• Title/Summary/Keyword: MOF

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Growth Effect of Mixed Organic Fertilizer Blending Poultry Manure Compost in Leaf Vegetables (가공계분 함유 혼합유기질비료의 시비효과)

  • Kim, Young-Sun;Lee, Tae-Soon;Cho, Sung-Hyun;Jeong, Je-Yong;An, Ji-Ye;Lee, Jong-Jin;Han, Ki-Pil;Hong, Joo-Hwa
    • Journal of the Korea Organic Resources Recycling Association
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    • v.25 no.3
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    • pp.45-54
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    • 2017
  • Poultry manure compost (PMC) as the organic fertilizer sources has a high nutrient content such as nitrogen, phosphate and potassium, and its properties been affected by bulking agent. This study was conducted to evaluate properties of mixed organic fertilizer (MOF) containing PMC composting with sawdust and peat moss as bulking agent, and to measure a characteristics of plant growth by their application. The MOF containing 10~30 % PMC had a coincidency with its guideline in Korea. As applied with MOF containing PMC composting with sawdust (PMCS) or MOF containing PMC composting with peat moss (PMCP), dry weight of plant was increased in MOF treatments blending with 10~30 % PMCS or 10~30 % PMCP. In correlation coefficient between blending ratio of PMC in MOFs and plant growth indexes, PMCS was not significantly different, but its PMCP a positive effect (P<0.05). These results indicated that PMC was able to blend about 10~30 % as mixed organic fertilizer source, and its application increased in plant growth.

Efficient Humidity Color Sensor Based on a Photonic Crystal with a Metal-Organic Framework (금속-유기 구조체를 이용한 포토닉 크리스탈 기반의 효율적인 습도 컬러 센서)

  • Kim, Jun Yong;Lee, Sung Hak;Do, Yun Seon
    • Korean Journal of Optics and Photonics
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    • v.29 no.6
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    • pp.268-274
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    • 2018
  • In this study we suggest a humidity-sensitive color sensor using a one-dimensional photonic crystal and Hong Kong University of Science and Technology-1 (HKUST-1), which is a metal-organic framework (MOF) substance. One-dimensional photonic crystals have a photonic band gap, due to a periodic refractive-index change, and block and reflect light components in a specific wavelength band. The refractive index of HKUST-1 differs in dry and humid environments. Herein we designed a sensor using the presence of the photonic band gap, with FDTD simulation. As a result of optical analysis, the color conversion of the reflected light was superior to the color conversion of the transmitted light. When the center wavelength of the photonic band gap was 550 nm, the maximum peak value of the wet environment increased by a factor of about 9.5 compared to the dry environment, and the color conversion from achromatic to green was excellent as a sensor. The results of this study suggest the application of MOF materials to moisture sensors, and the nanostructure design of MOF materials will expand the applications to industrial devices.

Reviews on Post-synthetic Modification of Metal-Organic Frameworks Membranes (다결정 금속 유기 골격체 분리막의 후처리 성능 제어기술 개발 동향)

  • Hyuk Taek, Kwon;Kiwon, Eum
    • Membrane Journal
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    • v.32 no.6
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    • pp.367-382
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    • 2022
  • Numerous metal-organic frameworks (MOFs) produced by periodic combinations of organic ligands and metal ions or metal-oxo clusters have led the way for the creation of energy-efficient membrane-based separations that may serve as viable replacements for traditional thermal counterparts. Although tremendous progress has been made over the past decade in the synthesis of polycrystalline MOF membranes, only a small number of MOFs have been exploited in the relevant research. Intercrystalline defects, or nonselective diffusion routes in polycrystalline membranes, are likely the reason behind the delay. Postsynthetic modifications (PSMs) are newly emerging strategies for providing polycrystalline MOF membrane diversity by leveraging advanced membranes as a platform and improving their separation capabilities via physical and/or chemical treatments; therefore, neither designing and developing MOFs nor tailoring membrane synthesis techniques for focused MOFs is necessary. In this minireview, seven subclasses of PSM techniques that have recently been adapted to polycrystalline MOF membranes are outlined, along with obstacles and future directions.

