• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 가을학술발표대회논문집
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• pp.109-110
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• 2023

Domestic ultra-hard road repair materials require a lot of time before the road can be opened to traffic. Therefore, in this study, Methyl Methacrylate (MMA) based road repair material was used to improve the above problems. Furthermore, the basic physical properties of MMA-based pavement repair materials are examined to confirm their suitability in concrete pavements. For this study, two types of MMA road repair materials (A type and B type) were selected. Then, the curing of the test specimens prepared for painting was carried out under three conditions. The experimental items were viscosity (drop time) and drying time (set to touch, dry-hard). As a result of the experiment, viscosity (drop time) was faster in type A than in type B. The drying time results were as follows. In the case of set ti touch, both type A and type B dried in about 10 minutes regardless of the curing conditions. In the case of dry-hard, regardless of the curing conditions, A type dried longer than B type, but it dried faster than conventional road repair materials. Therefore, within the scope of this study, it is considered that A type has a high potential for utilization as a road repair material.

• Bulletin of the Korean Chemical Society
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• 제17권1호
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• pp.16-19
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• 1996

The bulk photopolymerization of methyl methacrylate (MMA) with disilanes such as 1,2-diphenyldisilane and 2-phenyl-1,3-disilapropane was carried out to yield poly(MMA)s containing the corresponding disilyl moiety presumably as an end group. It was found that while the polymerization yields and the polymer molecular weights decreased as the relative disilane concentration increased, the TGA residue yields and the relative intensities of SiH IR stretching bands increased with increment of molar ratio of disilane over MMA. The photopolymerization of MMA with 2-phenyl-1,3-disilapropane produced higher-molecular-weight polymer with lower TGA residue yield when compared to the photopolymerization of MMA with 1,2-diphenyldisilane. The disilanes seemed to significantly influence on the photopolymerization as both chain initiation and chain transfer agents.

• Bulletin of the Korean Chemical Society
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• 제16권11호
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• pp.1056-1059
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• 1995

The bulk photopolymerization of methyl methacrylate (MMA) with primary arylsilane (e.g., phenylsilane) and various primary alkylsilanes (e.g., benzylsilane, 3-phenoxyphenyl-1-silabutane, 3-naphthyl-1-silabutane, and 3-chlorophenyl-1-silabutane) was performed to produce poly(MMA)s containing the corresponding silyl moiety as an end group. It was found for the phenylsilane that while the polymerization yields increased and then decreased with a turning point at the molar ratio of MMA:silane=10:1 as the relative silane concentration increases, the polymer molecular weights decreased, and the TGA residue yields and the relative intensities of SiH IR stretching bands increased with increment of molar ratio of silane over MMA. The photopolymerization yield of MMA with the arylsilane was found to be higher than those with the alkylsilanes and without the silanes. Thus, the silanes seemed to significantly influence on the photopolymerization as both chain initiation and chain transfer agents.

• Bulletin of the Korean Chemical Society
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• 제21권3호
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• pp.291-294
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• 2000

The bulk photopolymerization of methyl methacrylate(MMA) with bis(silane)s such as 1,4-$C_6H_4(SiH_3)_2$ (1) and 1,4-$C_6H_4(SiH_2Me)_2$ (2) was performed to produce poly(MMA)s possessing the corresponding bis(silyl) moiety as an end group. For the bis(silane)s, while the polymerizaiton yields and the polymer molecular weights decreased, the TGA residue yields and the relative intensities of Si-H IR stretching bands increased as the relative bis(silane) concentration over MMA increased. The polymerizaion yield, polymer molecular weight, and TGA residue yield of MMA with 1 were found to be higher than those with 2. The bis(silane)s appears to influence significantly upon the photopolymerization of MMA as both chain initiation and chain transfer agents.

• 폴리머
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• 제33권3호
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• pp.230-236
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• 2009

비닐 아세테이트/알킬메타크릴레이트계 에멀젼 공중합에서 반응온도, 개시제의 종류와 농도, 보호콜로이드인 PVA의 종류와 농도, 공단량체인 MMA, EMA의 조성비를 변화시키며 중합하였다. 제조된 공중합체인 poly(vinyl acetate-co-methyl methacrylate)(PVAc/PMMA), poly(vinyl acetate-co-ethyl methacrylate)(PVAc/PEMA)를 수분 측정기를 사용하여 100, 130, 150, 180, $200^{\circ}C$에서 등온건조 시키고, 그 건조 특성을 고찰하여 다음과 같은 결론을 얻었다. 등온법으로 얻은 중합체 고형화 과정의 활성화 에너지는 PVAc/PMMA> PVAc/PEMA> PVAc의 순으로 공단량체의 곁사슬의 탄소수 증가에 따라 감소하였다. 접착박리강도는 동일한 조성의 공중합체에서 보호콜로이드 함량에 비례하여 증가하였고, 내수 접착박리강도는 최적의 보호콜로이드 함량에서 공단량체의 종류와 함량에 따라 PVAc/PMMA>PVAc/PEMA>PVAc 순이다.

