICP techniques. Elemental analysis of samples revealed that one C=N bond was formed through Schiff condensation on MCM-41 surface. The catalysts were tested for the alcohol oxidations using t-butyl hydroperoxide (TBHP) and $H_2O_2$ as oxidant. The catalytic experiments were carried out at both room temperature and reflux condition. Various solvents such as dichloromethane, acetonitrile and water were examined in the oxidation of alcohols. Among the different solvents, catalytic activity is found more in acetonitrile. Further, the catalysts were recycled three times in the oxidation of alcohols and no major change in the conversion and selectivity is observed, which shows that the immobilized metal-acetylacetonate complexes are stable under the present reaction conditions.

Characteristics of Nitrate Concentration Measured at Gosan: Measurement Data of PM2.5 and TSP between 1998 and 2002 (고산에서 측정한 입자상 질산염 농도 특성: 1998∼2002년 PM2.5와 TSP 측정자료)

  • 김나경;김용표;강창희;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.1
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    • pp.119-128
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    • 2004
  • The nitrate concentrations in PM$_{2.5}$ and TSP measured at Gosan, Jeju Island, Korea, between March 1998 and February 2002, are discussed. Especially, the characteristics of high nitrate concentration days were analyzed. High nitrate concentration cases in PM$_{2.5}$ were highly correlated with anthropogenic species such as NH$_4$$^{[-10]}$ , and high nitrate concentration cases in TSP were highly correlated with crustal species such as nss-Ca$^{2+}$ and nss -Mg$^{2+}$ Backward trajectory analysis results show the cases of high correlation between nitrate and anthropogenic species occurred when the air parcels moved from China, and the cases of high correlation between nitrate and crustal species occurred when the air parcels moved from Mongolia. Also, high nitrate concentration cases occurred most often in spring (65%) when the air parcels moved from Mongolia and China.ina.

Parameters Affecting the TiN Coated Machining Tool's Life (질화 티타늄이 코팅된 절삭공구의 수명에 영향을 미치는 인자)

  • 최병대;김동수
    • Journal of the Korean institute of surface engineering
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    • v.28 no.2
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    • pp.77-82
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    • 1995
  • In this study, we examined the relationships between the coating film's properties, such as microhardness, adhesion of coating fil $m_strate, and machining tool's life time. Samples were prepared by coating TiN on the 5.5 diameter twist drills using reactive ion plating technology, For measuring microhardness and adhesion of fil $m_strate, HSS plate was used for substrate. TiN coated drill's life time was dependent on the adhesion of fil $m_strate and averagely increased by several ten times more than uncoated drill's. The major parameter affecting TiN coated drill's life time was the strong adhesion between coating film and substrate.ate.

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