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First-principles Calculations on Magnetism of 1H/1T Boundary in Monolayer MoS2 (제일원리계산에 의한 단층 MoS2의 1H/1T 경계 자성)

  • Jekal, Soyoung;Hong, Soon Cheol
    • Journal of the Korean Magnetics Society
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    • v.26 no.3
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    • pp.71-75
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    • 2016
  • Monolayer $MoS_2$ is energetically most stable when it has a 1H phase, but 1H to 1T phase transition ($1H{\rightarrow}1T$) is easily realized by various ways. Even though magnetic moment is not observed during $1H{\rightarrow}1T$, $0.049{\mu}_B/MoS_2$ is obtained in local 1T phase; 75% 2H and 25% 1T phases are mixed in ($2{\times}2$) supercell. Most magnetic moment is originated from the 1T phase Mo atom in the supercell, while the magnetic moments of other atoms are negligible. As a result, magnetic/non-magnetic boundary is created in the monolayered $MoS_2$. Our result suggests that $MoS_2$ can be applied for spintronics such as a spin transistor.

Fabrication of Two-dimensional MoS2 Films-based Field Effect Transistor for High Mobility Electronic Device Application

  • Joung, DaeHwa;Park, Hyeji;Mun, Jihun;Park, Jonghoo;Kang, Sang-Woo;Kim, TaeWan
    • Applied Science and Convergence Technology
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    • v.26 no.5
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    • pp.110-113
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    • 2017
  • The two-dimensional layered $MoS_2$ has high mobility and excellent optical properties, and there has been much research on the methods for using this for next generation electronics. $MoS_2$ is similar to graphene in that there is comparatively weak bonding through Van der Waals covalent bonding in the substrate-$MoS_2$ and $MoS_2-MoS_2$ heteromaterial as well in the layer-by-layer structure. So, on the monatomic level, $MoS_2$ can easily be exfoliated physically or chemically. During the $MoS_2$ field-effect transistor fabrication process of photolithography, when using water, the water infiltrates into the substrate-$MoS_2$ gap, and leads to the problem of a rapid decline in the material's yield. To solve this problem, an epoxy-based, as opposed to a water-based photoresist, was used in the photolithography process. In this research, a hydrophobic $MoS_2$ field effect transistor (FET) was fabricated on a hydrophilic $SiO_2$ substrate via chemical vapor deposition CVD. To solve the problem of $MoS_2$ exfoliation that occurs in water-based photolithography, a PPMA sacrificial layer and SU-8 2002 were used, and a $MoS_2$ film FET was successfully created. To minimize Ohmic contact resistance, rapid thermal annealing was used, and then electronic properties were measured.

The Effect of Precursor pH and Calcination Temperature on the Molybdenum Species over Silica Surface (전구체의 pH와 소성 온도가 실리카에 담지된 몰리브드늄 활성종에 미치는 영향)

  • Ha Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.6
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    • pp.558-561
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    • 2004
  • The morphology of silica supported $MoO_{3}$ catalysts, which was prepared by impregnation of ammonium heptamolybdate(AHM) with various surface loadings up to 4 atoms $Mo/nm^{2}$, was studied using x-ray diffraction(XRD). All morphologies of silica supported $MoO_{3}$ appear to be thermodynamically driven. For high loaded catalysts there appeared three states: a sintered and well-dispersed hexagonal state at moderate temperature calcination($300^{\circ}C$), and a sintered orthorhombic state at high temperature calcination($500^{\circ}C$). Whereas the sintered orthorhombic phase is detected by XRD at loadings in excess of 1.1 atom $Mo/nm^{2}$, the well-dispersed hexagonal phase is not detected even until 4.0 $atomsMo/nm^{2}$. The higher apparent dispersion of the hexagonal phase may arise from some role of ammonia which results in a stronger $MoO_{3}-SiO_{2}$ surface interaction.