• Korean Chemical Engineering Research
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• 제52권4호
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• pp.451-458
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• 2014

Isophrone diisocyanate (IPDI), polycarbonate diol (PCD)과 dimethylol propionic acid (DMPA)를 출발물질로 하여 수분산 폴리우레탄(waterborne polyurethane dispersion, WPUD)을 합성하였다. 이 WPUD에 아크릴 단량체인 methyl methacrylate (MMA), 2-hydroxyethyl methacrylate (HEMA)와 butyl acrylate (BA)를 각각 첨가하여 다양한 종류의 수분산 아크릴 폴리우레탄(waterborne acrylic polyurethane dispersion, AUD)을 합성하였다. 이 AUD와 물에 분산된 다중벽 탄소나노튜브(multi-walled carbon nanotube, MWCNT)를 혼합하여 전도성 코팅 용액을 제조한 후 polycarbonate 시트 위에 도포하여 코팅 도막을 형성하고 물성을 살펴보았다. AUD로부터 제조된 코팅 도막의 연필경도, 내마모성 및 내약품성은 WPUD 보다 향상되었으나, 전기 전도도는 감소하였다. 또한 아크릴 단량체의 종류 변화 실험에서는 코팅 도막의 연필경도는 HEMA를 사용한 경우가 가장 우수하였으나, 내마모성, 내약품성 및 전기 전도도는 MMA를 사용한 경우가 가장 우수하였다.

• 한국건축시공학회지
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• 제24권1호
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• pp.35-42
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• 2024

본 연구에서는 도로 보수재로서 메틸 메타크릴레이트(MMA)의 활용 적합성을 평가하였다. A type과 B type의 2가지 MMA를 콘크리트에 적용하여 건조시간, 인장 접착 강도, 내알칼리 시험을 진행하였다. 항온항습(R), 수중(W), 수중+염화이온(N)의 3가지 조건으로 양생하여 모체의 표면 상태를 설정하였다. 시험 결과, B type MMA가 A type 보다 빠른 건조시간과 우수한 내알칼리성을 나타냈다. 인장 접착 강도는 A type이 더 높게 나타났지만, 콘크리트 모체와 함께 탈락되었다. 본 연구 범위에서는 B type이 도로 보수재로 사용하기 적합하다고 판단된다. 그러나 내구성을 고려하여 아스팔트 모체에서의 추가 실험을 진행할 필요가 있다.

• Korean Chemical Engineering Research
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• 제50권4호
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• pp.632-638
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• 2012

Isophorone diisocyanate (IPDI), polycarbonate diol (PCD), dimethylol propionic acid (DMPA)를 출발물질로 하여 수분산 폴리우레탄(waterborne polyurethane dispersion, PUD)을 합성하였다. 이 PUD에 아크릴 단량체인 HEMA (2-hydroxyethyl methacrylate)와 MMA (methyl methacrylate)의 혼합물을 첨가하여 수분산 폴리우레탄-아크릴 혼성 용액을 제조하였다. 그 결과 제조된 혼성 용액의 평균 입도는 아크릴 단량체의 첨가량이 증가함에 따라 증가하였다. 또한 수분산 폴리우레탄-아크릴 혼성 용액으로부터 제조된 코팅 도막의 내마모성과 내화학성은 순수한 PUD 보다 크게 향상되었다.

• Macromolecular Research
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• 제15권4호
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• pp.302-307
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• 2007

The living radical polymerization of methyl methacrylate (MMA) by atom transfer radical polymerization, (ATRP) employing a $Fe(II)X_2/diphenyl-2-pyridyl$ phosphine (PyP) catalytic system (X=Cl, Br), was investigated using several initiators and solvents at various temperatures. Most of the polymerizations with the PyP ligand were well controlled, with a linear increase in the number average molecular weights ($M_n$) vs. conversion, with relatively low molecular weight distributions ($M_w/M_n=1.2-1.4$) throughout the reactions. The measured weights matched those of the predicted values. The ethyl-2-bromoisobutyrate (EBriB) initiated ATRP of MMA, with the $Fe(II)X_2/diphenyl-2-pyridyl$ phosphine catalytic system (X=Cl, Br), was better controlled in p-xylene at $80^{\circ}C$ than the other solvents used in this study.

• Bulletin of the Korean Chemical Society
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• 제35권10호
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• pp.2929-2934
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• 2014

The reaction between $[CdBr_2{\cdot}4H_2O]$ and anhydrous $[ZnCl_2]$ with N,N'-bidentate N-(pyridin-2-ylmethylene)-cyclopentanamine (impy) in ethanol yields dimeric $[(impy)Cd({\mu}-Br)Br]_2$ and monomeric $[(impy)ZnCl_2]$ complexes, respectively. The X-ray crystal structure of Cd(II) and Zn(II) complexes revealed that the cadmium atom in $[(impy)Cd({\mu}-Br)Br]_2$ and zinc in $[(impy)ZnCl_2]$ formed a distorted trigonal-bipyramidal and tetrahedral geometry, respectively. Both complexes showed moderate catalytic activity for the polymerisation of methyl methacrylate (MMA) in the presence of modified methylaluminoxane (MMAO), with polymethylmethacrylate (PMMA) syndiotacticity of about 0.70.