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http://dx.doi.org/10.5764/TCF.2019.31.1.33

Preparation of Self-detoxifying Textile for Removal of Chemical Warfare Agents  

Kim, Hanil (Textile Convergence Team, DYETEC Institute)
Choi, Ik-Sung (Clothing Material Research Division, Korea Textile Development Institute(KTDI))
Park, Seong-Woo (Clothing Material Research Division, Korea Textile Development Institute(KTDI))
Han, Yo-han (Research Center for Green Carbon Catalysis, Korea Research Institute of Chemical Technology(KRICT))
Kim, Sung-Hun (Agency for Defense Development(ADD))
Park, Hyun-Bae (Agency for Defense Development(ADD))
Min, Mun-hong (Textile Convergence Team, DYETEC Institute)
Publication Information
Textile Coloration and Finishing / v.31, no.1, 2019 , pp. 33-41 More about this Journal
Abstract
In this report, nano-sized catalysts were introduced onto fabric surface to eliminate toxic chemicals assisted by physical adsorption. For chemical removal of toxic compounds, a series of zirconium-containing catalysts were synthesized and treated on fabric to catalyze the hydrolysis and oxidation of target molecules. Antimicrobial was also introduced for the research purpose to prove the compatibility of as-synthesized catalysts with other solutions. Zirconium ligated with hydroxyl group and MOF(Metal-Organic Frameworks) were exploited as catalyst for removal of toxic compounds, while zinc complex was used for an antimicrobial to culminate in a chemical shield. Once fabrics were functionalized, fabrics were washed 2 or 5 times for a washing durability test. The amount of catalyst in textile were measured by ICP-MS and weight increasing ratio of fabrics.
Keywords
metal-organic framework; zirconium hydroxide; Zr-MOF; catalysis; antimicrobial; padding; exhaust; chemical warfare agent; air-purification;
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