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Effect of $MoO_3$ addition on the permeability of Mn-Zn ferrites ($MoO_3$ 첨가가 Mn-Zn Ferrites의 투자율에 미치는 영향)

  • 장정수;한영호;신명승
    • Journal of the Korean Magnetics Society
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    • v.11 no.1
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    • pp.26-31
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    • 2001
  • The effect of MoO$_3$ addition on the permeability of Mn-Zn ferrites was studied. 600 ppm, 800 ppm and 1,000 ppm of MoO$_3$ were added to the main composition after calcination. Ferrite cores were sintered at 135$0^{\circ}C$ for 3hrs, followed by cooling according to the equilibrium oxygen concentration. The initial permeability was about 8,000 with heating rate 5$^{\circ}C$/min for 3hrs without MoO$_3$ addition. When 600 ppm and 800 ppm of MoO$_3$ were added, the initial permeabilities, 13,200 and 13,550 were obtained, respectively. However, the sample with 1,000 ppm MoO$_3$ showed lower permeabilities because of abnormal grain growth. At the heating rate 1$0^{\circ}C$/min, the ferrite cores with 1,000 ppm MoO$_3$ demonstrated the highest initial permeability greater than 15,000, without exaggerated grain growth.

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Failure Analysis and Accelerated Life Test of MoxW1-xSi2 Haters Fabricated by SHS process (SHS 공정으로 제조된 MoxW1-xSi2 발열체의 가속수명시험과 고장분석)

  • Lee, Dong-Won;Lee, Sang-Hun;Kim, Yong-Nam;Lee, Heesoo;Lee, Sung-Chul;Koo, Sang-Mo;Oh, Jong-Min
    • Journal of IKEEE
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    • v.21 no.3
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    • pp.252-255
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    • 2017
  • $Mo_xW_{1-x}Si_2$ heaters were fabricated by self-propagating high-temperature synthesis (SHS) process and post sintering process. To validate the reliability of the $Mo_xW_{1-x}Si_2$ heaters, the accelerated life test (ALT) was conducted, and then lifetime to $Mo_xW_{1-x}Si_2$ heaters was estimated by using Minitab programs. Also, the failure analysis of $Mo_xW_{1-x}Si_2$ heaters after ALT was performed through electrical and structural properties. As the results, it was confirmed that the dominant failure mode of $Mo_xW_{1-x}Si_2$ heaters is the crack formation in heaters and the delamination of protective $SiO_2$ layers.

A Study on the Effects of pH and Ni/Mo Mole Ratio during Wet Impregnation on the Characteristics and Methane Dry Reforming Reactivity of Activated Charcoal Supported Ni-Mo Carbide Catalyst (습식담지시 pH와 Ni/Mo 몰비가 Ni-Mo/AC 카바이드 촉매의 특성과 메탄건식개질 반응성에 미치는 영향)

  • Lee, Dongmin;Hwang, Unyeon;Park, Hyungsang;Park, Sungyoul;Kim, Seongsoo
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.4
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    • pp.344-354
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    • 2014
  • Activated charcoal supported nickel molybdenum carbide (carburized Ni-Mo/AC) catalysts were prepared by wet-impregnation followed by temperature-programmed carburization using 20% $CH_4/H_2$ gas. The effects of pH and initial Ni/Mo mole ratio during wet-impregnation step on the characteristics of the carburized Ni-Mo/AC catalysts were investigated using ICP, XRD, XPS, BET and $CO_2$-TPD techniques, and correlated with the catalytic activity of the carburized Ni-Mo/AC in methane dry reforming reaction. Comparison of the results of methane dry reforming reaction kinetics with the results of characterization of the carburized Ni-Mo/AC catalyst showed that the catalytic activity in methane dry reforming reaction was higher at higher initial Ni/Mo mole ratio or at lower pH(3~natural value). This phenomenon was related to the crystal size of metallic Ni in the carburized Ni-Mo/AC catalyst.

Rates and Mechanism of the Reactions of Aquaoxomolybdenum (IV) Trimer with Vanadium (V) (아쿠아옥소몰리브덴(IV) 삼합체 착물과 바나듐(V)과의 반응에 대한 속도와 메카니즘)

  • Chang-Su Kim;Moon-Pyoung Yi
    • Journal of the Korean Chemical Society
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    • v.31 no.2
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    • pp.178-183
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    • 1987
  • The kinetics of the reaction of $[Mo_3O_4(H_2O)_9]^{4+}$ with $VO_2^+$have been studied at $25^{\circ}C$ by spectrophotometric method. With$VO_2^+$ in excess, the $[Mo_3O_4(H_2O)_9]^{4+}$ reaction can be expressed as $Mo^{IV}_3+6V^V{\rightleftarrows}3Mo^{IV}+6V^IV}$. Observed rate constants for the reaction are dependent on [$H^+$] and [$VO_2^+$]. Mechanism for the redox of $[Mo_3O_4(H_2O)_9]^{4+}$and $VO_2^+$ is proposed and discussed.