A Study on the Fire Properties of MOF Insulation Cover and Field Condition of 22.9kV Class Power Receiving System (22.9kV 수변전설비의 실태 및 계기용변성기 절연커버의 출화특성에 관한 연구)

  • Choi Chung-Seog;Kim Dong-Woo;Han Woon-Ki;Lee Ki-Yeon
    • Journal of the Korean Society of Safety
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    • v.20 no.2 s.70
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    • pp.56-60
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    • 2005
  • We studied fire properties of MOF(Metering Out Fit) insulation cover and field condition of 22.9kV power receiving system. $49.5\%$ of formal equipments were installed indoors, whereas $40.8\%$ of informal equipments were installed as H-type. Insulation treatment was not done at a $22.4\%$ ratio of main line($27.7\%$ of transformer, $70.2\%$ of COS, $10.4\%$ of MOF). Fire pattern analysis showed that the fire started at the secondary part of OC wire. In the result of DTA(Differential Thermal Analysis), normal cover showed exothermic reactions at $310^{\circ}C,\;399^{\circ}C\;and\;510^{\circ}C$ (endothermic reactions at $382^{\circ}C$). Whereas damaged cover showed exothermic reactions at $412^{\circ}C$(endothermic reactions at $389^{\circ}C$). In the result of TGA(Thermo Gravimetric Analysis), the thermal weight change of normal cover was similar compared to damaged cover. In the result of FT-IR analysis, normal cover showed absorption peaks at $3,024cm^{-l},\;2,921cm^{-l},\;1,600cm^{-1},\;1,492cm^{-1},\;1,451cm^{-1},\;1,154cm^{-l},\;1,027cm^{-1},\;906cm^{-1}$. Whereas, in case of tracked cover, the absorption peaks that were shown in normal cover disappeared and different absorption peak was shown at $966cm^{-1}$.

Deodorization Rate according to Zr-MOF Content and the Properties from Spinning Conditions of Polypropylene Non-woven Fabric Manufactured by Melt-blown Method (Melt-blown법에 의해 제조된 Polypropylene 부직포의 방사 조건별 특성과 기능화된 Zr-MOF 함유량에 따른 소취율 변화에 대한 연구)

  • Choi, Ik-Sung;Min, Mun-Hong;Kim, Han-Il;Lee, Woo-Seung;Noh, Kyung-Gyu;Park, Seong-Woo
    • Textile Coloration and Finishing
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    • v.30 no.3
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    • pp.199-207
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    • 2018
  • In this study, the properties of polypropylene(PP) non-woven fabric spun under various conditions by the Melt-blown method were verified, and the deodorant content and deodorization of PP non-woven fabric after deodorant-treatment were investigated. PP non-woven fabrics are manufactured by varying the temperature of spin beam, hot air temperature and amount, the RPM of collector R/O and the distance between collector and spinneret, which affects the structure of the non-woven fabric. After that, the structural characteristics and air permeability of the non-woven fabric were measured. The experimental results show that the amount of air, the distance between the collector and the spinneret significantly affect the structural characteristics and air permeability of the PP non-woven fabric. And, regardless of the weight of the PP non-woven fabric, the deodorizing effect of UiO-66 MOF deodorant add-on ratio and content was higher.

Catalytic Application of Metal-Organic Frameworks for Chemical Fixation of CO2 into Cyclic Carbonate (CO2로부터 5원환 탄산염의 화학적 고정화 반응을 위한 Metal-Organic Frameworks의 촉매적 응용)

  • Ji, Hoon;Naveen, Kanagaraj;Kim, Dongwoo;Cho, Deug-Hee
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.258-266
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    • 2020
  • The chemical fixation of CO2 into cyclic carbonates is considered to be one of the most promising way to alleviate global warming and produce fine chemicals. In this work, the catalytic applicability of metal-organic frameworks (MOFs) as porous crystalline materials for the synthesis of five-membered cyclic carbonate from CO2 and epoxides was reviewed. In addition, we have briefly classified the materials based on their different structural features and compositions. The studies revealed that MOFs exhibited good catalytic performance towards cyclic carbonate synthesis because of the synergistic effect between the acid sites of MOFs and nucleophile. Moreover, the effect of structure of designed MOFs and mechanism for the cycloaddition of CO2 were suggested.