• Title/Summary/Keyword: MOF-5

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Effect of Consecutive Application of Organic Matter on Soil Chemical Properties and Enzyme Activity in Potato Cultivation Soil (유기물 연용이 감자재배 비화산회토양의 화학성과 효소활성에 미치는 영향)

  • Joa, Jae-Ho;Moon, Kyung-Hwan;Seo, Hyeong-Ho;Choi, Kyung-San;Kim, Seong-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.801-807
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    • 2011
  • This study was carried out to evaluate effect of consecutive application of organic matter on soil chemical properties and dehydrogenase, acid phosphatase activity in non-volcanic ash soil during three cropping season. Organic matter mixture and organic fertilizer (MOF, $2,000kg\;10a^{-1}$), food waste compost (FWC, $2,000kg\;10a^{-1}$), and pig manure compost (PMC, 2,000, 4,000, and $6,000kg\;10a^{-1}$) were applied for each cropping season. Soil pH values were increased after three cropping season in all treatment. In the soils of the increased application of PMC, soil pH, total-nitrogen, available phosphate, exchangeable cations (K, Ca, and Mg), and heavy metal (Zn and Cu) contents were increased. In addition, Soil dehydrogenase activity was significantly increased in proportions to PMC application rate and cropping season during potato cultivation period. The activity was two times higher in PMC ($4,000kg\;10a^{-1}$) than control after the third cropping season. Soil dehydrogenase activity was in order of PMC>FWC>NPK+PMC>MOF. Acid phosphatase activity was higher in PMC ($6,000kg\;10a^{-1}$) than other treatment. Soil Zn content and dehydrogenase activity showed linearly correlation, which were MOF ($R^2$=0.427), FWC ($R^2$=0.427) and PMC ($R^2$=0.411, p<0.01), respectively. This study demonstrated that soil chemical properties and enzyme activity could be affected greatly by consecutive application of different organic matter in the potato cultivation field.

Response of Yield and Nitrogen Use Efficiency for Garlic on Different Types and Rates of Organic Fertilizer (유기질 비료의 종류 및 시비량이 마늘의 수량과 질소이용효율에 미치는 영향)

  • Kim, Seong Heon;Hwang, Hyun Young;Seo, Hye Bin;Rim, Jae Eun;Park, Seong Jin;Lee, Yun Hae;Kim, Myung Sook
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.4
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    • pp.35-42
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    • 2019
  • Organic fertilization (OF) was an effective management strategy to improve crop yield and soil fertility. Determination of optimum application rate has been received great interest as a major research field. In this study, we evaluated optimum application level of three different organic fertilizers; mixed expeller compost (MEC), mixed organic fertilizer (MOF) and organic complex fertilizer (OCF), for garlic cultivation. Treatments consisted of MEC, MOF, OCF (50, 100, 150% of standard nitrogen input), inorganic fertilizer(NPK, N-P2O5-K2O : 250-78-128 kg ha-1) and no-fertilization (control). Overall, the yields of garlic under MEC, MOF and OCF 100% (5,337, 5,617 and 5,276 kg ha-1) were higher than under control (4,496 kg ha-1). The 100% of three OFs treatements showed the highest yield and bulb diameter, similar with NPK, while leaf length and bulb height were not significantly different among all treatments. The 150% of three OFs rather decreased yield. The highest nitrogen use efficiency (38.4 and 38.0%) was observed in MOF 100% and OCF100%, which was the most similar with that in NPK (38.8%). As OF application rate increased, pH was decreased, but soil NO3-N and NH4-N were increased. There was no significant difference in soil organic matter (OM), av. P2O5 and Ex. cation values. From these results, 100% application of OFs could be recommended as a suitable input level for garlic cultivation, regardless of organic fertilizer types. Further study might be required to evaluate long-term OF application effect on soil health and crop productivity.