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Fabrication and Fracture Properties of Nb/MoSi2Laminate Composites (Nb/MoSi2적층복합재료의 제조 및 파괴특성)

  • Lee, Sang-Pill;Yoon, Han-Ki
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.6
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    • pp.1047-1052
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    • 2002
  • The impact value, the interfacial shear strength, the tensile strength and the fracture strain of Nb/MoSi$_2$laminate composites, which were associated with the interfacial reaction layer, have been investigated. Three types of Nb/MoSi$_2$ laminate composites alternating sintered MoSi$_2$ layers and Nb foils were fabricated as the parameter of hot press temperature. The thickness of interfacial reaction layer of Nb/MoSi$_2$ laminate composites increased with increasing the fabrication temperature. The growth of interfacial reaction layer increased the interfacial shear strength and led to the decrease of impact value in Nb/MoSi$_2$ laminate composites. It was also found that in order to maximize the fracture energy of Nb/MoSi$_2$ laminate composites, interfacial shear strength and the thickness of interfacial reaction layer must be secured appropriately.

Effect of Phase Change of $MoO_3$ on $H_2$ Spillover Kinetics over Pt/$MoO_3$ (Pt/$MoO_3$ 촉매에서 $MoO_3$ 상변화가 수소 spillover에 미치는 효과)

  • Kim, Jin-Gul;Kim, Seong-Soo;Yoo, Seung-Joon
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.4
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    • pp.331-336
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    • 2009
  • 수소가 Pt/$MoO_3$로 흡장되는 현상을 XRD, TEM, CO 화학흡착 분석방법을 사용하여 조사하였다. 소성과정은 Pt/$MoO_3$ 촉매의 Chlorine 함유량을 감소하며 박막을 형성하였다. 소성전과 비교하여 수소 흡장량은 소성 후에 증가하였다. Orthorhombic Pt/$MoO_3$은 Hexagonal Pt/$MoO_3$보다 항상 수소 흡장량이 증가하였다. 상대적으로 Hexagonal Pt/$MoO_3$에서 수소 흡장량이 감소하는 이유는 Hexagonal 결정격자 내에 존재하는 $NH_4^+$ 이온에 기인하는 것으로 판단된다. 결정격자 내부로의 수소 침투시 암모니움 이온이 수소내부 기공에 장애물 역할을 하므로, 수소 흡장량이 감소하는 것으로 판단된다.

A Study on the Architectural Means of Mo-Jung (모정건축이 갖는 건축적 의미에 관한 연구)

  • 김학삼
    • Journal of the Korean housing association
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    • v.12 no.2
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    • pp.65-76
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    • 2001
  • The study background is that Mo-Jung happens as the produce of the agricultural society but it is not easy to find it beside Ho-nam area. Because of this, it results construction has. The study progress is to understand the happening time, and regional cause the Mo-Jung construction has. The study progress is to understand the happening time of Mo-Jung, constructional meaning, and the meaning of Mo-Jung with the investigation method of literature consideration of the village society, data of the existing study, survey investigation, interview, and question through the process of analyzing the characteristics of differentiation of the village and Dure organization. 1. Mo-Jung construction has the meaning of vernacular construction reflecting the meaning of village community intensively as an element comprising the village, and the territory of Mo-Jung space is revealed as the male space. 2. The economic wealth of the village community and the image reflecting the community sense are stood out. 3. It is the reason why Mo-Jung construction is limited to Ho-nam area and is explained as the life style difference each village community has, the regional characteristic difference Dae-dong play of Yong.Ho-nam areas have, etc. so to speak. 4. It is estimated that the happening time of Mo-Jung is after the 18th century when the agricultural As my suggestion, Mo-Jung construction is the construction phenomenon reflecting the phenomenon of social change directly and it is to suggest the possibility of approaching the regional housing construction as the life style difference the life community of each area has is reflected. production quantity was increased and Dure organization was activated.

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