Failure Modes and Effects Analysis for Electric Power Installations of D University (D대학 수변전설비의 고장모드 영향 분석)

  • Park, Young Ho;Kim, Doo-Hyun
    • Journal of the Korean Society of Safety
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    • v.31 no.5
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    • pp.7-15
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    • 2016
  • The purpose of this paper is to carry out Failure Modes and Effects Analysis (FMEA) and use criticality in order to determine risk priority number of the components of electric power installations in Engineering college building of D university. In risk priority number, GROUP A had 7 failure modes; more specifically, Transfomer had 4 modes, Filter(C)(1 mode), LA(1 mode), and CB(MCCB)(1 mode), and thus 4 components had failure modes. In terms of criticality, high-grade group a total of 16 failure modes, and 7 components-LA(1 mode), CB(MCCB)(1 mode), MOF(2 modes), PT(1 mode), Transformer(7 modes), Cable(3 modes), and Filter(C)(1 mode)-had failure modes. Comparison of risk priority number and criticality was made. The components which had high risk priority number and high criticality were Transformer, Filter(C), LA, and CB(MCCB). The components which had high criticality were MOF and cable. In particular, Transformer(RPN: 4 modes, Criticality: 7 modes) was chosen as an intensive management component.

A Study on The Standard Process of Battle Experiment of the Maritime Weapon Systems Based on the M&S (모의실험 기반의 해양무기체계 전투실험 프로세스 표준화 방안연구)

  • Baek, Sang-Hoon;Hur, Jung-Haeng;Lee, Dong-Hoon;Choi, Bong-Wan
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.5
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    • pp.577-585
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    • 2012
  • Modeling & simulation-based battle experiments(BEx) is being used extensively as an efficient, scientific and rational verification methodology for maritime weapon system acquisition. However, research of definition and concept of BEx and standardized rules and process for the BEx are insufficient in recent military field of BEx. In this study, we discussed the definition and process of BEx based on the role of MND(including JCS), Navy and ADD and proposed the standardized process of BEx for maritime weapon system. Secondly suggested a evaluation methods of modeling and simulation-based BEx with MOP, MOF, MOE in linkage of engineering, engagement, mission and constructive model. Finally presented validate result that applied to the Torpedo using standardized process based on our proposed methodology.

Treatment Planning for Minimizing Carotid Artery Dose in the Radiotherapy of Early Glottic Cancer (조기 성문암의 방사선치료에서 경동맥을 보호하기 위한 치료 계획)

  • Ki, Yang-Kan;Kim, Won-Taek;Nam, Ji- Ho;Kim, Dong-Hyun;Lee, Ju-Hye;Park, Dal;Kim, Don-Won
    • Radiation Oncology Journal
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    • v.29 no.2
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    • pp.115-120
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    • 2011
  • Purpose: To examine the feasibility of the treatment planning for minimizing carotid artery dose in the radiotherapy of early glottic cancer. Materials and Methods: From 2007 to 2010, computed tomography simulation images of 31 patients treated by radiotherapy for early glottic cancer were analyzed. The virtual planning was used to compare the parallel-opposing fields (POF) with the modified oblique fields (MOF) placed at angles to exclude the ipsilateral carotid arteries. Planning target volume (PTV), irradiated volume, carotid artery, and spinal cord were analyzed at a mean dose, $V_{35}$, $V_{40}$, $V_{50}$ and with a percent dose-volume. Results: The beam angles were arranged 25 degrees anteriorly in 23 patients and 30 degrees anteriorly in 8 dose-volume of carotid artery shows the significant difference (p<0.001). The mean doses of carotid artery were 38.5 Gy for POF and 26.3 Gy for MOF and the difference was statistically significant (p=0.012). Similarly, $V_{35}$, $V_{40}$, and $V_{50}$ also showed significant differences between POF and MOF. Conclusion: The modified oblique field was respected to prevent a carotid artery stenosis and reduce the incidence of a stroke based on these results.

Preparation of Self-detoxifying Textile for Removal of Chemical Warfare Agents (군사목적의 유해화학물질 제거용 보호복 소재 제조를 위한 섬유 후가공 처리)

  • Kim, Hanil;Choi, Ik-Sung;Park, Seong-Woo;Han, Yo-han;Kim, Sung-Hun;Park, Hyun-Bae;Min, Mun-hong
    • Textile Coloration and Finishing
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    • v.31 no.1
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    • pp.33-41
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    • 2019
  • In this report, nano-sized catalysts were introduced onto fabric surface to eliminate toxic chemicals assisted by physical adsorption. For chemical removal of toxic compounds, a series of zirconium-containing catalysts were synthesized and treated on fabric to catalyze the hydrolysis and oxidation of target molecules. Antimicrobial was also introduced for the research purpose to prove the compatibility of as-synthesized catalysts with other solutions. Zirconium ligated with hydroxyl group and MOF(Metal-Organic Frameworks) were exploited as catalyst for removal of toxic compounds, while zinc complex was used for an antimicrobial to culminate in a chemical shield. Once fabrics were functionalized, fabrics were washed 2 or 5 times for a washing durability test. The amount of catalyst in textile were measured by ICP-MS and weight increasing ratio of fabrics.

Control of Water-Adsorption Properties of Mesoporous Silica and MOF by Ion Exchange and Salt Impregnation (양이온 교환 및 염 함침을 통한 메조다공성 실리카와 유기-금속 구조체의 수분 흡착 특성 조절)

  • Lee, Eun Kyung;Cho, Kanghee;Kim, Sang Kyum;Lim, Jong Sung;Kim, Jong-Nam
    • Clean Technology
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    • v.24 no.1
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    • pp.55-62
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    • 2018
  • The adsorbent used in water-adsorption cooling system utilizing low-temperature heat of below $90^{\circ}C$ is required to exhibit high water uptake capacity at a relative humidity ($P/P_0$) between 0.1 and 0.3. Mesoporous silica (MCM-41) and MOF(MIL-101) exhibit quite large water adsorption capacity under saturated water vapor at $35^{\circ}C$. However, these adsorbents show small water adsorption capacity ($0.027{g_{water}\;g_{ads}}^{-1}$, $0.074{g_{water}\;g_{ads}}^{-1}$, respectively) in the relative humidity ($P/P_0$) range of 0.1 to 0.3. In this study, the surface properties of mesoporous silica and MOF were modified by simple methods to develop an adsorbent having a higher water uptake than the conventional water adsorbents at a relative humidity ($P/P_0$) of 0.1 ~ 0.3. In the case of mesoporous silica (MCM-41) exhibiting mainly water adsorption at $P/P_0=0.5{\sim}0.7$, aluminum species was functionalized on the mesopore walls and then cations existing near the aluminum were exchanged with various cations (e.g., $Na^+$, ${NH_4}^+$, and $(C_2H_5)_4N^+$). In addition, 20 wt% (to total weight of the composites) of hygroscopic inorganic salt ($CaCl_2$) was impregnated on the MCM-41. In the case of the MIL-101 (MOF), 20 wt% of hygroscopic inorganic salt ($CaCl_2$) was impregnated on the MIL-101. The MCM-41 which was ion-exchanged with various cations has main adsorption branch around 0.5 of $P/P_0$ which was slightly shifted with low-pressure direction in comparison with pristine MCM-41. However, tiny increases were observed on the adsorption in the range of $P/P_0$ between 0.1 and 0.3. After salt impregnation on the MCM-41, the adsorption capacity under $P/P_0=0.1{\sim}0.3$ at $35^{\circ}C$ was increased from $0.027{g_{water}\;g_{ads}}^{-1}$ to $0.152{g_{water}\;g_{ads}}^{-1}$. In the case of MIL-101, the amount of water adsorption at $35^{\circ}C$ under $P/P_0=0.1{\sim}0.3$ was increased from $0.074{g_{water}\;g_{ads}}^{-1}$ to $0.330{g_{water}\;g_{ads}}^{-1}$ after the salt impregnation.

Ionic Liquid Consisted of Composite Membrane for Carbon Dioxide Separation: A Review (이산화탄소 분리를 위한 이온성 액체 기반 복합 멤브레인: 총설)

  • Young Simon Shi Young;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.5
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    • pp.240-247
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    • 2023
  • Even among gas separation methods, CO2 capture and separation via membranes is an ever-growing field, with many different membrane compositions continually being developed. Ionic liquid (IL) based composite membranes show excellent performance values in separating CO2. Similarly, various copolymer/IL composite membranes also display improved performance. The addition of fillers such as graphene oxide to these copolymer/IL composite membranes shows a further enhanced version of these fillers, most likely due to the strong interactions that occur between ILs and organic fillers, which consequently improves factors such as the affinity, selectivity, and adsorption of CO2. Copolymer/IL composite membranes utilizing a metal-organic framework (MOF) showed improved CO2 permeability. This review discusses the study of various combinations of ionic liquid and copolymer composite membranes for carbon dioxide separation.